METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE
- Product Name
- METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE
- CAS No.
- 70424-94-1
- Chemical Name
- METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE
- Synonyms
- NSC 525276;METHYL TRIBENZYLGALLATE;Methyl Tri-O-benzylgallate;METHYL 3,4,5-TRIBENZYLOXYBENZOATE;METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE;methyl 3,4,5-tris(phenylmethoxy)benzoate;3,4,5-TRIBENZYLOXYBENZOIC ACID METHYL ESTER;3,4,5-TRIS(BENZYLOXY)BENZOIC ACID METHYL ESTER;3,4,5-Tris(phenylMethoxy)benzoic Acid Methyl Ester;Benzoic acid, 3,4,5-tris(phenylmethoxy)-, methyl ester
- CBNumber
- CB0142555
- Molecular Formula
- C29H26O5
- Formula Weight
- 454.51
- MOL File
- 70424-94-1.mol
METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE Property
- Melting point:
- 98 °C
- Boiling point:
- 584.5±40.0 °C(Predicted)
- Density
- 1.191±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Acetone, Chloroform, Dichloromethane
- form
- Solid
- color
- White
- CAS DataBase Reference
- 70424-94-1
Safety
- HS Code
- 2918.29.7500
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- T1870
- Product name
- Methyl 3,4,5-Tris(benzyloxy)benzoate
- Purity
- >98.0%(HPLC)
- Packaging
- 5g
- Price
- $77
- Updated
- 2025/07/31
- Product number
- M331285
- Product name
- Methyl 3,4,5-Tris(benzyloxy)benzoate
- Packaging
- 25g
- Price
- $240
- Updated
- 2021/12/16
- Product number
- CHM0152032
- Product name
- METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $716.1
- Updated
- 2021/12/16
- Product number
- 8226AL
- Product name
- Methyl 3,4,5-Tris(benzyloxy)benzoate
- Packaging
- 500g
- Price
- $2044
- Updated
- 2021/12/16
- Product number
- A268071
- Product name
- Methyl 3,4,5-Tris(benzyloxy)benzoate
- Purity
- 95%
- Packaging
- 250mg
- Price
- $6
- Updated
- 2021/12/16
METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE Chemical Properties,Usage,Production
Chemical Properties
White Solid
Uses
Intermediate in the production of Gallic Acid derivatives.
Synthesis
99-24-1
100-39-0
70424-94-1
Benzyl bromide (4.4 g, 25.7 mmol) was added dropwise to a stirred solution of methyl 3,4,5-trihydroxybenzoate (0.94 g, 5.15 mmol) and potassium carbonate (6.56 g, 25.7 mmol) in N,N-dimethylformamide (DMF, 20 mL). The reaction mixture was stirred under nitrogen (N2) protection in an oil bath at 60 °C for 15 hours. Upon completion of the reaction, the reaction was quenched by adding an appropriate amount of water to the mixture and extracted with chloroform (3 × 20 mL). The organic phases were combined, washed with saturated brine, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford methyl 3,4,5-tris(benzyloxy)benzoate (1.93 g, 90% yield) as a white solid.
References
[1] Patent: EP1870403, 2007, A1. Location in patent: Page/Page column 95
[2] Patent: US2004/110790, 2004, A1. Location in patent: Page 14
[3] Bioscience, Biotechnology and Biochemistry, 2003, vol. 67, # 12, p. 2584 - 2590
[4] Patent: US7288273, 2007, B1. Location in patent: Page/Page column 38
[5] Synthetic Communications, 2002, vol. 32, # 20, p. 3149 - 3158
METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE Suppliers
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View Lastest Price from METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE manufacturers
- Product
- Methyl 3,4,5-Tris(benzyloxy)benzoate 70424-94-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27