6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct

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Product Name: 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct
CAS No.: 121627-17-6
Chemical Name: 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct
Synonyms: BiPhePhos;6,6'-[(3,3'-Di-tert-butyL;-5,5'-dimethoxy-1,1'-biphenyL;)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin);6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diy...;2,2'-Bis[(1,1'-biphenyl-2,2'-diyl)phosphite]-3,3'-di-tert-butyl-5,5'-dimethoxy-1,1'-biphenyl;6,6-((3,3-diisopropyl-5,5-dimethoxy-[1,1-biphenyl]-2,2-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine;6,6'-((3,3'-di-tert-butyl-5,5'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine;6,6μ-[(3,3μ-Di-tert-butyl-5,5μ-dimethoxy-1,1μ-biphenyl-2,2μ-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin);6,6'-((3,3'-Di-tert-butyl-5,5'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine
CBNumber: CB01181025
Molecular Formula: C46H44O8P2
Formula Weight: 786.78
MOL File: 121627-17-6.mol

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6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct Property

Melting point:: 128-133 °C
Boiling point:: 768.3±60.0 °C(Predicted)
Density: 1.258 at 20℃
storage temp.: -20°C
form: Powder
color: white to off-white
Sensitive: air sensitive, moisture sensitive
LogP: 6 at 30℃ and pH7
CAS DataBase Reference: 121627-17-6

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 699535
Product name: 6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)
Purity: 97%
Packaging: 100mg
Price: $131
Updated: 2024/03/01

Sigma-Aldrich

Product number: 699535
Product name: 6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)
Purity: 97%
Packaging: 500mg
Price: $238.8
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0107
Product name: 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS
Packaging: 250mg
Price: $98
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0107
Product name: 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS
Packaging: 1g
Price: $343
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: CHM0012934
Product name: 6,6'-[(3,3'-DI-TERT-BUTYL-5,5'-DIMETHOXY-1,1'-BIPHENYL-2,2'-DIYL)BIS(OXY)]BIS(DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN) HEMI ETHYL ACETATE ADDUCT
Purity: 95.00%
Packaging: 5MG
Price: $502.18
Updated: 2021/12/16

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6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct Chemical Properties,Usage,Production

Reactions

With rhodium forms a highly active catalyst for the hydroformylation of α-olefins.
The hydroformylation of functionalized α-olefins is highly regioselective. The sterically demanding ligand increases n/iso ratio by reducing rhodium interaction with heteroatom functionality.
Ligand used in tandem reaction sequences where high n/iso ratio is desired in the hydroformylation step.

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct Preparation Products And Raw materials

Raw materials

Preparation Products

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121627-17-6, 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadductRelated Search:

PHENYLHYDROQUINONE 3-ISOPROPYLBIPHENYL 3-TERT-BUTYL-4-HYDROXYANISOLE 2,2'-Biphenol 2-ISOPROPYL-4-METHOXYPHENOL tert-Butylhydroquinone 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct,min.95%BIPHEPHOS

6,6μ-[(3,3μ-Di-tert-butyl-5,5μ-dimethoxy-1,1μ-biphenyl-2,2μ-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)

BiPhePhos

6,6'-[[3,3'-Bis(1,1-dimethylethyl)-5,5'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(oxy)]bis[dibenzo[d,f][1,3,2]dioxaphosphepin]

6,6'-[(3,3'-Di-tert-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemi ethyl acetate adduct

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPOS

6,6'-((3,3'-di-tert-butyl-5,5'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine

2,2'-Bis[(1,1'-biphenyl-2,2'-diyl)phosphite]-3,3'-di-tert-butyl-5,5'-dimethoxy-1,1'-biphenyl

6-[2-(2-benzo[d][1,3,2]benzodioxaphosphepin-6-yloxy-3-tert-butyl-5-methoxyphenyl)-6-tert-butyl-4-methoxyphenoxy]benzo[d][1,3,2]benzodioxaphosphepine

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct,BIPHEPHOS

Dibenzo[d,f][1,3,2]dioxaphosphepin, 6,6'-[[3,3'-bis(1,1-dimethylethyl)-5,5'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(oxy)]bis-

)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)

-5,5'-dimethoxy-1,1'-biphenyL

6,6'-[(3,3'-Di-tert-butyL

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diy...

6,6-((3,3-diisopropyl-5,5-dimethoxy-[1,1-biphenyl]-2,2-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine

6,6''-[(3,3''-Di-t-butyl-5,5''-dimethoxy-1,1''-biphenyl-2,2''-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct

6,6'-((3,3'-Di-tert-butyl-5,5'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct,98%

121627-17-6

C46H44O8P2

Aryl Phosphine

Achiral Phosphine