2-Methyl-4-chlorophenoxyacetic acid

ChemicalBook > CAS DataBase List > 2-Methyl-4-chlorophenoxyacetic acid

2-Methyl-4-chlorophenoxyacetic acid

Product Name: 2-Methyl-4-chlorophenoxyacetic acid
CAS No.: 94-74-6
Chemical Name: 2-Methyl-4-chlorophenoxyacetic acid
Synonyms: MCP;MCPA;MCPA Ester;2-Methyl-4-chlorophenoxyacetic;(4-CHLORO-2-METHYLPHENOXY)ACETIC ACID;2-(4-CHLORO-2-METHYLPHENOXY)ACETIC ACID;Mecpa;EMPAL;MCCPA;2M2Kh
CBNumber: CB0165198
Molecular Formula: C9H9ClO3
Formula Weight: 200.62
MOL File: 94-74-6.mol

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2-Methyl-4-chlorophenoxyacetic acid Property

Melting point:: 114-118 °C (lit.)
Boiling point:: 288.02°C (rough estimate)
Density: 1.2799 (rough estimate)
refractive index: 1.5230 (estimate)
Flash point:: 2 °C
storage temp.: Sealed in dry,Room Temperature
solubility: water: insoluble(lit.)
form: Solid
pka: 3.14±0.10(Predicted)
color: White to Light yellow to Light orange
Water Solubility: 1.174g/L(25 ºC)
Merck: 14,5764
BRN: 2051752
CAS DataBase Reference: 94-74-6(CAS DataBase Reference)
NIST Chemistry Reference: [(4-Chloro-o-tolyl)oxy]acetic acid(94-74-6)
EPA Substance Registry System: MCPA (94-74-6)

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Safety

Hazard Codes: Xn,F,N
Risk Statements: 22-38-41-36-20/21/22-11-50/53
Safety Statements: 26-37-39-36-16-61-60-36/37
RIDADR: UN 2765
WGK Germany: 2
RTECS: AG1575000
HazardClass: 9
PackingGroup: III
HS Code: 29189900
Hazardous Substances Data: 94-74-6(Hazardous Substances Data)
Toxicity: LD50 orally in rats: 700 mg/kg (Rowe, Hymas)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 45555
Product name: MCPA
Purity: PESTANAL
Packaging: 250mg
Price: $41.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 25190
Product name: 4-Chloro-2-methylphenoxyacetic acid
Purity: technical, ≥95.0% (T)
Packaging: 100g
Price: $143.4
Updated: 2024/03/01

TCI Chemical

Product number: C0206
Product name: (4-Chloro-2-methylphenoxy)acetic Acid
Purity: >98.0%(T)
Packaging: 25g
Price: $50
Updated: 2024/03/01

TCI Chemical

Product number: C0206
Product name: (4-Chloro-2-methylphenoxy)acetic Acid
Purity: >98.0%(T)
Packaging: 500g
Price: $385
Updated: 2024/03/01

TRC

Product number: C369470
Product name: 4-Chloro-2-methylphenoxyacetic acid
Packaging: 250mg
Price: $85
Updated: 2021/12/16

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2-Methyl-4-chlorophenoxyacetic acid Chemical Properties,Usage,Production

Description

MCPA is a colorless crystalline solid. Molecular weight= 200.63; Freezing/Melting point=118.8℃; Vapor pressure= 1.5×106 mmHg at 20℃. Insoluble in water.

Chemical Properties

White, crystalline solid. Free acid insoluble in water but sodium and amine salts are soluble.

Chemical Properties

MCPA is a colorless crystalline solid

Uses

Systemic postemergence herbicide used to control annual and perennial weeds in cereals, rice, flax, vines, peas, potatoes, asparagus, grassland and turf.

Uses

(4-Chloro-2-methylphenoxy)acetic Acid is a herbicide.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.

Uses

Labelled MCPA (C369470). Herbicide.

Definition

ChEBI: A chlorophenoxyacetic acid that is (4-chlorophenoxy)acetic acid substituted by a methyl group at position 2.

General Description

Colorless plates. Corrosive. Practically insoluble in water. Used as an herbicide.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-Methyl-4-chlorophenoxyacetic acid is a chlorinated benzoic acid derivative. Reacts as a weak acid to neutralize bases, both organic (for example, the amines) and inorganic. May corrode iron, steel, and aluminum parts and containers if moist. Reacts with cyanide salts in the presence of moisture to generate gaseous hydrogen cyanide. May react if moist with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A variety of products is possible. Like other acids, may initiate polymerization reactions or catalyze other reactions. is a chlorinated carboxylic acid herbicide. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in 2-Methyl-4-chlorophenoxyacetic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Agricultural Uses

Herbicide: A U.S. EPA restricted Use Pesticide (RUP) as MCPA, sodium salt. MCPA is a systemic post-emergence phenoxy herbicide used to control broadleaf annual and perennial weeds (including thistle and dock) in cereals, flax, rice, vines, peas, potatoes, grasslands, forestry applications, and on rights-of-way. It is very compatible with many other compounds and may be used in formulation with many other products, including bentazone, bromoxynil, 2,4-D, dicamba, fenoxaprop, MCPB, mecoprop, thifensulfuron, and tribenuron.

Trade name

ACME MCPA AMINE 4®; AGRITOX®; AGROXONE®; AGROZONE®; AGSCO®; ANICON KOMBI®; ANICON M®; BANLENE®; BLESEL MC®; BORDERMASTER®; BROMINAL M & PLUS®; CAMBILENE®; CHEYENNE®; CHIMAC OXY®; CHIPTOX®; CHWASTOX®; CORNOX M®; DAKOTA®; DED WEED®; DICOPUR-M®; DICOTEX®; DOW MCP AMINE WEED KILLER®; DYVEL®; EH1356 HERBICIDE®; EMCEPAN®; EMPAL®; ENVOY®; HEDAPUR M 52®; HEDAREX M®; HEDONAL M®; HERBICIDE M®; HORMOTUHO®; HORNOTUHO®; KILSEM®; 4 K-2 M®; KVK®; LEGUMEX DB®; LEUNA M®; LEYSPRAY®; LINORMONE®; M 40®; 2 M-4C®; 2 M-4KH®; MALERBANE®; MAYCLENE®; MEPHANAC®; MIDOX®; MXL®; OKULTIN®; PHENOXYLENE 50®; PHENOXYLENE PLUS®; PHENOXYLENE SUPER®; RAZOL DOCK KILLER®; RHOMENE®; RHONOX®; SHAMOX®; B-SELEKTONON M®; SEPPIC MMD®; TILLER®; TRIMEC®; U 46®; VACATE®; VESAKONTUHO®; WEEDAR®; WEEDAR MCPA CONCENTRATE®; WEEDONE MCPA ESTER®; WEED RHAP®; ZELAN®

Safety Profile

Suspected carcinogen. Poison by subcutaneous and intravenous routes. Moderately toxic by ingestion. Human systemic effects by ingestion: blood pressure decrease and coma. Experimental teratogenic and reproductive effects. Mutation data reported. An herbicide. When heated to decomposition it emits toxic fumes of Cl-.

Potential Exposure

A potential danger to those involved in the manufacture, formulation, and application of this postemergence herbicide, used for control of broadleaf weeds in agricultural applications.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Environmental Fate

Biological. Cell-free extracts isolated from Pseudomonas sp. in a basal salt medium degraded MCPA to 4-chloro-o-cresol and glyoxylic acid (Gamar and Gaunt, 1971).
Soil. Residual activity in soil is limited to approximately 3–4 months (Hartley and Kidd, 1987).
Plant. The penetration, translocation and metabolism of radiolabeled MCPA in a cornland weed (Galium aparine) was studied by Leafe (1962). Carbon dioxide was identified as a metabolite but this could only account 7% of the applied MCPA. Though no
Photolytic. When MCPA in dilute aqueous solution was exposed to summer sunlight or an indoor photoreactor (l >290 nm), 2-methyl-4-chlorophenol formed as the major product as well as o-cresol and 4-chloro-2-formylphenol (Soderquist and Crosby, 1975). Clapés et al. (1986) studied the photodecomposition of aqueous solution of MCPA (120 ppm, pH 5.4, 25°C) in a photoreactor equipped with a high pressure mercury lamp. After three minutes of irradiation, 4-chloro-2-methylphenol formed as an intermediate which degraded to 2-methylphenol. Both compounds were not detected after 6 minutes of irradiation; however, 1,4-dihydroxy-2-methylbenzene and 2-methyl-2,5-cyclohexadiene-1,4- dione formed as major and minor photodecomposition products, respectively. The same experiment was conducted using simulated sunlight (l <300 nm) in the presence of riboflavin, a known photosensitizer. 4-Chloro-2-methylphenol and 4-chloro-2-methylbenzyl formate formed as major and minor photoproducts, respectively (Clapés et al., 1986). Ozone degraded MCPA in dilute aqueous solution with and without UV light (l >300 nm) (Benoit-Guyod et al., 1986).
Chemical/Physical. Reacts with alkalies forming water soluble salts (Hartley and Kidd, 1987). Ozonolysis of MCPA in the dark yielded the following benzenoid intermediates: 4-chloro-2-methylphenol, its formate ester, 5-chlorosalicyaldehyde, 5-chlo

storage

Color Code—Blue: Health Hazard/Poison: Store in a secure poison location. Prior to working with this chemical you should be trained on its proper handling and storage. Store in tightly closed containers in a cool, wellventilated area. A regulated, marked area should be established where this chemical is handled, used, or stored in compliance with OSHA Standard 1910.1045.

Shipping

UN3345 Phenoxyacetic acid derivative pesticide, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

Purification Methods

It is insoluble in H2O (solubility is 0.55g/L at 20o) and recrystallises from *C6H6 or chlorobenzene as plates [J.nsson et al. Acta Chem Scand 6 993 1952]. The S-benzylisothiouronium salt has m 164-165o, and the Cu2+ salt has m 247-249o(dec) [Armarego et al. Nature 183 1176 1959, UV: Duvaux & Grabe Acta Chem Scand 4 806 1950, IR: J.berg Acta Chem Scand 4 798 1950]. [Beilstein 6 IV 1991.] It is a plant growth substance and a herbicide.

Incompatibilities

A weak acid. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur). Incompatible with alkalis.

Waste Disposal

Incineration with added flammable solvent; incinerator equipped with fume scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

2-Methyl-4-chlorophenoxyacetic acid Preparation Products And Raw materials

Raw materials

2 methyl 4-chloro sodium original drug Chloroacetic acid Phenol o-Cresol 4-Chloro-2-methylphenol

Preparation Products

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2-Methyl-4-chlorophenoxyacetic acid Suppliers

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View Lastest Price from 2-Methyl-4-chlorophenoxyacetic acid manufacturers

Wuhan Quanjinci New Material Co.,Ltd.

Product: 2-Methyl-4-chlorophenoxyacetic acid 94-74-6
Price: US $30.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000000 tons
Release date: 2023-11-07

Hebei Mojin Biotechnology Co., Ltd

Product: 2-Methyl-4-chlorophenoxyacetic acid 94-74-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-18

Hebei Guanlang Biotechnology Co., Ltd.

Product: 2-Methyl-4-chlorophenoxyacetic acid 94-74-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2022-10-31

94-74-6, 2-Methyl-4-chlorophenoxyacetic acidRelated Search:

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(4-CHLORO-O-TOLYOXY)ACETICACID

4-CHLORO-2-METHYLCHLOROPHENOXYACETICACID

2-Methyl-4-chlorphenoxyessigsure

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bhmcpa

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brominalm&plus

B-Selektonon M

b-selektononm

Campbell's MCPA 25, 50

Cekherbex

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Chiptox

Chloro-(O-cresoxy)acetic acid

Chloro-(O-tolyloxy)acetic acid

Chwastox

Chwastox 30

Chwastox F

chwastox30

chwastoxextra

CMP acetate

cornox

Cornox-M

Dicotex

Dikotes

Dikotex

Dow MCP amine weed killer

Emcepan

ethanoicacid,(4-chloro-2-methylphenoxy)-

Farmon MCPA 50

FBC MCPA

FLUID 4

Hedapur M 52

hedapurm52

Hedarex M

hedarexm

Hedonal M

hedonalm

Herbicide M

herbicidem

Hormotuho

Hornotuho

Kilsem

Kilsem4k-2m

Krezone

Kwas 4-chloro-2-metylofenoksyoctowy

kwas4-chloro-2-metylofenoksyoctowy

Kyselina 4-chlor-2-methylfenoxyoctova

kyselina4-chlor-2-methylfenoxyoctova

Legumex db

legumexdb

Leuna M