ChemicalBook > CAS DataBase List > 1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI)

1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI)

Product Name
1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI)
CAS No.
62366-53-4
Chemical Name
1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI)
Synonyms
methyl 1-methylimidazole-2-carboxylate;1,2-Propanediol,3-(3,10-dimethylphenoxy)-;Methyl 1-Methyl-1H-iMidazole-2-carboxylate;1-methyl-1H-Imidazole-2-carboxylic acid methyl ester;1H-Imidazole-2-carboxylic acid, 1-methyl-, methyl ester;1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI)
CBNumber
CB01278626
Molecular Formula
C6H8N2O2
Formula Weight
140.14
MOL File
62366-53-4.mol
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1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI) Property

Boiling point:
90-94℃/0.6Torr
Density 
1.18±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
4.00±0.25(Predicted)
Appearance
Light yellow to yellow Liquid
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Safety

HS Code 
2933299090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Apolloscientific
Product number
OR910010
Product name
Methyl1-methyl-1H-imidazole-2-carboxylate
Purity
95%
Packaging
1g
Price
$85
Updated
2021/12/16
Matrix Scientific
Product number
123809
Product name
Methyl1-methyl-1H-imidazole-2-carboxylate
Purity
95+%
Packaging
1g
Price
$100
Updated
2021/12/16
Apolloscientific
Product number
OR910010
Product name
Methyl1-methyl-1H-imidazole-2-carboxylate
Purity
95%
Packaging
10g
Price
$245
Updated
2021/12/16
Apolloscientific
Product number
OR910010
Product name
Methyl1-methyl-1H-imidazole-2-carboxylate
Purity
95%
Packaging
25g
Price
$490
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0313641
Product name
METHYL-1-METHYL-1H-IMIDAZOLE-2-CARBOXYLATE
Purity
95.00%
Packaging
5MG
Price
$500.05
Updated
2021/12/16
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1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI) Chemical Properties,Usage,Production

Synthesis

616-47-7

79-22-1

62366-53-4

In a 100 mL three-necked flask protected with argon, 22 mL of acetonitrile and 6.3 mL of methyl chloroformate were added and the mixture was cooled to -20°C. A solution of 3.3 g N-methylimidazole and 6.8 mL triethylamine dissolved in 8 mL of acetonitrile was slowly added dropwise for a controlled time of 30 minutes. After the dropwise addition, the reaction mixture was stirred at room temperature for 12 hours. After completion of the reaction, 50 mL of ethyl acetate was added to the reaction solution, the insoluble material was removed by filtration and the solid residue was washed with 50 mL of ethyl acetate. The filtrate and washings were combined and concentrated under reduced pressure. The resulting crude product was purified by silica gel column chromatography with the eluent being a mixed solvent of hexane/ethyl acetate to give 4.2 g of methyl 1-methyl-1H-imidazole-2-carboxylate in 73% yield.

References

[1] Patent: JP2017/66077, 2017, A. Location in patent: Paragraph 0059

1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI) Suppliers

Shanghai Sunway Pharmaceutical Technology Co., Ltd
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Nanjing YaoCheng Pharmaceutical Co., Ltd.
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View Lastest Price from 1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI) manufacturers

Career Henan Chemical Co
Product
1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI) 62366-53-4
Price
US $2.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
ask
Release date
2020-01-08

62366-53-4, 1H-Imidazole-2-carboxylicacid,1-methyl-,methylester(9CI)Related Search:


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