3-Phenoxybenzaldehyde

ChemicalBook > CAS DataBase List > 3-Phenoxybenzaldehyde

3-Phenoxybenzaldehyde

Product Name: 3-Phenoxybenzaldehyde
CAS No.: 39515-51-0
Chemical Name: 3-Phenoxybenzaldehyde
Synonyms: 3-PHENOXYBENZALDEHYDE;META PHENOXY BENZALDEHYE;3-PhenoxybenzaL;AKOS BBS-00003181;Phenoxybenzaldehyde;3-Phenoxy-benzaldehy;5-Phenoxybenzaldehyde;3-phenoxy-benzaldehyd;3-FORMYLDIPHENYL ETHER;M-PHENOXY BENZALDEHYDE
CBNumber: CB1697209
Molecular Formula: C13H10O2
Formula Weight: 198.22
MOL File: 39515-51-0.mol

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3-Phenoxybenzaldehyde Property

Melting point:: 13 °C
Boiling point:: 169-169.5 °C11 mm Hg(lit.)
Density: 1.147 g/mL at 25 °C(lit.)
refractive index: n20/D 1.595(lit.)
Flash point:: >230 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform, Dichloromethane (Slightly), Methanol (Slightly)
form: Oil
color: Colourless to Pale Yellow
Sensitive: Air Sensitive
BRN: 511662
InChIKey: MRLGCTNJRREZHZ-UHFFFAOYSA-N
CAS DataBase Reference: 39515-51-0(CAS DataBase Reference)
EPA Substance Registry System: Benzaldehyde, 3-phenoxy- (39515-51-0)

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Safety

Hazard Codes: Xn
Risk Statements: 22-26
Safety Statements: 23-24/25-45-38-28
RIDADR: UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany: 3
RTECS: CU7560200
TSCA: Yes
HazardClass: 6.1
PackingGroup: II
HS Code: 29124900
Toxicity: LD ipr-mus: >500 mg/kg JAFCAU26,954,78

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 191752
Product name: 3-Phenoxybenzaldehyde
Purity: 98%
Packaging: 5g
Price: $40
Updated: 2024/03/01

Sigma-Aldrich

Product number: 191752
Product name: 3-Phenoxybenzaldehyde
Purity: 98%
Packaging: 25g
Price: $40.2
Updated: 2024/03/01

TCI Chemical

Product number: P0960
Product name: 3-Phenoxybenzaldehyde
Purity: >97.0%(GC)
Packaging: 25g
Price: $84
Updated: 2024/03/01

TCI Chemical

Product number: P0960
Product name: 3-Phenoxybenzaldehyde
Purity: >97.0%(GC)
Packaging: 500g
Price: $694
Updated: 2024/03/01

TRC

Product number: P297800
Product name: 3-Phenoxybenzaldehyde
Packaging: 2.5g
Price: $65
Updated: 2021/12/16

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3-Phenoxybenzaldehyde Chemical Properties,Usage,Production

Chemical Properties

clear light yellow to amber liquid, insoluble in water, soluble in alcohol, benzene, toluene and other organic solvents.

Uses

3-phenoxybenzaldehyde is an important intermediate for the synthesis of pyrethroid pesticides phenothrin, cypermethrin, deltamethrin,fenvalerate, fenpropathrin, flucythrinate, cyhalothrin, etc.

Preparation

Synthesis of 3-Phenoxybenzaldehyde: 3-phenoxybenzoic acid is generated by catalytic oxidation of 3-phenoxytoluene, followed by electrolytic reduction to obtain Phenoxybenzyl alcohol , and then selective oxidation with sodium hypochlorite to obtain 3-Phenoxybenzaldehyde.

Production Methods

3-Phenoxybenzaldehyde is prepared by adding, at a relatively low temperature, a mixture of a 3-phenoxybenzyl halide and a 3-phenoxybenzal halide to a mixture of hexamethylenetetramine, acetic acid and water, the amounts of the water and acid bearing certain relationships to the amount of the mixture of halides, then heating the resulting mixture to a specified temperature level and maintaining it at that level for a specified period of time.
https://patents.google.com/patent/US4229380A/en

General Description

Enantioselective autoinduction during asymmetric hydrocyanation of 3-phenoxybenzaldehyde catalyzed by cyclo[(R)-phenylalanyl-(R)-histidyl] has been investigated. It undergoes hydrogenation catalyzed by Au/Pt bimetallic core/shell nanoparticles to yield 3-phenoxyphenyl methanol.

Safety Profile

Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.

Degradation

3-Phenoxybenzoic acid(3-PBA) and 3-phenoxybenzaldehyde are the most common intermediates in the degradation pathways of Type Il pyrethroids by bacteria, except the cyfluthrin degradation in Brevibacterium aureum DG-12, the beta-cyfluthrin degradation in Pseudomonas stutzeri S1, and the fenpropathrin degradation in Clostridium sp. ZP3(Chen et al.2013a; Saikia et al.2005;Zhang et al.2011b).

3-Phenoxybenzaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

Esfenvalerate Cyhalothrin 3-PHENOXYBENZALDEHYDE CYANOHYDRIN alpha-Cypermethrin CYCLOPROTHRIN Fenpropathrin Deltamethrin VALERATE Fenvalerate 3-Phenoxybenzyl alcohol brofluthrinate 3-(4-Bromophenoxy)Benzaldehyde Cypermethrin

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View Lastest Price from 3-Phenoxybenzaldehyde manufacturers

Hebei Duling International Trade Co. LTD

Product: 3-Phenoxybenzaldehyde 39515-51-0
Price: US $38.50/L
Min. Order: 1L
Purity: 98%
Supply Ability: 800MT/MONTH
Release date: 2022-10-21

Hebei Guanlang Biotechnology Co., Ltd.

Product: 3-Phenoxybenzaldehyde 39515-51-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2022-10-20

Henan Bao Enluo International TradeCo.，LTD

Product: 3-Phenoxy-benzaldehyde 39515-51-0
Price: US $100.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 500t/month
Release date: 2023-06-27

39515-51-0, 3-PhenoxybenzaldehydeRelated Search:

4-Hydroxybenzaldehyde 3,5-Dimethoxybenzaldehyde 2,5-Dimethoxybenzaldehyde o-Anisaldehyde 3-(Trifluoromethyl)benzaldehyde 3,4,5-Trimethoxybenzaldehyde 3-Phenoxybenzyl alcohol Benzaldehyde p-Anisaldehyde m-Anisyl alcohol Veratraldehyde 2-Nitrobenzaldehyde 2,3,4-Trimethoxybenzaldehyde 4-Dimethylaminobenzaldehyde 4-Fluoro-3-phenoxybenzaldehyde sodium benzaldehyde-o-sulfonate 3-[3-(TRIFLUOROMETHYL)PHENOXY]BENZALDEHYDE 3-(4-METHOXYPHENOXY)BENZALDEHYDE

M-PHENOXY BENZALDEHYDE

3-phenoxy-benzaldehyd

3-PHENOXYBENZALDEHYDE

3-FORMYLDIPHENYL ETHER

AKOS BBS-00003181

m-Phenoxybenzaldehyde 3-Phenoxybenzaldehyde

Benzaldehyde,3-phenoxy-

m-(phenyloxy)benzaldehyde

5-Phenoxybenzaldehyde

3-PHENOXYBENZALDEHYDE FOR SYNTHESIS

3-Phenoxybenzaldehyde,97%

3-Phenoxy-benzaldehy

(1,1'-Oxybisbebzene)-3-carbaldehyde

3-Phenoxybenzaldehyde, 97% 5GR

Permethrin EP Impurity D

Permethrin Impurity 4（Permethrin EP Impurity D）

500g of 3-Phenoxybenzaldehyde

Permethrin EP Impurity D (3-Phenoxybenzyl Aldehyde)

3-Phenoxy-benZHldehyde

3-Phenoxybenzaldehyde&gt

3-PhenoxybenzaL

META PHENOXY BENZALDEHYE

3-Phenoxy-benzaldehyde(meta-Phenoxy-benzaldehyde)

3-Phenoxybenzyl Aldehyde

Phenoxybenzaldehyde

39515-51-0

9515-51-0

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