Triphenylmethanol
Luminescence performance- Product Name
- Triphenylmethanol
- CAS No.
- 76-84-6
- Chemical Name
- Triphenylmethanol
- Synonyms
- TRT-OH;TRIPHENYLCARBINOL;TRITYL ALCOHOL;Tritanol;Triphenylmethanol, (Triphenyl carbinol;Ih-Tetrazole;tirphenylmethanol;Triphenylmethanol ,99%;Triphenylmethyl alcohol;Triphenylmethanol(76-84-6)
- CBNumber
- CB3335936
- Molecular Formula
- C19H16O
- Formula Weight
- 260.33
- MOL File
- 76-84-6.mol
Triphenylmethanol Property
- Melting point:
- 160-163 °C (lit.)
- Boiling point:
- 360 °C (lit.)
- Density
- d40 1.199
- refractive index
- 1.6220 (estimate)
- Flash point:
- 360-380°C
- storage temp.
- 2-8°C
- solubility
- dioxane: 0.1 g/mL, clear
- pka
- 12.73±0.29(Predicted)
- form
- Fine Crystalline Powder
- color
- White to light yellow
- Water Solubility
- INSOLUBLE
- Merck
- 14,9739
- BRN
- 1460837
- Stability:
- Stable. Combustible. Incompatible with oxidizing agents, acids, acid chlorides, acid anhydrides.
- CAS DataBase Reference
- 76-84-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenemethanol, «alpha»,«alpha»-diphenyl-(76-84-6)
- EPA Substance Registry System
- Benzenemethanol, .alpha.,.alpha.-diphenyl- (76-84-6)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 38-36/37/38
- Safety Statements
- 22-24/25-36-26
- WGK Germany
- 3
- TSCA
- Yes
- HS Code
- 29062900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 8.21196
- Product name
- Triphenylmethanol
- Purity
- for synthesis
- Packaging
- 50g
- Price
- $75.7
- Updated
- 2024/03/01
- Product number
- 8.21196
- Product name
- Triphenylmethanol
- Purity
- for synthesis
- Packaging
- 250g
- Price
- $201
- Updated
- 2024/03/01
- Product number
- 134848
- Product name
- Triphenylmethanol
- Purity
- 97%
- Packaging
- 50g
- Price
- $68.9
- Updated
- 2024/03/01
- Product number
- 134848
- Product name
- Triphenylmethanol
- Purity
- 97%
- Packaging
- 250g
- Price
- $252
- Updated
- 2024/03/01
- Product number
- T0516
- Product name
- Triphenylmethanol
- Purity
- >99.0%(GC)
- Packaging
- 25g
- Price
- $38
- Updated
- 2024/03/01
Triphenylmethanol Chemical Properties,Usage,Production
Luminescence performance
Triphenylmethanol (TPOH) is a non-fluorescent compound that emits strong fluorescence in an aggregate state or on a solid surface after irradiation by UV light at 254 nm (UV1). Interestingly, the photo-induced fluorescence of TPOH was quenched when irradiated by UV light at a longer wavelength of 365 nm (UV2) and further repeatable on and off by UV1 and UV2, respectively. The reversible activation and deactivation of fluorescence at a solid surface could be repeatable at least 5 times. TPOH is thus applied for rewritable photopatterning tuned by UV light[1].
Chemical Properties
white powder or colorless trisolated crystals. Soluble in alcohol, ether and benzene, dark yellow when dissolved in concentrated sulfuric acid, colorless when dissolved in glacial acetic acid, insoluble in water and petroleum ether. Distilled at 360-380℃ without decomposition.
Uses
Triphenylmethanol is used as a reagent in the research laboratory. It acts as an intermediate in the production of the commercially useful triarylmethane dyes. It is used in the preparation of triphenylmethane. It is also used as an antiproliferative agent. Further, it is used in the preparation of two-electron reduction product of pyrylogen. In addition to this, it reacts with triphenylphosphine oxide to form a 1:1 molecular complex. It serves as a specific clathrate host for methanol and dimethyl sulphoxide and forms clathrate inclusion complexes.
Triphenylmethanol was used in the synthesis of of the two-electron reduction product of pyrylogen.
It undergoes reduction to triphenylmethane by 9, 10-dihydro-10-methylacridine in the presence of perchloric acid.
Uses
Triphenylmethanol (Zidovudine EP Impurity D) is a triaryl methane derivative as antiproliferative agent.
Preparation
Triphenylmethanol synthesis: Triphenylmethanol was prepared by the action of benzene with carbon tetrachloride in the presence of Aluminum chloride, followed by acidification and hydrolysis.
Triphenylmethanol can also be prepared by the reaction of phenylmagnesium bromide with methyl benzoate (instead of benzophenone).
Synthesis of Triphenylmethanol
Reactions
The first one is the formation of the triphenylmethyl bromide from the reaction of triphenylmethanol with hydrobromic acid.
The second reaction is the formation of an ether from the reaction of triphenylmethanol with methanol in acidic conditions.
Synthesis Reference(s)
Organic Syntheses, Coll. Vol. 3, p. 839, 1955
The Journal of Organic Chemistry, 57, p. 4555, 1992 DOI: 10.1021/jo00042a044
General Description
Triphenylmethanol forms 1:1 molecular complex with triphenylphosphine oxide. It is a specific clathrate host for methanol and dimethyl sulphoxide and forms clathrate inclusion complexes. It undergoes reduction to triphenylmethane by 9, l0-dihydro-10-methylacridine in the presence of perchloric acid.
Purification Methods
Crystallise the carbinol from EtOH, MeOH, CCl4 (4mL/g), *benzene, hexane or pet ether (b 60-70o). Dry it at 90o. [Ohwada et al. J Am Chem Soc 108 3029 1986, Beilstein 6 IV 5014.]
References
[1] Zheng, Yue et al. “Photoactivatable aggregation-induced emission of triphenylmethanol?.” Chemical Communications 81 (2017): 11130–11133.
Triphenylmethanol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Triphenylmethanol manufacturers
- Product
- Triphenylmethanol 76-84-6
- Price
- US $70.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-06-05
- Product
- Triphenylmethanol 76-84-6
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-21
- Product
- Triphenylmethanol 76-84-6
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-22