ChemicalBook > CAS DataBase List > 1H-Indole-3-carboxamide(9CI)

1H-Indole-3-carboxamide(9CI)

Product Name
1H-Indole-3-carboxamide(9CI)
CAS No.
1670-85-5
Chemical Name
1H-Indole-3-carboxamide(9CI)
Synonyms
1H-Indole-3-carboxamide(9CI);indole-3-yl carboxylic acid amide;2,6-Piperidinedione,3-[(6-chlorophenyl)methyl]-
CBNumber
CB01282935
Molecular Formula
C9H8N2O
Formula Weight
160.17
MOL File
1670-85-5.mol
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1H-Indole-3-carboxamide(9CI) Property

Melting point:
201 °C
Boiling point:
457.6±18.0 °C(Predicted)
Density 
1.328±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
15.80±0.30(Predicted)
Appearance
Off-white to light brown Solid
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Safety

HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
I629028
Product name
1H-Indole-3-carboxylicAcidAmide
Packaging
100mg
Price
$65
Updated
2021/12/16
AK Scientific
Product number
W3631
Product name
1H-Indole-3-carboxylicacidamide
Packaging
1g
Price
$192
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0077922
Product name
1H-INDOLE-3-CARBOXYLIC ACID AMIDE
Purity
95.00%
Packaging
1G
Price
$808.89
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0077922
Product name
1H-INDOLE-3-CARBOXYLIC ACID AMIDE
Purity
95.00%
Packaging
2.5G
Price
$1147.43
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0077922
Product name
1H-INDOLE-3-CARBOXYLIC ACID AMIDE
Purity
95.00%
Packaging
5G
Price
$1421.65
Updated
2021/12/16
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1H-Indole-3-carboxamide(9CI) Chemical Properties,Usage,Production

Synthesis

5457-28-3

1670-85-5

GENERAL METHOD: To an anhydrous ethanol solution of 3-cyanoindole (15 mmol) was added 40% aqueous NaOH (5 mL) under stirring conditions. The reaction process was monitored by thin layer chromatography (TLC). Subsequently, 30% aqueous H2O2 solution (10.5 mL, 104.7 mmol) was slowly added dropwise to the reaction mixture. Upon completion of the reaction, the precipitated solid was collected by filtration, washed with water and recrystallized with anhydrous ethanol. Finally, the product was dried under vacuum to give 1H-indole-3-carboxamide (20a). The product was a white solid in 75% yield with a melting point of 195-197 °C (literature value 197-199 °C [31]).1H NMR (δ, ppm): 6.84 (s, 1H, NH), 7.13-7.21 (m, 2H, ArH), 7.47 (d, J = 8.0 Hz, 2H, ArH), 8.08 (s, 1H, NH), 8.20 (d, J = 7.5 Hz, 1H, ArH), 11.60 (s, 1H, NH).

References

[1] Applied Organometallic Chemistry, 2014, vol. 28, # 12, p. 900 - 907
[2] Catalysis Science and Technology, 2015, vol. 5, # 3, p. 1606 - 1622
[3] Synthetic Communications, 2013, vol. 43, # 21, p. 2867 - 2875
[4] Dalton Transactions, 2016, vol. 45, # 34, p. 13590 - 13603
[5] Russian Journal of General Chemistry, 2017, vol. 87, # 12, p. 3006 - 3016

1H-Indole-3-carboxamide(9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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