ChemicalBook > CAS DataBase List > CYCLOATE

CYCLOATE

Product Name
CYCLOATE
CAS No.
1134-23-2
Chemical Name
CYCLOATE
Synonyms
SABET;EUREX;Ronit;etsan;R-2063;RO-NEET;CYCLOATE;Cycolate;ro-neete;AGRO-NET
CBNumber
CB0134167
Molecular Formula
C11H21NOS
Formula Weight
215.36
MOL File
1134-23-2.mol
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CYCLOATE Property

Melting point:
11.5°C
Boiling point:
145 °C(Press: 10 Torr)
Density 
1.0156
vapor pressure 
0.002Pa at 25℃
refractive index 
1.5500 (estimate)
Flash point:
>100 °C
storage temp. 
0-6°C
form 
Liquid
pka
-1.30±0.20(Predicted)
Water Solubility 
85mg/L(22 ºC)
BRN 
2937178
LogP
3.88 at 20℃
CAS DataBase Reference
1134-23-2
EPA Substance Registry System
Cycloate (1134-23-2)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
22-51/53
Safety Statements 
61
RIDADR 
UN3082 9/PG 3
WGK Germany 
2
RTECS 
GU7200000
Hazardous Substances Data
1134-23-2(Hazardous Substances Data)
Toxicity
LC50 (96-hour) for rainbow trout 4.5 mg/L (Hartley and Kidd, 1987), for mosquito fish 10 ppm (Humburg et al., 1989); acute oral LD50 of technical cycloate for male and female rats 2,000–3,190 and 3,160–4,100 mg/kg, respectively (Hartley and Kidd, 1987), 1,678 mg/kg (RTECS, 1985)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H331Toxic if inhaled

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45408
Product name
Cycloate
Purity
PESTANAL
Packaging
250mg
Price
$63.1
Updated
2024/03/01
TRC
Product number
C989320
Product name
Cycloate
Packaging
500mg
Price
$130
Updated
2021/12/16
TRC
Product number
C989320
Product name
Cycloate
Packaging
5g
Price
$1050
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
PST0000348
Product name
CYCLOATE
Purity
98.00%
Packaging
10G
Price
$1536.15
Updated
2021/12/16
AHH
Product number
MT-49579
Product name
Cycloate
Purity
98%
Packaging
10g
Price
$360
Updated
2021/12/16
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CYCLOATE Chemical Properties,Usage,Production

Chemical Properties

Cycolate is an oily, clear, or amber to yellow liquid. Aromatic odor;

Uses

Herbicide used to control several broad-leaved weeds and many annual grasses in sugar beets, table beets and spinach

Definition

ChEBI: Cycloate is a primary aliphatic amine.

General Description

Colorless liquid with an aromatic odor. Used as a selective systemic herbicide.

Air & Water Reactions

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids or alkalis.

Reactivity Profile

CYCLOATE is a thiocarbamate ester. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Flammability and Explosibility

Non flammable

Agricultural Uses

Herbicide: Used to control broadleaf weeds, annual and perennial grasses and nutgrass in spinach, beets, and sugar beets. Not approved for use in EU countries. Actively registered in the U.S.

Trade name

ETSAN®; EUREX®; R-2063®; RO- NEET®; RO-NEET®-6E; RO-NEET® 10G; RONIT®; SABET®

Potential Exposure

Cycolate is a thiocarbamate herbicide used to control broad leaf weeds, annual and perennial grasses and nutgrass in spinach, beets, and sugar beets.

Environmental Fate

Soil. The reported half-life in soil is approximately 4–8 weeks (Hartley and Kidd, 1987)
Groundwater. According to the U.S. EPA (1986) cycloate has a high potential to leach to groundwater
Plant. Cycloate is rapidly metabolized in sugarbeets to carbon dioxide, ethylcyclohexylamine, sugars, amino acids and other natural constituents (Humburg et al., 1989)
Chemical/Physical. In the gas phase, cycloate reacts with hydroxyl and NO3 radicals but not with ozone. With hydroxy radicals, cleavage of the cyclohexyl ring was suggested leading to the formation of a compound tentatively identified as C2H5(CHO)NC(O)SC2H5. The calculated photolysis lifetimes of cycloate in the troposphere with hydroxyl and NO3 radicals are 5.2 hours and 1.4 days, respectively (Kwok et al., 1992).

Shipping

UN3082 Environmentally Hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz- ardous material, Technical Name Required

Incompatibilities

Cycolate reacts violently with powerful oxidizers such as calcium hypochlorite. Thiocarbamate esters are combustible. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitro- gen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solu- tion to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thio- carbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with acids, peroxides, and acid halides.

Waste Disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guid- ance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

CYCLOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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CYCLOATE Suppliers

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1134-23-2, CYCLOATERelated Search:


  • Cyclohexylethylcarbamothioic acid, S-Ethyl ester
  • Cycolate
  • N-cyclohexyl-N-ethyl-thiocarbamic acid S-ethyl ester
  • S-ethyl N-cyclohexyl-N-ethylcarbamothioate
  • S-ethyl N-cyclohexyl-N-ethyl-carbamothioate
  • CYCLOATE
  • EUREX
  • S-ETHYL CYCLOHEXYL(ETHYL)THIOCARBAMATE
  • S-ETHYL-N-ETHYL-N-CYCLOHEXYLTHIOL-CARBAMATE
  • SABET
  • RO-NEET
  • R-2063
  • Carbamic acid, cyclohexylethylthio-, S-ethyl ester
  • Carbamothioic acid, cyclohexylethyl-, S-ethyl ester
  • Cyclohexanecarbamic acid, N-ethylthio-, S-ethyl ester
  • ro-neete
  • Ronit
  • S-Ethyl N-ethyl-N-cyclohexylthiocarbamate
  • s-ethylcyclohexylethylcarbamothioate
  • s-ethylethylcyclohexylthiocarbamate
  • s-ethyln-cyclohexyl-n-ethyl(thiocarbamate)
  • s-ethyln-ethylthiocyclohexanecarbamate
  • 5-ETHYL N-CYCLOHEXYL N-ETHYL THIOCARBAMATE
  • AGRO-NET
  • S-ethyl N-cyclohexylthiocarbamate
  • CYCLOATE, 1GM, NEAT
  • CYCLOATE PESTANAL (S-ETHYL N-CYCLO- HEXY
  • cycloate (bsi,iso,wssa)
  • hexylthiocarbam (jmaf)
  • S-ETHYLN-ETHYLCYCLOHEXANECARBAMOTHIOATE
  • 5-Ethylcyclohexylehtylcarbatate
  • cyclohexylethyl-carbamothioicacis-ethylester
  • cyclohexylethylthio-carbamicacis-ethylester
  • etsan
  • hexylthiocarbam
  • n-ethylthio-cyclohexanecarbamicacis-ethylester
  • ro-neet10g
  • ro-neet6-e
  • Cycloate @100 μg/mL in Methanol
  • Cycloate Standard
  • Cycloate@1000 μg/mL in Methanol
  • Carbamothioic acid, N-cyclohexyl-N-ethyl-, S-ethyl ester
  • Cycloate Solution in Acetonitrile, 100μg/mL
  • HSDB 1712
  • HSDB-1712
  • Enavogliflozin Impurity 28
  • 1134-23-2
  • 000134-23-3
  • C11H21NOS
  • Alphabetic
  • C
  • CO - CZPesticides&Metabolites
  • Herbicides
  • Thiocarbamates