ChemicalBook > CAS DataBase List > 3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE

3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE

Product Name
3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE
CAS No.
84531-36-2
Chemical Name
3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE
Synonyms
3-nitro-5H,6H,7H-cyclopenta[b]pyridine;3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE;6,7-dihydro-3-nitro-5H-Cyclopenta[b]pyridine;5H-Cyclopenta[b]pyridine,6,7-dihydro-3-nitro-;3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE ISO 9001:2015 REACH
CBNumber
CB01253478
Molecular Formula
C8H8N2O2
Formula Weight
164.16
MOL File
84531-36-2.mol
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3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE Property

Melting point:
94-95 °C
Boiling point:
277.9±40.0 °C(Predicted)
Density 
1.328±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
2.15±0.20(Predicted)
Appearance
Light yellow to yellow Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
N901215
Product name
3-Nitro-6,7-dihydro-5H-cyclopenta[b]pyridine
Packaging
100mg
Price
$330
Updated
2021/12/16
AK Scientific
Product number
W8722
Product name
3-Nitro-6,7-dihydro-5H-cyclopenta[b]pyridine
Packaging
1g
Price
$177
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0382606
Product name
3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE
Purity
95.00%
Packaging
5MG
Price
$500.01
Updated
2021/12/16
AK Scientific
Product number
W8722
Product name
3-Nitro-6,7-dihydro-5H-cyclopenta[b]pyridine
Packaging
5g
Price
$555
Updated
2021/12/16
Matrix Scientific
Product number
085984
Product name
3-Nitro-6,7-dihydro-5H-cyclopenta[b]pyridine
Purity
97%
Packaging
1g
Price
$1517
Updated
2021/12/16
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3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE Chemical Properties,Usage,Production

Synthesis

14150-94-8

120-92-3

84531-36-2

GENERAL METHOD: 1-methyl-3,5-dinitro-1H-pyridin-2-one (50 mg, 0.25 mmol) was dissolved in ethanol (5 mL), followed by cyclopentanone (26 μL, 0.25 mmol) and ammonium acetate (289 mg, 3.75 mmol). The reaction mixture was heated in an oil bath at 65 °C for 24 hours. After completion of the reaction, the solvent was removed by rotary evaporation and the residue was washed with benzene (3 × 10 mL) to afford 3-nitro-6,7-dihydro-5-hydro-cyclopenta[b]pyridine (42 mg, 0.24 mmol, 95% yield) as a yellow powder. The reaction of other ketones with 1-methyl-3,5-dinitro-1H-pyridin-2-one was carried out according to similar conditions. When microwave heating was used, the reaction conditions were the same as described above.

References

[1] Synthesis (Germany), 2014, vol. 46, # 16, p. 2175 - 2178
[2] Bulletin of the Chemical Society of Japan, 1990, vol. 63, # 10, p. 2820 - 2827

3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE Suppliers

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View Lastest Price from 3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE 84531-36-2
Price
US $1.10/g
Min. Order
1g
Purity
99.0% min
Supply Ability
100 tons min
Release date
2021-05-13

84531-36-2, 3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINERelated Search:


  • 3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE
  • 3-nitro-5H,6H,7H-cyclopenta[b]pyridine
  • 6,7-dihydro-3-nitro-5H-Cyclopenta[b]pyridine
  • 5H-Cyclopenta[b]pyridine,6,7-dihydro-3-nitro-
  • 3-NITRO-6,7-DIHYDRO-5H-CYCLOPENTA[B]PYRIDINE ISO 9001:2015 REACH
  • 84531-36-2
  • Heterocycle-Pyridine series
  • Fused Ring Systems