methyl 3-(2-bromophenyl)propanoate
- Product Name
- methyl 3-(2-bromophenyl)propanoate
- CAS No.
- 66191-86-4
- Chemical Name
- methyl 3-(2-bromophenyl)propanoate
- Synonyms
- O-broMophenolMethyl propionate;Methyl 3-(2-bromophenyl)propionate;methyl 3-(2-bromophenyl)propanoate;Methyl3-(2-bromophenyl)propionate,98%;Methyl 3-(2-Bromophenyl)propionate >3-(2-bromophenyl)propanoic acid methyl ester;3-(2-Bromophenyl)propionic Acid Methyl Ester;Benzenepropanoic acid, 2-bromo-, methyl ester
- CBNumber
- CB01563913
- Molecular Formula
- C10H11BrO2
- Formula Weight
- 243.1
- MOL File
- 66191-86-4.mol
methyl 3-(2-bromophenyl)propanoate Property
- Boiling point:
- 87℃/0.02Torr
- Density
- 1.389±0.06 g/cm3(Predicted)
- refractive index
- 1.5380 to 1.5420
- storage temp.
- Sealed in dry,Room Temperature
- form
- Liquid
- color
- Colorless to pale yellow
- CAS DataBase Reference
- 66191-86-4
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- M2587
- Product name
- Methyl 3-(2-Bromophenyl)propionate
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $30
- Updated
- 2025/07/31
- Product number
- M2587
- Product name
- Methyl 3-(2-Bromophenyl)propionate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $118
- Updated
- 2025/07/31
- Product number
- M296543
- Product name
- Methyl3-(2-Bromophenyl)propanoate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M296543
- Product name
- Methyl3-(2-Bromophenyl)propanoate
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- M296543
- Product name
- Methyl3-(2-Bromophenyl)propanoate
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
methyl 3-(2-bromophenyl)propanoate Chemical Properties,Usage,Production
Synthesis
67-56-1
15115-58-9
66191-86-4
To a stirred solution of 3-(2-bromophenyl)propionic acid (7.7 g, 33.6 mmol) in methanol (60 mL) at room temperature was added thionyl chloride (0.9 mL, 12 mmol) dropwise. The reaction mixture was heated to reflux for 1 hour. Subsequently, additional thionyl chloride (0.9 mL each, total 24 mmol) was added in two additions under reflux conditions, the second addition following the complete reaction of the first. After continuing the reflux reaction for 2 h, the volatile components were removed by distillation under reduced pressure (70 °C, 0.8 kPa). The light yellow oily residue obtained was dissolved in dichloromethane (60 mL) and washed with saturated aqueous sodium bicarbonate (60 mL). The organic layer was dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to afford methyl o-bromophenylpropionate (7.8 g, 96% yield) as a yellow oily liquid. The proton NMR spectral data of the product were in agreement with those reported in the literature [10].
References
[1] Angewandte Chemie - International Edition, 2016, vol. 55, # 51, p. 15797 - 15801
[2] Angew. Chem., 2016, vol. 128, p. 16029 - 16033,5
[3] Beilstein Journal of Organic Chemistry, 2015, vol. 11, p. 884 - 892
[4] Journal of Heterocyclic Chemistry, 2018, vol. 55, # 3, p. 670 - 684
[5] Tetrahedron, 2013, vol. 69, # 36, p. 7618 - 7626
methyl 3-(2-bromophenyl)propanoate Preparation Products And Raw materials
Raw materials
Preparation Products
methyl 3-(2-bromophenyl)propanoate Suppliers
- Tel
- --
- Fax
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- info@pschemicals.com
- Country
- The Netherlands
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View Lastest Price from methyl 3-(2-bromophenyl)propanoate manufacturers
- Product
- methyl 3-(2-bromophenyl)propanoate 66191-86-4
- Price
- US $1.00/ASSAYS
- Min. Order
- 1ASSAYS
- Purity
- 85.0-99.8%
- Supply Ability
- 20tons
- Release date
- 2020-01-08