ChemicalBook > CAS DataBase List > 3-Phenoxybenzaldehyde

3-Phenoxybenzaldehyde

Product Name
3-Phenoxybenzaldehyde
CAS No.
39515-51-0
Chemical Name
3-Phenoxybenzaldehyde
Synonyms
3-PHENOXYBENZALDEHYDE;META PHENOXY BENZALDEHYE;3-PhenoxybenzaL;AKOS BBS-00003181;Phenoxybenzaldehyde;3-Phenoxy-benzaldehy;5-Phenoxybenzaldehyde;3-phenoxy-benzaldehyd;3-FORMYLDIPHENYL ETHER;M-PHENOXY BENZALDEHYDE
CBNumber
CB1697209
Molecular Formula
C13H10O2
Formula Weight
198.22
MOL File
39515-51-0.mol
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3-Phenoxybenzaldehyde Property

Melting point:
13 °C
Boiling point:
169-169.5 °C11 mm Hg(lit.)
Density 
1.147 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.595(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform, Dichloromethane (Slightly), Methanol (Slightly)
form 
Oil
color 
Colourless to Pale Yellow
Sensitive 
Air Sensitive
BRN 
511662
InChIKey
MRLGCTNJRREZHZ-UHFFFAOYSA-N
CAS DataBase Reference
39515-51-0(CAS DataBase Reference)
EPA Substance Registry System
Benzaldehyde, 3-phenoxy- (39515-51-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-26
Safety Statements 
23-24/25-45-38-28
RIDADR 
UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany 
3
RTECS 
CU7560200
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29124900
Toxicity
LD ipr-mus: >500 mg/kg JAFCAU26,954,78
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
191752
Product name
3-Phenoxybenzaldehyde
Purity
98%
Packaging
5g
Price
$40
Updated
2024/03/01
Sigma-Aldrich
Product number
191752
Product name
3-Phenoxybenzaldehyde
Purity
98%
Packaging
25g
Price
$40.2
Updated
2024/03/01
TCI Chemical
Product number
P0960
Product name
3-Phenoxybenzaldehyde
Purity
>97.0%(GC)
Packaging
25g
Price
$84
Updated
2024/03/01
TCI Chemical
Product number
P0960
Product name
3-Phenoxybenzaldehyde
Purity
>97.0%(GC)
Packaging
500g
Price
$694
Updated
2024/03/01
TRC
Product number
P297800
Product name
3-Phenoxybenzaldehyde
Packaging
2.5g
Price
$65
Updated
2021/12/16
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3-Phenoxybenzaldehyde Chemical Properties,Usage,Production

Chemical Properties

clear light yellow to amber liquid, insoluble in water, soluble in alcohol, benzene, toluene and other organic solvents.

Uses

3-phenoxybenzaldehyde is an important intermediate for the synthesis of pyrethroid pesticides phenothrin, cypermethrin, deltamethrin,fenvalerate, fenpropathrin, flucythrinate, cyhalothrin, etc.

Preparation

Synthesis of 3-Phenoxybenzaldehyde: 3-phenoxybenzoic acid is generated by catalytic oxidation of 3-phenoxytoluene, followed by electrolytic reduction to obtain Phenoxybenzyl alcohol , and then selective oxidation with sodium hypochlorite to obtain 3-Phenoxybenzaldehyde.

Production Methods

3-Phenoxybenzaldehyde is prepared by adding, at a relatively low temperature, a mixture of a 3-phenoxybenzyl halide and a 3-phenoxybenzal halide to a mixture of hexamethylenetetramine, acetic acid and water, the amounts of the water and acid bearing certain relationships to the amount of the mixture of halides, then heating the resulting mixture to a specified temperature level and maintaining it at that level for a specified period of time.
https://patents.google.com/patent/US4229380A/en

General Description

Enantioselective autoinduction during asymmetric hydrocyanation of 3-phenoxybenzaldehyde catalyzed by cyclo[(R)-phenylalanyl-(R)-histidyl] has been investigated. It undergoes hydrogenation catalyzed by Au/Pt bimetallic core/shell nanoparticles to yield 3-phenoxyphenyl methanol.

Safety Profile

Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.

Degradation

3-Phenoxybenzoic acid(3-PBA) and 3-phenoxybenzaldehyde are the most common intermediates in the degradation pathways of Type Il pyrethroids by bacteria, except the cyfluthrin degradation in Brevibacterium aureum DG-12, the beta-cyfluthrin degradation in Pseudomonas stutzeri S1, and the fenpropathrin degradation in Clostridium sp. ZP3(Chen et al.2013a; Saikia et al.2005;Zhang et al.2011b).

3-Phenoxybenzaldehyde Preparation Products And Raw materials

Raw materials

BENZAL CHLORIDE 3-Phenoxybenzoic acid Benzyl chloride 2-(5-methyl-2-propan-2-yl-phenoxy)ethanamine 2,2'-Azobis(2-methylpropionitrile) Benzyl alcohol N-VINYLACETAMIDE 97 Chlorine Diphenyl ether 3-PHENOXYTOLUENE Carbon tetrachloride Bromobenzene Copper(I) chloride Sodium chlorate Nitric acid m-Cresol Cobalt chloride Hexamethylenetetramine Benzyl dichloride 3-Bromobenzaldehyde

Preparation Products

Esfenvalerate Cyhalothrin 3-PHENOXYBENZALDEHYDE CYANOHYDRIN alpha-Cypermethrin CYCLOPROTHRIN Fenpropathrin Deltamethrin VALERATE Fenvalerate 3-Phenoxybenzyl alcohol brofluthrinate 3-(4-Bromophenoxy)Benzaldehyde Cypermethrin
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View Lastest Price from 3-Phenoxybenzaldehyde manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
3-Phenoxy-benzaldehyde 39515-51-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-26
Hebei Weibang Biotechnology Co., Ltd
Product
3-Phenoxybenzaldehyde 39515-51-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-29
Hebei Chuanghai Biotechnology Co,.LTD
Product
3-Phenoxybenzaldehyde 39515-51-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 ton
Release date
2024-08-13

39515-51-0, 3-PhenoxybenzaldehydeRelated Search:

4-Hydroxybenzaldehyde 3,5-Dimethoxybenzaldehyde 2,5-Dimethoxybenzaldehyde o-Anisaldehyde 3-(Trifluoromethyl)benzaldehyde 3,4,5-Trimethoxybenzaldehyde 3-Phenoxybenzyl alcohol Benzaldehyde p-Anisaldehyde m-Anisyl alcohol Veratraldehyde 2-Nitrobenzaldehyde 2,3,4-Trimethoxybenzaldehyde 4-Dimethylaminobenzaldehyde 4-Fluoro-3-phenoxybenzaldehyde sodium benzaldehyde-o-sulfonate 3-[3-(TRIFLUOROMETHYL)PHENOXY]BENZALDEHYDE 3-(4-METHOXYPHENOXY)BENZALDEHYDE

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