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1-Bromo-2-methoxy-3-nitro-benzene

Product Name
1-Bromo-2-methoxy-3-nitro-benzene
CAS No.
98775-19-0
Chemical Name
1-Bromo-2-methoxy-3-nitro-benzene
Synonyms
2-Bromo-6-nitroanisole;3-Bromo-2-methoxynitrobenzene;1-bromo-2-methoxy-3-Nitroenzene;1-Bromo-2-methoxy-3-nitro-benzene;2-bromo-6-nitrophenyl methyl ether;Benzene,1-bromo-2-methoxy-3-nitro-;3-BroMo-2-Methoxynitrobenzene[2-BroMo-6-nitroanisole];2-BROMO-6-NITRO ANISOLE / 1-Bromo-2-methoxy-3-nitrobenzene;3-Bromo-2-methoxynitrobenzene, 1-Bromo-2-methoxy-3-nitrobenzene
CBNumber
CB01180356
Molecular Formula
C7H6BrNO3
Formula Weight
232.03
MOL File
98775-19-0.mol
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1-Bromo-2-methoxy-3-nitro-benzene Property

Boiling point:
296.4±20.0 °C(Predicted)
Density 
1.640±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
solid
color 
Off white to faint yellow
InChI
InChI=1S/C7H6BrNO3/c1-12-7-5(8)3-2-4-6(7)9(10)11/h2-4H,1H3
InChIKey
YAYBLVOBUIXMQY-UHFFFAOYSA-N
SMILES
C1(Br)=CC=CC([N+]([O-])=O)=C1OC
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Safety

HS Code 
2909309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC
Product number
B696760
Product name
1-Bromo-2-methoxy-3-nitrobenzene
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
B696760
Product name
1-Bromo-2-methoxy-3-nitrobenzene
Packaging
10g
Price
$165
Updated
2021/12/16
Matrix Scientific
Product number
116109
Product name
1-Bromo-2-methoxy-3-nitrobenzene
Purity
>90%
Packaging
500mg
Price
$10
Updated
2021/12/16
Matrix Scientific
Product number
116109
Product name
1-Bromo-2-methoxy-3-nitrobenzene
Purity
>90%
Packaging
1g
Price
$14
Updated
2021/12/16
Oakwood
Product number
211481
Product name
1-Bromo-2-methoxy-3-nitrobenzene
Purity
95+%
Packaging
1g
Price
$18
Updated
2021/12/16
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1-Bromo-2-methoxy-3-nitro-benzene Chemical Properties,Usage,Production

Chemical Properties

White to off-white powder

Synthesis

13073-25-1

74-88-4

98775-19-0

General procedure for the synthesis of 2-bromo-6-nitroanisole from 2-bromo-6-nitrophenol (19.6 g, 90.0 mmol) and iodomethane (25.6 g, 180 mmol): first, 2-bromo-6-nitrophenol and potassium carbonate (24.9 g, 180 mmol) were mixed in acetone (400 mL). Subsequently, iodomethane was added to the mixture. The reaction mixture was heated to reflux overnight. After completion of the reaction, it was cooled to room temperature, the mixture was filtered and the filter cake was washed with ethyl acetate (100 mL). The filtrate was concentrated under reduced pressure. The residue was dissolved in ethyl acetate and the resulting solution was washed with saturated brine and dried with anhydrous sodium sulfate. Finally, the dried solution was concentrated to give 1-bromo-2-methoxy-3-nitrobenzene (20.2 g, 97% yield) as a yellow solid. The 1H-NMR spectrum (300 MHz, DMSO-d6) data of the product were as follows: δ (ppm): 3.92 (s, 3H), 7.32 (d, 1H, J = 8.1 Hz), 7.94-8.03 (m, 2H).

References

[1] Patent: EP2987787, 2016, A1. Location in patent: Paragraph 0129-0130
[2] Patent: WO2014/74661, 2014, A1. Location in patent: Paragraph 00172
[3] Patent: US2014/296229, 2014, A1. Location in patent: Paragraph 0254; 0255; 0256
[4] Patent: WO2014/154760, 2014, A1. Location in patent: Page/Page column 55
[5] Patent: EP2236500, 2010, A1. Location in patent: Page/Page column 15

1-Bromo-2-methoxy-3-nitro-benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Bromo-2-methoxy-3-nitro-benzene Suppliers

China 172 Germany 1 India 13 The Netherlands 1 United Kingdom 3 United States 13 Global 203
Specs
Tel
--
Fax
--
Email
info@specs.net
Country
The Netherlands
ProdList
6833
Advantage
70
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View Lastest Price from 1-Bromo-2-methoxy-3-nitro-benzene manufacturers

Jinan Ruitong Biotech Co., Ltd.
Product
2-Bromo-6-Nitroanisole 98775-19-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1
Release date
2025-08-25
Henan Aochuang Chemical Co.,Ltd.
Product
1-Bromo-2-methoxy-3-nitro-benzene 98775-19-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-27
Henan Fengda Chemical Co., Ltd
Product
1-Bromo-2-methoxy-3-nitro-benzene 98775-19-0
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28

98775-19-0, 1-Bromo-2-methoxy-3-nitro-benzeneRelated Search:

p-Anisidine 2-Bromo-6-nitrophenol Eltrombopag

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  • 2-Bromo-6-nitroanisole
  • 3-Bromo-2-methoxynitrobenzene, 1-Bromo-2-methoxy-3-nitrobenzene
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  • 2-bromo-6-nitrophenyl methyl ether
  • 1-bromo-2-methoxy-3-Nitroenzene
  • 2-BROMO-6-NITRO ANISOLE / 1-Bromo-2-methoxy-3-nitrobenzene
  • 98775-19-0