Chlorodimethylphenylsilane
- Product Name
- Chlorodimethylphenylsilane
- CAS No.
- 768-33-2
- Chemical Name
- Chlorodimethylphenylsilane
- Synonyms
- DMPSCl;PHENYLDIMETHYLCHLOROSILANE;DIMETHYLPHENYLSILYLCHLORIDE;DK394;DK900;DK437;CP0160;DMPSCI;DKFELEX0239;CHLORODIMETHYLPHENYLSILANE
- CBNumber
- CB0480954
- Molecular Formula
- C8H11ClSi
- Formula Weight
- 170.71
- MOL File
- 768-33-2.mol
Chlorodimethylphenylsilane Property
- Melting point:
- <0°C
- Boiling point:
- 194-198 °C
- Density
- 1.017 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.509(lit.)
- Flash point:
- 143 °F
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Miscible with tetrahydrofuran, ether and hexane.
- form
- clear liquid
- color
- Colorless to Light yellow
- Specific Gravity
- 1.017
- Water Solubility
- MAY DECOMPOSE
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Sensitive
- Moisture Sensitive
- BRN
- 606292
- InChIKey
- KWYZNESIGBQHJK-UHFFFAOYSA-N
- CAS DataBase Reference
- 768-33-2(CAS DataBase Reference)
- NIST Chemistry Reference
- Silane, chlorodimethylphenyl-(768-33-2)
- EPA Substance Registry System
- Silane, chlorodimethylphenyl- (768-33-2)
Safety
- Hazard Codes
- C
- Risk Statements
- 34-37
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 2987 8/PG 2
- WGK Germany
- 1
- F
- 10-21
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 113379
- Product name
- Chloro(dimethyl)phenylsilane
- Purity
- 98%
- Packaging
- 5g
- Price
- $61.1
- Updated
- 2024/03/01
- Product number
- 113379
- Product name
- Chloro(dimethyl)phenylsilane
- Purity
- 98%
- Packaging
- 25g
- Price
- $197
- Updated
- 2024/03/01
- Product number
- D1147
- Product name
- Chlorodimethylphenylsilane
- Purity
- >96.0%(GC)
- Packaging
- 5mL
- Price
- $29
- Updated
- 2024/03/01
- Product number
- D1147
- Product name
- Chlorodimethylphenylsilane
- Purity
- >96.0%(GC)
- Packaging
- 25mL
- Price
- $73
- Updated
- 2024/03/01
- Product number
- A15638
- Product name
- Chlorodimethylphenylsilane, 97+%
- Packaging
- 5g
- Price
- $36.65
- Updated
- 2024/03/01
Chlorodimethylphenylsilane Chemical Properties,Usage,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.
Purification Methods
Fractionate it through a 1.5 x 18inch column packed with stainless steel helices, or a spinning band column. [Daudt & Hyde J Am Chem Soc 74 386 1952, Lewis et al. J Am Chem Soc 70 1115 1948, Eaborn J Chem Soc 494 1953.] It is used for standardising MeLi or MeMgBr which form Me3PhSi which is estimated by GC. [Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Beilstein 16 IV 1475.] TOXIC and MOISTURE SENSITIVE.
Chlorodimethylphenylsilane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Chlorodimethylphenylsilane manufacturers
- Product
- Chlorodimethylphenylsilane 768-33-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2022-12-10
- Product
- Chlorodimethylphenylsilane 768-33-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-30
- Product
- Chlorodimethylphenylsilane 768-33-2
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11