ChemicalBook > CAS DataBase List > CERIUM(III) CHLORIDE

CERIUM(III) CHLORIDE

Product Name
CERIUM(III) CHLORIDE
CAS No.
7790-86-5
Chemical Name
CERIUM(III) CHLORIDE
Synonyms
CeCl3;CERIUM CHLORIDE;cerium chloride anhydrous;Cerium trichloride heptahydrate;Cerium(III) trichloride;Anhydrous Cerium Chloride;CEROUS CHLORIDE;trichloroceriuM;Cerium(III) chL;ceriumtrichloride
CBNumber
CB0120131
Molecular Formula
CeCl3
Formula Weight
246.48
MOL File
7790-86-5.mol
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CERIUM(III) CHLORIDE Property

Melting point:
848 °C(lit.)
Boiling point:
1727 °C
Density 
3.97 g/mL at 25 °C(lit.)
Flash point:
1727°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in H2O, ethanol
form 
beads
color 
White to Pale Gray
Specific Gravity
3.92
Water Solubility 
Soluble in water, ethanol, acids and acetone.
Sensitive 
Hygroscopic
Crystal Structure
UCl3 type
crystal system
Six sides
Merck 
14,1997
Space group
P63/m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.7450.7450.43190901200.2073
Stability:
Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.
InChIKey
VYLVYHXQOHJDJL-UHFFFAOYSA-K
CAS DataBase Reference
7790-86-5(CAS DataBase Reference)
EPA Substance Registry System
Cerium chloride (CeCl3) (7790-86-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
UN 3260 8 / PGIII
WGK Germany 
2
RTECS 
FK5075000
F 
3-10
TSCA 
Yes
HS Code 
28461090
Toxicity
LD50 in mice, guinea pigs (mg/kg): 352, 110 i.p. (Graca)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
429406
Product name
Cerium(III) chloride
Purity
anhydrous, beads, 10 mesh, ≥99.99% trace metals basis
Packaging
5g
Price
$158
Updated
2024/03/01
Sigma-Aldrich
Product number
298190
Product name
Cerium(III) chloride
Purity
anhydrous, beads, 10 mesh, 99.9%
Packaging
50g
Price
$439
Updated
2024/03/01
TCI Chemical
Product number
C2058
Product name
Cerium(III) Chloride Anhydrous
Purity
>96.0%(T)
Packaging
5g
Price
$42
Updated
2024/03/01
TCI Chemical
Product number
C2058
Product name
Cerium(III) Chloride Anhydrous
Purity
>96.0%(T)
Packaging
25g
Price
$117
Updated
2024/03/01
Alfa Aesar
Product number
021112
Product name
Cerium(III) chloride, anhydrous, 99.5% (REO)
Packaging
10g
Price
$83.9
Updated
2024/03/01
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CERIUM(III) CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Cerium(III) chloride is a white powder and is used for incandescent gas mantles, spectrography and polymerization of olefins.

Cerium(III) chloride is mainly used as catalyst for petroleum,automobile exhaust catalyst , also used as a raw material for the production of cerium metal and other cerium compounds.

Physical properties

White, very fine powder; hexagonal crystal system; heptahydrate is yellow orthogonal crystal and hygroscopic; density of anhydrous salt 3.97 g/cm3; melts at 817°C; vaporizes at 1,727°C; heptahydrate begins to lose water above 90°C and becomes anhydrous at about 230°C; soluble in water and alcohol; hexahydrate has greater solubility in these solvents.

Uses

Cerium(III) chloride is used in incandescent gas mantles, spectrography and polymerization of olefins. It acts as a Lewis acid and used in Friedel-Crafts alkylation and acylation reactions in organic synthesis. It is used as a precursor for the preparation of other cerium salts, such as cerium(III) trifluoromethanesulfonate.

Production Methods

Cerium(III) chloride is prepared by the reaction of hydrochloric acid with a cerium salt, such as cerium hydroxide or carbonate, followed by crystallization;
Ce(OH)3 + 3HCl → CeCl3 + 3H2O
Ce2(CO3)3 + 6HCl → 2CeCl3 + 3CO2 + 3H2O.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by intravenous, intraperitoneal, and subcutaneous routes. Moderately toxic by ingestion. See also CERIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-

CERIUM(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Rare earth chlorides

Preparation Products

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CERIUM(III) CHLORIDE Suppliers

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View Lastest Price from CERIUM(III) CHLORIDE manufacturers

Shanghai MaiNo material technology Co.Ltd
Product
Cerium Chloride Anhydrous 7790-86-5
Price
US $30.00/kg
Min. Order
1kg
Purity
99.99
Supply Ability
500
Release date
2024-09-03
Hebei Weibang Biotechnology Co., Ltd
Product
CERIUM(III) CHLORIDE 7790-86-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-10-28
Hebei Fengjia New Material Co., Ltd
Product
CERIUM(III) CHLORIDE 7790-86-5
Price
US $3.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10000
Release date
2024-08-08

7790-86-5, CERIUM(III) CHLORIDERelated Search:

Cerium tetrahydroxide CERIUM (III) NITRATE CERIC SULFATE CERIUM(III) SULFATE N-HYDRATE CERIUM Sodium tripolyphosphate Cerium fluoride CEROUS CHLORIDE, HYDRATED AMMONIUM CERIUM(IV) SULFATE CEROUS CARBONATE CERIUM OXIDE CERIUM(III) NITRATE HEXAHYDRATE Cerium dioxide CERIC SULFATE CERIUM(III) PHOSPHATE Ceric ammonium nitrate Sodium Phosphate, Dibasic Calcium silicate Cerium Chloride

  • Cerium(III) chloride, ultra dry, 99.9% (REO)
  • Cerium(iii) chloride, 99.9%, anhydrous, pure
  • Cerium(III) chloride, anhydrous, pure
  • Cerium(III) trichloride
  • Cerium(III) chloride, anhydrous (H2O < 0.5%)
  • CERIUM(III) CHLORIDE, ANHYDROUS (H2O < 0.5%): 99.9% (REO)
  • Cerium(III) chloride,99.9%,pure,anhydrous
  • CERIUM(III) CHLORIDE
  • CERIUM CHLORIDE
  • Cerium trichloride heptahydrate
  • CEROUS CHLORIDE
  • cerium chloride anhydrous
  • "Cerium(III) chloride, anhydrous/99.9%"
  • Cerium(III) chloride,Cerous chloride
  • CeriuM(Ⅲ) chloride
  • SRM Cerium(III) Chloride
  • Cerium (III) chloride, anhydrous (99.9%-Ce) (REO)
  • trichloroceriuM
  • CeriuM(III) chloride, anhydrous,CeCl3
  • CeriuM(III) chloride anhydrous, beads, -10 Mesh, >=99.99% trace Metals basis
  • CeriuM(3+) trichloride
  • CEROUS CHLORIDE, ANHYDROUSCEROUS CHLORIDE, ANHYDROUSCEROUS CHLORIDE, ANHYDROUSCEROUS CHLORIDE, ANHYDROUS
  • CeCl3
  • Cerium chloride (CeCl3)
  • ceriumchloride(cecl3)
  • ceriumtrichloride
  • Cerium Chloride (Mohrs Salt)
  • CERIUM II CHLORIDE
  • Cerium(Ⅲ) chloride heptahydrate
  • CERIUM(III) CHLORIDE, 99.9%
  • Cerium(III) chloride, anhydrous, beads, #10 mesh, 99.99+% metals basis
  • CEROUS CHLORIDE ANHYDROUS
  • CERIUM(III) CHLORIDE, ANHYDROUS, BEADS, -10 MESH, 99.9+%
  • CERIUM(III) CHLORIDE, ANHYDROUS, BEADS, -10 MESH, 99+%
  • Cerium(III)chloride,anhydrous,99.5%(REO)
  • Cerium(III) chloride, anhydrous, pure, 99.9%
  • Cerium(III)chloride,anhydrous(H2O<0.5%)(99.9%-Ce)(REO)
  • cerium(iii) chloride, ultra dry
  • Cerium(III) chloride, anhydrous, 99.5% trace rare earth metals basis
  • Cerium(III) chloride, anhydrous, ampuled under argon, 99.9% trace rare earth metals basis
  • Cerium(III) chloride, 99.9%, anhydrous
  • Anhydrous Cerium Chloride
  • Cerium(III) chloride, Anhdrous
  • Cerium(III) chloride, ultra dry, (REO)
  • Cerium(III) chL
  • Cerium(III) chloride beads
  • Cerium(III) Chloride Anhydrous&gt
  • Cerous chloride,anhydrous,99.99%
  • Cerium(III) chloride anhydrous, beads, 10 mesh, ≥99.99%
  • Cerium(III) chloride, anhydrous, 99.5%
  • Cerium Chloride Andydrous
  • CERAMICS-AEium(III) chloride
  • 7790-86-5
  • 8618-55-8
  • CeC13
  • Ce (Cerium) Compounds
  • Classes of Metal Compounds
  • Transition Metal Compounds