BENZAL CHLORIDE
- Product Name
- BENZAL CHLORIDE
- CAS No.
- 98-87-3
- Chemical Name
- BENZAL CHLORIDE
- Synonyms
- Benzyl dichloride;BENZYLIDENE CHLORIDE;(DICHLOROMETHYL)BENZENE;benzal;Chlorobenzal;Benzylene chloride;A,A-DICHLOROTOLUENE;NSC 7915;ai-28597;chlorobenza
- CBNumber
- CB0124548
- Molecular Formula
- C7H6Cl2
- Formula Weight
- 161.03
- MOL File
- 98-87-3.mol
BENZAL CHLORIDE Property
- Melting point:
- -16 °C
- Boiling point:
- 207 °C
- Density
- 1.254
- vapor pressure
- 60Pa at 25℃
- refractive index
- 1.5500
- Flash point:
- 92°C
- Water Solubility
- Insoluble in water
- solubility
- Chloroform (Soluble), Methanol (Slightly)
- form
- clear liquid
- color
- Very refractive liquid
- Merck
- 14,1057
- BRN
- 1099407
- Dielectric constant
- 6.9（20℃）
- Stability:
- Stable, but moisture sensitive. Combustible. Incompatible with strong bases, strong oxidizing agents, most metals. Readily hydrolyzes in acidic or basic conditions.
- LogP
- 2.97
- CAS DataBase Reference
- 98-87-3(CAS DataBase Reference)
- IARC
- 2A (Vol. 29, Sup 7, 71) 1999
- EPA Substance Registry System
- Benzal chloride (98-87-3)
Safety
- Hazard Codes
- T
- Risk Statements
- 22-23-37/38-40-41
- Safety Statements
- 23-26-36/37/39-45-38-36/37
- RIDADR
- 1886
- RTECS
- CZ5075000
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29036990
- Hazardous Substances Data
- 98-87-3(Hazardous Substances Data)
- Toxicity
- LD50 orl-rat: 3249 mg/kg NTIS** PB214-270
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
H331Toxic if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 251046
- Product name
- α,α-Dichlorotoluene
- Purity
- 95%
- Packaging
- 25g
- Price
- $62.8
- Updated
- 2023/06/20
- Product number
- B1414
- Product name
- Benzal Chloride
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $33
- Updated
- 2023/06/20
- Product number
- B1414
- Product name
- Benzal Chloride
- Purity
- >95.0%(GC)
- Packaging
- 100g
- Price
- $82
- Updated
- 2023/06/20
- Product number
- B1414
- Product name
- Benzal Chloride
- Purity
- >95.0%(GC)
- Packaging
- 500g
- Price
- $170
- Updated
- 2021/12/16
- Product number
- D438310
- Product name
- α,α-Dichlorotoluene
- Packaging
- 5g
- Price
- $45
- Updated
- 2021/12/16
BENZAL CHLORIDE Chemical Properties,Usage,Production
Description
Benzal chloride (dichloromethylbenzene, a,adichlorotoluene, benzylidene chloride) is produced exclusively by the side-chain chlorination of toluene. It was first synthesized in 1848 by A. CAHOURS, by using the reaction of PCl5 with benzaldehyde. Almost the sole application of benzal chloride is in the production of benzaldehyde.
Chemical Properties
colourless oily liquid
Chemical Properties
Benzal chloride is a combustible, fuming, colorless, oily liquid; fumes on exposure to air. Faint, pungent odor.
Physical properties
Benzal chloride is a liquid which fumes in moist air and which has a pungent odor and a strong irritant effect on the mucous membranes and eyes.Benzal chloride is freely soluble in alcohol, ether, chloroform, and carbon tetrachloride, but only slightly soluble in water (0.05 g/L at 5 ℃; 0.25 g/L at 39 ℃). The solubility of chlorine in 100 g of benzal chloride is 6.2 g at 30 ℃, 4.3 g at 50 ℃, 1.5 g at 100 ℃.
Uses
manufacture of benzaldehyde, cinnamic acid.
Uses
α,α-Dichlorotoluene has been useds as initiator during the atom transfer radical polymerization (ATRP) of styrene and methyl methacrylate.
Definition
ChEBI: Benzal chloride is a member of benzenes.
Synthesis Reference(s)
The Journal of Organic Chemistry, 15, p. 795, 1950 DOI: 10.1021/jo01150a012
Tetrahedron Letters, 9, p. 4951, 1968
General Description
A colorless oily liquid with a faint aromatic odor. Insoluble in water and denser than water. Strongly irritates skin and eyes. Used to manufacture dyes.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
BENZAL CHLORIDE is incompatible with strong oxidizers and strong bases. BENZAL CHLORIDE readily hydrolyzes under acid or alkaline conditions. BENZAL CHLORIDE reacts with metals (except nickel and lead). .
Hazard
Strong irritant and lachrymator. Probable carcinogen.
Health Hazard
Acute: vapors are highly irritating to eyes. May be fatal if inhaled, swallowed, or absorbed through skin.
Fire Hazard
Fire may produce irritating or poisonous gases. Runoff from fire control water may give off poisonous gases and may cause pollution. Cylinder may explode in the heat of fire. Reacts with water to release hydrochloric acid.
Safety Profile
Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by inhalation. Moderately toxic by ingestion. A strong irritant and lachrymator. Causes central nervous system depression. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, AROMATIC.
Potential Exposure
Benzal chloride is used almost exclusively for the manufacture of benzaldehyde. It can also be used to prepare cinnamic acid and benzoyl chloride.
First aid
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 24 48 h afterbreathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor orauthorized paramedic may consider administering a corticosteroid spray
storage
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Store in tightly closed containers in a cool, well-ventilated area away from oxidizers,strong acids, flammable materials, sources fire as this material is combustible. Sources of ignition, such as smokingand open flames, are prohibited where this chemical isused, handled, or stored in a manner that could create apotential fire or explosion hazard.
Shipping
UN1886 Benzylidene chloride, Hazard class 6.1; Label 6.1—Poisonous materials.
Incompatibilities
May form explosive mixture with air. Reacts with water, air, or heat, forming fumes of hydrochloric acid. Reacts (possibly violently) with acids, bases, strong oxidizers; many metals; potassium, sodium, aluminum. Attacks plastics and coatings.
Waste Disposal
Incineration @ 816 C, 0.5 second minimum for primary combustion; 1204 C, 1.0 second for secondary combustion; elemental chlorine formation may be alleviated through injection of steam or methane into the combustion process.