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Chlorodimethylphenylsilane

Product Name
Chlorodimethylphenylsilane
CAS No.
768-33-2
Chemical Name
Chlorodimethylphenylsilane
Synonyms
DMPSCl;PHENYLDIMETHYLCHLOROSILANE;DIMETHYLPHENYLSILYLCHLORIDE;DK394;DK900;DK437;CP0160;DMPSCI;CHLORODIMETHYLPHENYLSILANE;chlorodimethylphenyl-silan
CBNumber
CB0480954
Molecular Formula
C8H11ClSi
Formula Weight
170.71
MOL File
768-33-2.mol
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Chlorodimethylphenylsilane Property

Melting point:
<0°C
Boiling point:
194-198 °C
Density 
1.017 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.509(lit.)
Flash point:
143 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Miscible with tetrahydrofuran, ether and hexane.
form 
clear liquid
color 
Colorless to Light yellow
Specific Gravity
1.017
Water Solubility 
MAY DECOMPOSE
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Sensitive 
Moisture Sensitive
BRN 
606292
InChIKey
KWYZNESIGBQHJK-UHFFFAOYSA-N
CAS DataBase Reference
768-33-2(CAS DataBase Reference)
NIST Chemistry Reference
Silane, chlorodimethylphenyl-(768-33-2)
EPA Substance Registry System
Silane, chlorodimethylphenyl- (768-33-2)
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Safety

Hazard Codes 
C
Risk Statements 
34-37
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2987 8/PG 2
WGK Germany 
1
10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
113379
Product name
Chloro(dimethyl)phenylsilane
Purity
98%
Packaging
5g
Price
$61.1
Updated
2024/03/01
Sigma-Aldrich
Product number
113379
Product name
Chloro(dimethyl)phenylsilane
Purity
98%
Packaging
25g
Price
$197
Updated
2024/03/01
TCI Chemical
Product number
D1147
Product name
Chlorodimethylphenylsilane
Purity
>96.0%(GC)
Packaging
5mL
Price
$29
Updated
2024/03/01
TCI Chemical
Product number
D1147
Product name
Chlorodimethylphenylsilane
Purity
>96.0%(GC)
Packaging
25mL
Price
$73
Updated
2024/03/01
Alfa Aesar
Product number
A15638
Product name
Chlorodimethylphenylsilane, 97+%
Packaging
5g
Price
$36.65
Updated
2024/03/01
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Chlorodimethylphenylsilane Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.

Purification Methods

Fractionate it through a 1.5 x 18inch column packed with stainless steel helices, or a spinning band column. [Daudt & Hyde J Am Chem Soc 74 386 1952, Lewis et al. J Am Chem Soc 70 1115 1948, Eaborn J Chem Soc 494 1953.] It is used for standardising MeLi or MeMgBr which form Me3PhSi which is estimated by GC. [Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Beilstein 16 IV 1475.] TOXIC and MOISTURE SENSITIVE.

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View Lastest Price from Chlorodimethylphenylsilane manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
Chlorodimethylphenylsilane 768-33-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2022-12-10
Henan Aochuang Chemical Co.,Ltd.
Product
Chlorodimethylphenylsilane 768-33-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Zhuozhou Wenxi import and Export Co., Ltd
Product
Chlorodimethylphenylsilane 768-33-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

768-33-2, ChlorodimethylphenylsilaneRelated Search:


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  • ChlorodiMethylphenylsilane, 95% 25GR
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  • Benzene, (chlorodiMethylsilyl)-
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  • Chlorodimethylphenylsilane, 97%, for synthesis
  • DK394
  • DK900
  • DK437
  • 768-33-2
  • C8H11ClS1
  • C8H11ClSi
  • C6H5SiCH32Cl
  • C8H11SiCl
  • Si (Classes of Silicon Compounds)
  • Monochlorosilanes
  • Si-Cl Compounds
  • Silicon Compounds (for Synthesis)
  • Protecting and Derivatizing Reagents
  • Protection and Derivatization
  • Silicon-Based
  • Synthetic Reagents
  • Monochlorosilanes
  • Si (Classes of Silicon Compounds)
  • Si-Cl Compounds
  • Silicon Compounds (for Synthesis)
  • Synthetic Organic Chemistry