(2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE

Product Name: (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE
CAS No.: 74839-84-2
Chemical Name: (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE
Synonyms: (R,R)-CHIRAPHOS;(2R,3R)-Chiraphos;(R,R)-Chiraphos,97%;2,3-Bis(diphenylphosphino)butane;(2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE;(2R,3R)-Butane-2,3-diylbis(diphenylphosphine);(2R,3R)-(+)-2,3-BIS(DIPHENYL PHOSPHINO)BUTANE;((2R,3R)-butane-2,3-diyl)bis(diphenylphosphane);(2R,3R)-(+)-Bis(diphenylphosphino)butane, (R,R)-CHIRAPHOS;[(2R,3R)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane
CBNumber: CB2351836
Molecular Formula: C28H28P2
Formula Weight: 426.48
MOL File: 74839-84-2.mol

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(2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE Property

Melting point:: 104-109 °C
Boiling point:: 529.2±33.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
color: white
Sensitive: Air Sensitive
InChI: 1S/C28H28P2/c1-23(29(25-15-7-3-8-16-25)26-17-9-4-10-18-26)24(2)30(27-19-11-5-12-20-27)28-21-13-6-14-22-28/h3-24H,1-2H3/t23-,24-/m1/s1
InChIKey: FWXAUDSWDBGCMN-DNQXCXABSA-N
SMILES: C[C@H]([C@@H](C)P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
CAS DataBase Reference: 74839-84-2

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 36/37/39-26-37/39
WGK Germany: 3
TSCA: No
HS Code: 29310099
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 725102
Product name: (2R,3R)-(+)-2,3-Bis(diphenylphosphino)butane
Packaging: 250mg
Price: $99.9
Updated: 2025/07/31

Sigma-Aldrich

Product number: 725102
Product name: (2R,3R)-(+)-2,3-Bis(diphenylphosphino)butane
Packaging: 1g
Price: $361
Updated: 2025/07/31

Strem Chemicals

Product number: 15-0165
Product name: (2R,3R)-(+)-Bis(diphenylphosphino)butane, min.98%,(R,R)-CHIRAPHOS
Packaging: 250mg
Price: $95
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0165
Product name: (2R,3R)-(+)-Bis(diphenylphosphino)butane, min.98%,(R,R)-CHIRAPHOS
Packaging: 1g
Price: $286
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0165
Product name: (2R,3R)-(+)-Bis(diphenylphosphino)butane, min.98%,(R,R)-CHIRAPHOS
Packaging: 5g
Price: $1143
Updated: 2024/03/01

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(2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder

Uses

(2R,3R)-Bis(diphenylphosphino)butane is a reagent used in the synthesis of endothelin A receptor antagonists. Also used in the synthesis of (R)-Tolterodine and (S)-Tolterodine.

Purification Methods

It recrystallises from absolute EtOH (~6g in 60mL) as colourless plates [Fryzuk & Bosnich J Am Chem Soc 99 6262 1977, Fryzuk & Bosnich J Am Chem Soc 101 3043 1979].

(2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE Suppliers

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View Lastest Price from (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE manufacturers

Career Henan Chemical Co

Product: (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE 74839-84-2
Price: US $1.00-2.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,10kg,100kg
Release date: 2019-08-07

74839-84-2, (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANERelated Search:

(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE (-)-DIOP 1,4-Bis(diphenylphosphino)butane (+)-DIOP 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Diphenylphosphine 1,4-Bis(diphenylphosphino)butane Monooxide DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II) (+)-(3R,4R)-BIS(DIPHENYLPHOSPHINO)-1-BENZYLPYRROLIDINE (+)-(3R,4R)-BIS(DIPHENYLPHOSPHINO)-1-BENZYLPYRROLIDINE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh [1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE (+)-2,3-O-Isopropyliden-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane CHLOROCARBONYL[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM (I) [1,4-Bis(Diphenylphosphino)Butane]Nickel(Ii)Chloride

((2R,3R)-butane-2,3-diyl)bis(diphenylphosphane)

(R,R)-CHIRAPHOS

(2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE

(2R,3R)-(+)-2,3-BIS(DIPHENYL PHOSPHINO)BUTANE

(2R,3R)-(+)-Bis(diphenylphosphino)butane, (R,R)-CHIRAPHOS

(R,R)-Chiraphos,97%

(2R,3R)-(+)-Bis(diphenylphosphino)butane, 98% (R,R)-CHIRAPHOS

(2R,3R)-(+)-2,3-Bis(diphenylphosphino)butane (R,R)-CHIRAPHOS

2,3-Bis(diphenylphosphino)butane

(2R,3R)-Butane-2,3-diylbis(diphenylphosphine)

1,1'-[(1R,2R)-1,2-Dimethyl-1,2-ethanediyl]bis[1,1-diphenyl-phosphine

Phosphine, 1,1'-[(1R,2R)-1,2-dimethyl-1,2-ethanediyl]bis[1,1-diphenyl-

(2R,3R)?-?(+)?-?2,3-?Bis(diphenylphosphino)?butane,98%,99%ee

(2R,3R)-Chiraphos

[(2R,3R)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane

(2R,3R)?-?(+)?-?2,3-?Bis(diphenylphosphino)?butane (R,R)-CHIRAPHOS，97%

(R,R)-CHIRAPHOS, (2R,3R)-(+)-2,3-Bis(diphenylphosphino)butane

74839-84-2

C28H28P2

C30H43O2P

Chiral Phosphine

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