ChemicalBook > CAS DataBase List > METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE

METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE

Product Name
METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE
CAS No.
70424-94-1
Chemical Name
METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE
Synonyms
NSC 525276;METHYL TRIBENZYLGALLATE;Methyl Tri-O-benzylgallate;METHYL 3,4,5-TRIBENZYLOXYBENZOATE;METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE;methyl 3,4,5-tris(phenylmethoxy)benzoate;3,4,5-TRIBENZYLOXYBENZOIC ACID METHYL ESTER;3,4,5-TRIS(BENZYLOXY)BENZOIC ACID METHYL ESTER;3,4,5-Tris(phenylMethoxy)benzoic Acid Methyl Ester;Benzoic acid, 3,4,5-tris(phenylmethoxy)-, methyl ester
CBNumber
CB0142555
Molecular Formula
C29H26O5
Formula Weight
454.51
MOL File
70424-94-1.mol
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METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE Property

Melting point:
98 °C
Boiling point:
584.5±40.0 °C(Predicted)
Density 
1.191±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Acetone, Chloroform, Dichloromethane
form 
Solid
color 
White
CAS DataBase Reference
70424-94-1
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Safety

HS Code 
2918.29.7500
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T1870
Product name
Methyl 3,4,5-Tris(benzyloxy)benzoate
Purity
>98.0%(HPLC)
Packaging
5g
Price
$77
Updated
2025/07/31
TRC
Product number
M331285
Product name
Methyl 3,4,5-Tris(benzyloxy)benzoate
Packaging
25g
Price
$240
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0152032
Product name
METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE
Purity
95.00%
Packaging
1G
Price
$716.1
Updated
2021/12/16
AK Scientific
Product number
8226AL
Product name
Methyl 3,4,5-Tris(benzyloxy)benzoate
Packaging
500g
Price
$2044
Updated
2021/12/16
Ambeed
Product number
A268071
Product name
Methyl 3,4,5-Tris(benzyloxy)benzoate
Purity
95%
Packaging
250mg
Price
$6
Updated
2021/12/16
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METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

Intermediate in the production of Gallic Acid derivatives.

Synthesis

99-24-1

100-39-0

70424-94-1

Benzyl bromide (4.4 g, 25.7 mmol) was added dropwise to a stirred solution of methyl 3,4,5-trihydroxybenzoate (0.94 g, 5.15 mmol) and potassium carbonate (6.56 g, 25.7 mmol) in N,N-dimethylformamide (DMF, 20 mL). The reaction mixture was stirred under nitrogen (N2) protection in an oil bath at 60 °C for 15 hours. Upon completion of the reaction, the reaction was quenched by adding an appropriate amount of water to the mixture and extracted with chloroform (3 × 20 mL). The organic phases were combined, washed with saturated brine, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford methyl 3,4,5-tris(benzyloxy)benzoate (1.93 g, 90% yield) as a white solid.

References

[1] Patent: EP1870403, 2007, A1. Location in patent: Page/Page column 95
[2] Patent: US2004/110790, 2004, A1. Location in patent: Page 14
[3] Bioscience, Biotechnology and Biochemistry, 2003, vol. 67, # 12, p. 2584 - 2590
[4] Patent: US7288273, 2007, B1. Location in patent: Page/Page column 38
[5] Synthetic Communications, 2002, vol. 32, # 20, p. 3149 - 3158

METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE Suppliers

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View Lastest Price from METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Methyl 3,4,5-Tris(benzyloxy)benzoate 70424-94-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

70424-94-1, METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATERelated Search:


  • METHYL TRIBENZYLGALLATE
  • METHYL 3,4,5-TRIBENZYLOXYBENZOATE
  • METHYL 3,4,5-TRIS(BENZYLOXY)BENZOATE
  • 3,4,5-TRIS(BENZYLOXY)BENZOIC ACID METHYL ESTER
  • 3,4,5-TRIBENZYLOXYBENZOIC ACID METHYL ESTER
  • methyl 3,4,5-tris(phenylmethoxy)benzoate
  • 3,4,5-Tris(phenylMethoxy)benzoic Acid Methyl Ester
  • Methyl Tri-O-benzylgallate
  • NSC 525276
  • Methyl 3,4,5-Tribenzyloxybenzoate 3,4,5-Tribenzyloxybenzoic Acid Methyl Ester 3,4,5-Tris(benzyloxy)benzoic Acid Methyl Ester
  • Benzoic acid, 3,4,5-tris(phenylmethoxy)-, methyl ester
  • Methyl3,4,5-tris(benzyloxy)benzoateMethyl3,4,5-tris(benzyloxy)benzoate
  • 70424-94-1
  • C29H26O5
  • Building Blocks for Dendrimers
  • Building Blocks for Dendrimers
  • Functional Materials
  • Aromatics
  • Intermediates