Chlorodimethylphenylsilane
- Product Name
- Chlorodimethylphenylsilane
- CAS No.
- 768-33-2
- Chemical Name
- Chlorodimethylphenylsilane
- Synonyms
- DMPSCl;PHENYLDIMETHYLCHLOROSILANE;DIMETHYLPHENYLSILYLCHLORIDE;DK394;DK900;DK437;CP0160;DMPSCI;DKFELEX0239;CHLORODIMETHYLPHENYLSILANE
- CBNumber
- CB0480954
- Molecular Formula
- C8H11ClSi
- Formula Weight
- 170.71
- MOL File
- 768-33-2.mol
Chlorodimethylphenylsilane Property
- Melting point:
- <0°C
- Boiling point:
- 194-198 °C
- Density
- 1.017 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.509(lit.)
- Flash point:
- 143 °F
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Miscible with tetrahydrofuran, ether and hexane.
- form
- clear liquid
- color
- Colorless to Light yellow
- Specific Gravity
- 1.017
- Water Solubility
- MAY DECOMPOSE
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Sensitive
- Moisture Sensitive
- BRN
- 606292
- InChIKey
- KWYZNESIGBQHJK-UHFFFAOYSA-N
- CAS DataBase Reference
- 768-33-2(CAS DataBase Reference)
- NIST Chemistry Reference
- Silane, chlorodimethylphenyl-(768-33-2)
- EPA Substance Registry System
- Silane, chlorodimethylphenyl- (768-33-2)
Safety
- Hazard Codes
- C
- Risk Statements
- 34-37
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 2987 8/PG 2
- WGK Germany
- 1
- F
- 10-21
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 113379
- Product name
- Chloro(dimethyl)phenylsilane
- Purity
- 98%
- Packaging
- 5g
- Price
- $63
- Updated
- 2025/07/31
- Product number
- 113379
- Product name
- Chloro(dimethyl)phenylsilane
- Purity
- 98%
- Packaging
- 25g
- Price
- $203
- Updated
- 2025/07/31
- Product number
- D1147
- Product name
- Chlorodimethylphenylsilane
- Purity
- >96.0%(GC)
- Packaging
- 5mL
- Price
- $29
- Updated
- 2025/07/31
- Product number
- D1147
- Product name
- Chlorodimethylphenylsilane
- Purity
- >96.0%(GC)
- Packaging
- 25mL
- Price
- $73
- Updated
- 2025/07/31
- Product number
- P319735
- Product name
- Phenyldimethylchlorosilane
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
Chlorodimethylphenylsilane Chemical Properties,Usage,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.
Application
Chlorodimethylphenylsilane can be used for nucleophilic silylation; alcohol derivatization; antenna chromophores; enolate capture; and Kumada-FlemingTamao oxidation.
Hazard
Chlorodimethylphenylsilane is a combustible liquid, it can causes severe skin burns and eye damage.
storage
Like other chlorosilanes, this compound can be destructive to tissue of the mucous membranes, upper respiratory tract, eyes and skin. Store in a cool dry place; the compound is moisture sensitive.
Purification Methods
Fractionate it through a 1.5 x 18inch column packed with stainless steel helices, or a spinning band column. [Daudt & Hyde J Am Chem Soc 74 386 1952, Lewis et al. J Am Chem Soc 70 1115 1948, Eaborn J Chem Soc 494 1953.] It is used for standardising MeLi or MeMgBr which form Me3PhSi which is estimated by GC. [Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Beilstein 16 IV 1475.] TOXIC and MOISTURE SENSITIVE.
Chlorodimethylphenylsilane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Chlorodimethylphenylsilane manufacturers
- Product
- Chlorodimethylphenylsilane 768-33-2
- Price
- US $0.00/Kg/Drum
- Min. Order
- 1Kg/Drum
- Purity
- 96%min
- Supply Ability
- 200TON
- Release date
- 2025-08-14
- Product
- Dimethylphenylchlorosilane 768-33-2
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98.0%min
- Supply Ability
- 100mt per month
- Release date
- 2025-06-12
- Product
- Chlorodimethylphenylsilane 768-33-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-12-11