ChemicalBook > CAS DataBase List > 3-Phenoxybenzyl alcohol

3-Phenoxybenzyl alcohol

Product Name
3-Phenoxybenzyl alcohol
CAS No.
13826-35-2
Chemical Name
3-Phenoxybenzyl alcohol
Synonyms
3-PBA;(3-Phenoxyphenyl)methanol;Meta Phenoxy Benzal Alcohol;mpbd;3-Phenoxybenzy;3-phenoxybenzyl;RARECHEM AL BD 0058;3-PhenoxyBenzalcohol;PermethrinEPImpurity;m-Phenoxy Benzalcohol
CBNumber
CB7329070
Molecular Formula
C13H12O2
Formula Weight
200.23
MOL File
13826-35-2.mol
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3-Phenoxybenzyl alcohol Property

Melting point:
4-7°C
Boiling point:
135-140 °C/0.1 mmHg (lit.)
Density 
1.149 g/mL at 25 °C (lit.)
vapor pressure 
0.1 mm Hg ( 37.7 °C)
refractive index 
n20/D 1.591(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Solid or Liquid
pka
14.19±0.10(Predicted)
color 
White or clear colorless
Water Solubility 
Insoluble
BRN 
475312
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
LogP
2.797 at 25℃
CAS DataBase Reference
13826-35-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanol, 3-phenoxy-(13826-35-2)
EPA Substance Registry System
3-Phenoxybenzenemethanol (13826-35-2)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22
Safety Statements 
26-36/37-29
RIDADR 
UN 3082 9 / PGIII
WGK Germany 
3
RTECS 
DP0775400
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29062990
Toxicity
mouse,LD50,intraperitoneal,575mg/kg (575mg/kg),Journal of Agricultural and Food Chemistry. Vol. 25, Pg. 9, 1977.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
190284
Product name
3-Phenoxybenzyl alcohol
Purity
98%
Packaging
25g
Price
$94.7
Updated
2025/07/31
TCI Chemical
Product number
P0979
Product name
3-Phenoxybenzyl Alcohol
Packaging
25g
Price
$66
Updated
2025/07/31
TCI Chemical
Product number
P0979
Product name
3-Phenoxybenzyl Alcohol
Packaging
500g
Price
$410
Updated
2025/07/31
TRC
Product number
P228050
Product name
3-Phenoxybenzyl Alcohol
Packaging
5g
Price
$55
Updated
2021/12/16
Apolloscientific
Product number
OR18354
Product name
(3-Phenoxyphenyl)methanol
Packaging
100g
Price
$56
Updated
2021/12/16
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3-Phenoxybenzyl alcohol Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

3-Phenoxybenzyl alcohol has been used in the synthesis of 3-phenoxylbenzyl β-D-glucuronide.

Definition

ChEBI: A member of the class of benzyl alcohols that is benzyl alcohol bearing a phenoxy substituent at C-3. It is a metbaolite of the insecticide permethrin.

Flammability and Explosibility

Non flammable

Synthesis

39515-51-0

13826-35-2

M-phenoxybenzaldehyde (5 g, 25.22 mmol) was dissolved in anhydrous methanol (60 mL), cooled to 0 °C, and sodium borohydride (1.14 g, 30.26 mmol) was added in batches. The reaction mixture was stirred at room temperature for 1.5 hours and then concentrated under reduced pressure. The resulting residue was quenched with saturated aqueous ammonium chloride solution (50 mL) and extracted with ethyl acetate (3 x 50 mL). The organic phases were combined, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give 3-phenoxybenzyl alcohol (5 g, 99% yield). The product was analyzed by LCMS showing [M+H]+ m/z 183.0, retention time 5.4 min, and purity 93.1% (area normalization method).

References

[1] Patent: WO2015/130905, 2015, A1. Location in patent: Paragraph 00209
[2] Tetrahedron Letters, 2015, vol. 56, # 46, p. 6460 - 6462
[3] Journal of Organic Chemistry, 2004, vol. 69, # 5, p. 1492 - 1496
[4] Patent: WO2018/42461, 2018, A1. Location in patent: Page/Page column 7; 8
[5] Patent: US4366325, 1982, A

3-Phenoxybenzyl alcohol Preparation Products And Raw materials

Raw materials

3-Phenoxybenzoic acid 3-Phenoxybenzaldehyde Ethanol Potassium hydroxide Formaldehyde Benzene Lithium Aluminum Hydride Sodium formate Sodium hydroxide Benzyl benzoate 3-PHENOXYBENZYL CHLORIDE

Preparation Products

λ-Cyhalothrin Tau-fluvalinate 3-PHENOXYBENZALDEHYDE CYANOHYDRIN CYCLOPROTHRIN S-α-cyano-3-phenoxy benzyl alcohol ETHOPERMETHRIN，95% Deltamethrin TRALOMETHRIN VALERATE Cypermethrin
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View Lastest Price from 3-Phenoxybenzyl alcohol manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
3-Phenoxybenzyl alcohol 13826-35-2
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 mt
Release date
2024-11-19
Hebei Zhuanglai Chemical Trading Co Ltd
Product
3-Phenoxybenzyl alcohol 13826-35-2
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-16
Henan Aochuang Chemical Co.,Ltd.
Product
3-Phenoxybenzyl alcohol 13826-35-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-14

13826-35-2, 3-Phenoxybenzyl alcoholRelated Search:

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