ChemicalBook > CAS DataBase List > 3-Phenoxybenzyl alcohol
3-Phenoxybenzyl alcohol
- Product Name
- 3-Phenoxybenzyl alcohol
- CAS No.
- 13826-35-2
- Chemical Name
- 3-Phenoxybenzyl alcohol
- Synonyms
- 3-PBA;(3-Phenoxyphenyl)methanol;Meta Phenoxy Benzal Alcohol;mpbd;3-Phenoxybenzy;3-phenoxybenzyl;RARECHEM AL BD 0058;3-PhenoxyBenzalcohol;PermethrinEPImpurity;m-Phenoxy Benzalcohol
- CBNumber
- CB7329070
- Molecular Formula
- C13H12O2
- Formula Weight
- 200.23
- MOL File
- 13826-35-2.mol
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3-Phenoxybenzyl alcohol Property
- Melting point:
- 4-7°C
- Boiling point:
- 135-140 °C/0.1 mmHg (lit.)
- Density
- 1.149 g/mL at 25 °C (lit.)
- vapor pressure
- 0.1 mm Hg ( 37.7 °C)
- refractive index
- n20/D 1.591(lit.)
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Solid or Liquid
- pka
- 14.19±0.10(Predicted)
- color
- White or clear colorless
- Water Solubility
- Insoluble
- BRN
- 475312
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- LogP
- 2.797 at 25℃
- CAS DataBase Reference
- 13826-35-2(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenemethanol, 3-phenoxy-(13826-35-2)
- EPA Substance Registry System
- 3-Phenoxybenzenemethanol (13826-35-2)
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Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22
- Safety Statements
- 26-36/37-29
- RIDADR
- UN 3082 9 / PGIII
- WGK Germany
- 3
- RTECS
- DP0775400
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 29062990
- Toxicity
- mouse,LD50,intraperitoneal,575mg/kg (575mg/kg),Journal of Agricultural and Food Chemistry. Vol. 25, Pg. 9, 1977.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 190284
- Product name
- 3-Phenoxybenzyl alcohol
- Purity
- 98%
- Packaging
- 25g
- Price
- $94.7
- Updated
- 2025/07/31
TCI Chemical
- Product number
- P0979
- Product name
- 3-Phenoxybenzyl Alcohol
- Packaging
- 25g
- Price
- $66
- Updated
- 2025/07/31
TCI Chemical
- Product number
- P0979
- Product name
- 3-Phenoxybenzyl Alcohol
- Packaging
- 500g
- Price
- $410
- Updated
- 2025/07/31
TRC
- Product number
- P228050
- Product name
- 3-Phenoxybenzyl Alcohol
- Packaging
- 5g
- Price
- $55
- Updated
- 2021/12/16
Apolloscientific
- Product number
- OR18354
- Product name
- (3-Phenoxyphenyl)methanol
- Packaging
- 100g
- Price
- $56
- Updated
- 2021/12/16
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3-Phenoxybenzyl alcohol Chemical Properties,Usage,Production
Chemical Properties
colourless liquid
Uses
3-Phenoxybenzyl alcohol has been used in the synthesis of 3-phenoxylbenzyl β-D-glucuronide.
Definition
ChEBI: A member of the class of benzyl alcohols that is benzyl alcohol bearing a phenoxy substituent at C-3. It is a metbaolite of the insecticide permethrin.
Flammability and Explosibility
Non flammable
Synthesis
39515-51-0
13826-35-2
M-phenoxybenzaldehyde (5 g, 25.22 mmol) was dissolved in anhydrous methanol (60 mL), cooled to 0 °C, and sodium borohydride (1.14 g, 30.26 mmol) was added in batches. The reaction mixture was stirred at room temperature for 1.5 hours and then concentrated under reduced pressure. The resulting residue was quenched with saturated aqueous ammonium chloride solution (50 mL) and extracted with ethyl acetate (3 x 50 mL). The organic phases were combined, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give 3-phenoxybenzyl alcohol (5 g, 99% yield). The product was analyzed by LCMS showing [M+H]+ m/z 183.0, retention time 5.4 min, and purity 93.1% (area normalization method).
References
[1] Patent: WO2015/130905, 2015, A1. Location in patent: Paragraph 00209
[2] Tetrahedron Letters, 2015, vol. 56, # 46, p. 6460 - 6462
[3] Journal of Organic Chemistry, 2004, vol. 69, # 5, p. 1492 - 1496
[4] Patent: WO2018/42461, 2018, A1. Location in patent: Page/Page column 7; 8
[5] Patent: US4366325, 1982, A
3-Phenoxybenzyl alcohol Preparation Products And Raw materials
Raw materials
3-Phenoxybenzoic acid
3-Phenoxybenzaldehyde
Ethanol
Potassium hydroxide
Formaldehyde
Benzene
Lithium Aluminum Hydride
Sodium formate
Sodium hydroxide
Benzyl benzoate
3-PHENOXYBENZYL CHLORIDE
Preparation Products
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3-Phenoxybenzyl alcohol Suppliers
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View Lastest Price from 3-Phenoxybenzyl alcohol manufacturers
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- 3-Phenoxybenzyl alcohol 13826-35-2
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-19
Hebei Zhuanglai Chemical Trading Co Ltd
- Product
- 3-Phenoxybenzyl alcohol 13826-35-2
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 ton
- Release date
- 2024-12-16
Henan Aochuang Chemical Co.,Ltd.
- Product
- 3-Phenoxybenzyl alcohol 13826-35-2
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-14
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