ChemicalBook > CAS DataBase List > 3-Phenoxybenzaldehyde

3-Phenoxybenzaldehyde

Product Name
3-Phenoxybenzaldehyde
CAS No.
39515-51-0
Chemical Name
3-Phenoxybenzaldehyde
Synonyms
3-PHENOXYBENZALDEHYDE;META PHENOXY BENZALDEHYE;3-PhenoxybenzaL;AKOS BBS-00003181;Phenoxybenzaldehyde;3-Phenoxy-benzaldehy;5-Phenoxybenzaldehyde;3-phenoxy-benzaldehyd;3-FORMYLDIPHENYL ETHER;M-PHENOXY BENZALDEHYDE
CBNumber
CB1697209
Molecular Formula
C13H10O2
Formula Weight
198.22
MOL File
39515-51-0.mol
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3-Phenoxybenzaldehyde Property

Melting point:
13 °C
Boiling point:
169-169.5 °C11 mm Hg(lit.)
Density 
1.147 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.595(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform, Dichloromethane (Slightly), Methanol (Slightly)
form 
Oil
color 
Colourless to Pale Yellow
Sensitive 
Air Sensitive
BRN 
511662
InChIKey
MRLGCTNJRREZHZ-UHFFFAOYSA-N
CAS DataBase Reference
39515-51-0(CAS DataBase Reference)
EPA Substance Registry System
Benzaldehyde, 3-phenoxy- (39515-51-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-26
Safety Statements 
23-24/25-45-38-28
RIDADR 
UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany 
3
RTECS 
CU7560200
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29124900
Toxicity
LD ipr-mus: >500 mg/kg JAFCAU26,954,78
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
191752
Product name
3-Phenoxybenzaldehyde
Purity
98%
Packaging
5g
Price
$40
Updated
2024/03/01
Sigma-Aldrich
Product number
191752
Product name
3-Phenoxybenzaldehyde
Purity
98%
Packaging
25g
Price
$40.2
Updated
2024/03/01
TCI Chemical
Product number
P0960
Product name
3-Phenoxybenzaldehyde
Purity
>97.0%(GC)
Packaging
25g
Price
$84
Updated
2024/03/01
TCI Chemical
Product number
P0960
Product name
3-Phenoxybenzaldehyde
Purity
>97.0%(GC)
Packaging
500g
Price
$694
Updated
2024/03/01
TRC
Product number
P297800
Product name
3-Phenoxybenzaldehyde
Packaging
2.5g
Price
$65
Updated
2021/12/16
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3-Phenoxybenzaldehyde Chemical Properties,Usage,Production

Chemical Properties

clear light yellow to amber liquid, insoluble in water, soluble in alcohol, benzene, toluene and other organic solvents.

Uses

3-phenoxybenzaldehyde is an important intermediate for the synthesis of pyrethroid pesticides phenothrin, cypermethrin, deltamethrin,fenvalerate, fenpropathrin, flucythrinate, cyhalothrin, etc.

Preparation

Synthesis of 3-Phenoxybenzaldehyde: 3-phenoxybenzoic acid is generated by catalytic oxidation of 3-phenoxytoluene, followed by electrolytic reduction to obtain Phenoxybenzyl alcohol , and then selective oxidation with sodium hypochlorite to obtain 3-Phenoxybenzaldehyde.

Production Methods

3-Phenoxybenzaldehyde is prepared by adding, at a relatively low temperature, a mixture of a 3-phenoxybenzyl halide and a 3-phenoxybenzal halide to a mixture of hexamethylenetetramine, acetic acid and water, the amounts of the water and acid bearing certain relationships to the amount of the mixture of halides, then heating the resulting mixture to a specified temperature level and maintaining it at that level for a specified period of time.
https://patents.google.com/patent/US4229380A/en

General Description

Enantioselective autoinduction during asymmetric hydrocyanation of 3-phenoxybenzaldehyde catalyzed by cyclo[(R)-phenylalanyl-(R)-histidyl] has been investigated. It undergoes hydrogenation catalyzed by Au/Pt bimetallic core/shell nanoparticles to yield 3-phenoxyphenyl methanol.

Safety Profile

Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.

Degradation

3-Phenoxybenzoic acid(3-PBA) and 3-phenoxybenzaldehyde are the most common intermediates in the degradation pathways of Type Il pyrethroids by bacteria, except the cyfluthrin degradation in Brevibacterium aureum DG-12, the beta-cyfluthrin degradation in Pseudomonas stutzeri S1, and the fenpropathrin degradation in Clostridium sp. ZP3(Chen et al.2013a; Saikia et al.2005;Zhang et al.2011b).

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3-Phenoxybenzaldehyde Suppliers

Shaoxing Jiufu New Material Technology Co., LTD
Tel
0575-87095566 18067860628
Email
sales@sxjiufu.com
Country
China
ProdList
256
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58
Shangqiu Ladybug Network Technology Co., LTD
Tel
0370-2059268 15672839268
Fax
03702782809
Email
2352713635@qq.com
Country
China
ProdList
4205
Advantage
58
Tai 'an Huanyu Chemical Co., LTD
Tel
13176825516
Email
78995114@qq.com
Country
China
ProdList
32
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15848
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
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81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
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61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35906
Advantage
56
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View Lastest Price from 3-Phenoxybenzaldehyde manufacturers

Hebei Duling International Trade Co. LTD
Product
3-Phenoxybenzaldehyde 39515-51-0
Price
US $38.50/L
Min. Order
1L
Purity
98%
Supply Ability
800MT/MONTH
Release date
2022-10-21
Hebei Guanlang Biotechnology Co., Ltd.
Product
3-Phenoxybenzaldehyde 39515-51-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-10-20
Henan Bao Enluo International TradeCo.,LTD
Product
3-Phenoxy-benzaldehyde 39515-51-0
Price
US $100.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500t/month
Release date
2023-06-27

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