ChemicalBook > CAS DataBase List > (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide

Product Name
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
CAS No.
52509-14-5
Chemical Name
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
Synonyms
OMTPPB;96.0%(T);2-(1,3)-DIO;LABOTEST-BB LT00233112;Amyl 4-Carboxyphenyl Carbonate >(1,3-DIOXOLAN-2-YL)-METHYLTRIPHENYLPHOSP;1,3-dioxolan-2-ylmethyl(triphenyl)phosphanium;1,3-Dioxolan-2-ylmethyl-triphenylphosphanium bromide;(1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE;TRIPHENYL-1,3-DIOXOLAN-2-YLMETHYL-PHOSPHONIUM BROMIDE
CBNumber
CB0176860
Molecular Formula
C22H22BrO2P
Formula Weight
429.29
MOL File
52509-14-5.mol
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(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Property

Melting point:
193-195 °C(lit.)
storage temp. 
Store below +30°C.
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder or Crystals
color 
White to light brown
Water Solubility 
Soluble in water (20°C).
Sensitive 
Hygroscopic
InChIKey
FRHRVQQUICVJDG-UHFFFAOYSA-M
CAS DataBase Reference
52509-14-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29329970
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.18094
Product name
(1,3-Dioxolan-2-yl)-methyltriphenylphosphonium bromide
Purity
for synthesis
Packaging
10G
Price
$141
Updated
2024/03/01
Sigma-Aldrich
Product number
223859
Product name
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
5g
Price
$71.2
Updated
2023/01/07
TCI Chemical
Product number
D2164
Product name
(1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide
Purity
>97.0%(T)
Packaging
5g
Price
$42
Updated
2024/03/01
TCI Chemical
Product number
D2164
Product name
(1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide
Purity
>97.0%(T)
Packaging
25g
Price
$144
Updated
2024/03/01
Alfa Aesar
Product number
A18882
Product name
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%
Packaging
10g
Price
$66.65
Updated
2024/03/01
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(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Chemical Properties,Usage,Production

Chemical Properties

white to light brown granular powder

Uses

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium Bromide is used as a reactant in the synthesis of ketolides methyloxoerythromycins with antibacterial activity as highly potent against macrolide-resistant and susceptible respiratory pathogens.

Uses

Reactant for:

  • Preparation of a ratiometric fluorescent probe for specific detection of cysteine over homocysteine and glutathione
  • Microwave-assisted synthesis of KN-93 as inhibitor of calmodulin kinase II
  • Preparation of fluorinated spirobenzofuran piperidines as s1 receptor ligands
  • Synthesis and antitumor agents
  • Regio-selective preparation of indole derivatives via rhodium-catalyzed domino hydroformylation/indolization

Purification Methods

Wash the crystals with Et2O, dry them in a vacuum and recrystallise them from CH2Cl2/dry Et2O to give prisms m 172-174o, which is raised to 191.5-193o on drying at 56o/0.5mm. [Cresp et al. J Chem Soc, Perkin Trans 1 37 1974.]

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Suppliers

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View Lastest Price from (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide manufacturers

Henan Fengda Chemical Co., Ltd
Product
((1,3-Dioxolan-2-yl)methyl)triphenylphosphonium bromide 52509-14-5
Price
US $8.00-0.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-14
Hebei Duling International Trade Co. LTD
Product
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide 52509-14-5
Price
US $20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 tons
Release date
2023-01-15
WUHAN FORTUNA CHEMICAL CO., LTD
Product
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide 52509-14-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-08

52509-14-5, (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromideRelated Search:

Rocuronium bromide Diphenylphosphine 2-Bromomethyl-1,3-dioxolane Ethidium bromide Tetrakis(triphenylphosphine)palladium Sodium bromate Triphenylphosphine Methylmagnesium Bromide Methyl cyclopentenolone DBDCB Chlorodiphenylphosphine Triphenylphosphine hydrobromide METHYLCYCLOPENTADIENE DIMER Chlorodimethylphenylsilane Sodium bromide Allyl bromide Bromo-PEG1-t-butyl ester Diethyl bromodifluoromethanephosphonate

  • LABOTEST-BB LT00233112
  • (1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
  • (1,3-DIOXOLANE-2-YL METHYL) TRIPHENYL PHOSPHONIUM BROMIDE
  • TRIPHENYL-1,3-DIOXOLAN-2-YLMETHYL-PHOSPHONIUM BROMIDE
  • 2-(1,3)-DIOXOLANE-2-YL-METHYLTRIPHENYLPHOSPHONIUM BROMIDE
  • (1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE 98%
  • (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98 %
  • Phosphonium, (1,3-dioxolan-2-ylmethyl)triphenyl-, bromide
  • 1,3-Dioxolan-2-ylmethyl-triphenylphosphanium bromide
  • Triphenyl(1,3-dioxolane-2-ylmethyl)phosphonium·bromide
  • (1,3-DIOXOLAN-2-YL)-METHYLTRIPHENYLPHOSP
  • 2-(1,3)-DIO
  • OMTPPB
  • (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%, for synthesis
  • (1,3-Dioxolan-2-yl)methyltriphenylphosphoniumBromide&gt
  • N-1-NaphthylethylenediamineDihydrochlorideMonomethanolate&gt
  • 96.0%(T)
  • Amyl 4-Carboxyphenyl Carbonate &gt
  • 1,3-dioxolan-2-ylmethyl(triphenyl)phosphanium
  • 52509-14-5
  • C22H22BrO2P
  • C22H22O2PBr
  • C22H24BrO2P
  • Wittig Reaction
  • Phosphonium Compounds
  • C-C Bond Formation
  • Wittig Reagents
  • Synthetic Reagents
  • Olefination
  • Wittig & Horner-Emmons Reaction
  • Dioxanes & Dioxolanes
  • Dioxolanes
  • Dioxanes & Dioxolanes
  • Dioxolanes
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents