(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh

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Product Name: (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh
CAS No.: 521272-85-5
Chemical Name: (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh
Synonyms: (R,R)-NORPHOS-Rh;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh;(1Z,5Z)-cycloocta-1,5-diene:[(1S,2R,3R,4R)-2-diphenylphosphanyl-3-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane:rhodium:tetrafluoroborate;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh
CBNumber: CB01180967
Molecular Formula: C31H28P2.C8H12.BF4.Rh
Formula Weight: 760.406
MOL File: 521272-85-5.mol

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(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh Property

form: Powder
color: red-orange
Sensitive: air sensitive
CAS DataBase Reference: 521272-85-5

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 45-0184
Product name: (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh
Packaging: 100mg
Price: $129
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0184
Product name: (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh
Packaging: 500mg
Price: $512
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: OGM0000054
Product name: (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
Purity: 95.00%
Packaging: 5MG
Price: $504.87
Updated: 2021/12/16

Arctom

Product number: AS442837
Product name: (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
Purity: 98%
Packaging: 50mg
Price: $124
Updated: 2021/12/16

Arctom

Product number: AS442837
Product name: (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
Purity: 98%
Packaging: 100mg
Price: $219
Updated: 2021/12/16

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(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh Chemical Properties,Usage,Production

Reactions

Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh Preparation Products And Raw materials

Raw materials

Preparation Products

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(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh Suppliers

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521272-85-5, (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-RhRelated Search:

1,2-Bis(diphenylphosphino)ethane 1,5-Bis(diphenylphosphino)pentane (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE 1,2-BIS(PHENYLPHOSPHINO)ETHANE R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-<br />cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh

(1Z,5Z)-cycloocta-1,5-diene:[(1S,2R,3R,4R)-2-diphenylphosphanyl-3-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane:rhodium:tetrafluoroborate

(R,R)-NORPHOS-Rh

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

521272-85-5

C39H40BF4P2Rh

RhC8H12C31H28P2BF4

organometallic complex