Reactions
ChemicalBook > CAS DataBase List > 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct

Reactions
Product Name
6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct
CAS No.
121627-17-6
Chemical Name
6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct
Synonyms
BiPhePhos;6,6'-[(3,3'-Di-tert-butyL;-5,5'-dimethoxy-1,1'-biphenyL;)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin);6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diy...;2,2'-Bis[(1,1'-biphenyl-2,2'-diyl)phosphite]-3,3'-di-tert-butyl-5,5'-dimethoxy-1,1'-biphenyl;6,6-((3,3-diisopropyl-5,5-dimethoxy-[1,1-biphenyl]-2,2-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine;6,6'-((3,3'-di-tert-butyl-5,5'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine;6,6μ-[(3,3μ-Di-tert-butyl-5,5μ-dimethoxy-1,1μ-biphenyl-2,2μ-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin);6,6'-((3,3'-Di-tert-butyl-5,5'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine
CBNumber
CB01181025
Molecular Formula
C46H44O8P2
Formula Weight
786.78
MOL File
121627-17-6.mol
More
Less

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct Property

Melting point:
128-133 °C
Boiling point:
768.3±60.0 °C(Predicted)
Density 
1.258 at 20℃
storage temp. 
-20°C
form 
Powder
color 
white to off-white
Sensitive 
air sensitive, moisture sensitive
LogP
6 at 30℃ and pH7
CAS DataBase Reference
121627-17-6
More
Less

Safety

WGK Germany 
3
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
699535
Product name
6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)
Purity
97%
Packaging
100mg
Price
$131
Updated
2024/03/01
Sigma-Aldrich
Product number
699535
Product name
6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)
Purity
97%
Packaging
500mg
Price
$238.8
Updated
2024/03/01
Strem Chemicals
Product number
15-0107
Product name
6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS
Packaging
250mg
Price
$98
Updated
2024/03/01
Strem Chemicals
Product number
15-0107
Product name
6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS
Packaging
1g
Price
$343
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0012934
Product name
6,6'-[(3,3'-DI-TERT-BUTYL-5,5'-DIMETHOXY-1,1'-BIPHENYL-2,2'-DIYL)BIS(OXY)]BIS(DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN) HEMI ETHYL ACETATE ADDUCT
Purity
95.00%
Packaging
5MG
Price
$502.18
Updated
2021/12/16
More
Less

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct Chemical Properties,Usage,Production

Reactions

  1. With rhodium forms a highly active catalyst for the hydroformylation of α-olefins.
  2. The hydroformylation of functionalized α-olefins is highly regioselective. The sterically demanding ligand increases n/iso ratio by reducing rhodium interaction with heteroatom functionality.
  3. Ligand used in tandem reaction sequences where high n/iso ratio is desired in the hydroformylation step.

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct Suppliers

Gagri Global IT Services Pvt. Ltd.
Tel
--
Fax
--
Email
info@sapalaorganics.com
Country
India
ProdList
1321
Advantage
58

121627-17-6, 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadductRelated Search:


  • 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct,min.95%BIPHEPHOS
  • 6,6μ-[(3,3μ-Di-tert-butyl-5,5μ-dimethoxy-1,1μ-biphenyl-2,2μ-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)
  • BiPhePhos
  • 6,6'-[[3,3'-Bis(1,1-dimethylethyl)-5,5'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(oxy)]bis[dibenzo[d,f][1,3,2]dioxaphosphepin]
  • 6,6'-[(3,3'-Di-tert-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemi ethyl acetate adduct
  • 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct
  • 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPOS
  • 6,6'-((3,3'-di-tert-butyl-5,5'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine
  • 2,2'-Bis[(1,1'-biphenyl-2,2'-diyl)phosphite]-3,3'-di-tert-butyl-5,5'-dimethoxy-1,1'-biphenyl
  • 6-[2-(2-benzo[d][1,3,2]benzodioxaphosphepin-6-yloxy-3-tert-butyl-5-methoxyphenyl)-6-tert-butyl-4-methoxyphenoxy]benzo[d][1,3,2]benzodioxaphosphepine
  • 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)hemiethylacetateadduct,BIPHEPHOS
  • Dibenzo[d,f][1,3,2]dioxaphosphepin, 6,6'-[[3,3'-bis(1,1-dimethylethyl)-5,5'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(oxy)]bis-
  • )bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepin)
  • -5,5'-dimethoxy-1,1'-biphenyL
  • 6,6'-[(3,3'-Di-tert-butyL
  • 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diy...
  • 6,6-((3,3-diisopropyl-5,5-dimethoxy-[1,1-biphenyl]-2,2-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine
  • 6,6''-[(3,3''-Di-t-butyl-5,5''-dimethoxy-1,1''-biphenyl-2,2''-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct
  • 6,6'-((3,3'-Di-tert-butyl-5,5'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(oxy))didibenzo[d,f][1,3,2]dioxaphosphepine
  • 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct
  • 6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct,98%
  • 121627-17-6
  • C46H44O8P2
  • Aryl Phosphine
  • Achiral Phosphine