methyl 3-(2-bromophenyl)propanoate

Product Name: methyl 3-(2-bromophenyl)propanoate
CAS No.: 66191-86-4
Chemical Name: methyl 3-(2-bromophenyl)propanoate
Synonyms: O-broMophenolMethyl propionate;Methyl 3-(2-bromophenyl)propionate;methyl 3-(2-bromophenyl)propanoate;Methyl3-(2-bromophenyl)propionate,98%;Methyl 3-(2-Bromophenyl)propionate >3-(2-bromophenyl)propanoic acid methyl ester;3-(2-Bromophenyl)propionic Acid Methyl Ester;Benzenepropanoic acid, 2-bromo-, methyl ester
CBNumber: CB01563913
Molecular Formula: C10H11BrO2
Formula Weight: 243.1
MOL File: 66191-86-4.mol

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methyl 3-(2-bromophenyl)propanoate Property

Boiling point:: 87℃/0.02Torr
Density: 1.389±0.06 g/cm3(Predicted)
refractive index: 1.5380 to 1.5420
storage temp.: Sealed in dry,Room Temperature
form: Liquid
color: Colorless to pale yellow
CAS DataBase Reference: 66191-86-4

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2587
Product name: Methyl 3-(2-Bromophenyl)propionate
Purity: >98.0%(GC)
Packaging: 1g
Price: $30
Updated: 2025/07/31

TCI Chemical

Product number: M2587
Product name: Methyl 3-(2-Bromophenyl)propionate
Purity: >98.0%(GC)
Packaging: 5g
Price: $118
Updated: 2025/07/31

TRC

Product number: M296543
Product name: Methyl3-(2-Bromophenyl)propanoate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: M296543
Product name: Methyl3-(2-Bromophenyl)propanoate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: M296543
Product name: Methyl3-(2-Bromophenyl)propanoate
Packaging: 500mg
Price: $75
Updated: 2021/12/16

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methyl 3-(2-bromophenyl)propanoate Chemical Properties,Usage,Production

Synthesis

67-56-1

15115-58-9

66191-86-4

To a stirred solution of 3-(2-bromophenyl)propionic acid (7.7 g, 33.6 mmol) in methanol (60 mL) at room temperature was added thionyl chloride (0.9 mL, 12 mmol) dropwise. The reaction mixture was heated to reflux for 1 hour. Subsequently, additional thionyl chloride (0.9 mL each, total 24 mmol) was added in two additions under reflux conditions, the second addition following the complete reaction of the first. After continuing the reflux reaction for 2 h, the volatile components were removed by distillation under reduced pressure (70 °C, 0.8 kPa). The light yellow oily residue obtained was dissolved in dichloromethane (60 mL) and washed with saturated aqueous sodium bicarbonate (60 mL). The organic layer was dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to afford methyl o-bromophenylpropionate (7.8 g, 96% yield) as a yellow oily liquid. The proton NMR spectral data of the product were in agreement with those reported in the literature [10].

References

[1] Angewandte Chemie - International Edition, 2016, vol. 55, # 51, p. 15797 - 15801
[2] Angew. Chem., 2016, vol. 128, p. 16029 - 16033,5
[3] Beilstein Journal of Organic Chemistry, 2015, vol. 11, p. 884 - 892
[4] Journal of Heterocyclic Chemistry, 2018, vol. 55, # 3, p. 670 - 684
[5] Tetrahedron, 2013, vol. 69, # 36, p. 7618 - 7626

methyl 3-(2-bromophenyl)propanoate Preparation Products And Raw materials

Raw materials

Preparation Products

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methyl 3-(2-bromophenyl)propanoate Suppliers

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View Lastest Price from methyl 3-(2-bromophenyl)propanoate manufacturers

Career Henan Chemical Co

Product: methyl 3-(2-bromophenyl)propanoate 66191-86-4
Price: US $1.00/ASSAYS
Min. Order: 1ASSAYS
Purity: 85.0-99.8%
Supply Ability: 20tons
Release date: 2020-01-08

66191-86-4, methyl 3-(2-bromophenyl)propanoateRelated Search:

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methyl 3-(2-bromophenyl)propanoate

Methyl 3-(2-bromophenyl)propionate

O-broMophenolMethyl propionate

3-(2-bromophenyl)propanoic acid methyl ester

Methyl 3-(2-Bromophenyl)propionate &gt

Benzenepropanoic acid, 2-bromo-, methyl ester

Methyl3-(2-bromophenyl)propionate,98%

3-(2-Bromophenyl)propionic Acid Methyl Ester

66191-86-4