methyl (4-formylphenoxy)acetate
- Product Name
- methyl (4-formylphenoxy)acetate
- CAS No.
- 73620-18-5
- Chemical Name
- methyl (4-formylphenoxy)acetate
- Synonyms
- Methyl 2-(4-formylphenoxy);methyl (4-formylphenoxy)acetate;Methyl 2-(4-forMylphenoxy)acetate;methyl 2-(4-methanoylphenoxy)ethanoate;2-(4-formylphenoxy)acetic acid methyl ester;acetic acid, (4-formylphenoxy)-, methyl ester;Acetic acid, 2-(4-formylphenoxy)-, methyl ester
- CBNumber
- CB01518731
- Molecular Formula
- C10H10O4
- Formula Weight
- 194.18
- MOL File
- 73620-18-5.mol
methyl (4-formylphenoxy)acetate Property
- Melting point:
- 40-42 °C
- Boiling point:
- 315.2±17.0 °C(Predicted)
- Density
- 1.201±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
Safety
- HazardClass
- IRRITANT
- HS Code
- 2918999090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M321383
- Product name
- Methyl2-(4-Formylphenoxy)acetate
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- W8169
- Product name
- Methyl(4-formylphenoxy)acetate
- Packaging
- 1g
- Price
- $62
- Updated
- 2021/12/16
- Product number
- OR907093
- Product name
- Methyl(4-formylphenoxy)acetate
- Purity
- 95%
- Packaging
- 1g
- Price
- $160
- Updated
- 2021/12/16
- Product number
- W8169
- Product name
- Methyl(4-formylphenoxy)acetate
- Packaging
- 5g
- Price
- $185
- Updated
- 2021/12/16
- Product number
- OR907093
- Product name
- Methyl(4-formylphenoxy)acetate
- Purity
- 95%
- Packaging
- 5g
- Price
- $399
- Updated
- 2021/12/16
methyl (4-formylphenoxy)acetate Chemical Properties,Usage,Production
Synthesis
123-08-0
96-32-2
73620-18-5
General procedure for the synthesis of methyl (4-formylphenoxy)acetate from p-hydroxybenzaldehyde and methyl bromoacetate: K2CO3 (5.43 g, 39.3 mmol) was added to a solution of 4-hydroxybenzaldehyde (3.0 g, 25 mmol) in acetone (61.4 mL) and the mixture was stirred vigorously. Methyl bromoacetate (2.8 mL, 29 mmol) was then added and the mixture was stirred at room temperature for 3.5 hours. Upon completion of the reaction, the reaction mixture was concentrated under reduced pressure and then washed with 110 mL of water and extracted with ethyl acetate (EtOAc). The organic layer was separated, dried with anhydrous Na2SO4, filtered and concentrated to give a colorless oil which solidified to a white solid under vacuum in 82% isolated yield. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 9.87 (s, 1H), 7.82 (d, J = 8.8 Hz, 2H), 6.98 (d, J = 8.7 Hz, 2H), 4.70 (s, 2H), 3.79 (s, 3H). eSI-MS (m/z): 195.1 [M + H]+.
References
[1] Organic Letters, 2011, vol. 13, # 20, p. 5656 - 5659
[2] Organic Letters, 2004, vol. 6, # 12, p. 2019 - 2022
[3] Chemistry - A European Journal, 2008, vol. 14, # 19, p. 5812 - 5819
[4] Patent: WO2015/65716, 2015, A1. Location in patent: Paragraph 00490
[5] Patent: WO2016/144958, 2016, A1. Location in patent: Paragraph 00296
methyl (4-formylphenoxy)acetate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from methyl (4-formylphenoxy)acetate manufacturers
- Product
- Methyl2-(4-formylphenoxy)acetate 73620-18-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.5%
- Supply Ability
- 100 tons
- Release date
- 2022-01-14
- Product
- methyl (4-formylphenoxy)acetate 73620-18-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- methyl (4-formylphenoxy)acetate 73620-18-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09