ChemicalBook > CAS DataBase List > Chlorodimethylphenylsilane

Chlorodimethylphenylsilane

Product Name
Chlorodimethylphenylsilane
CAS No.
768-33-2
Chemical Name
Chlorodimethylphenylsilane
Synonyms
DMPSCl;PHENYLDIMETHYLCHLOROSILANE;DIMETHYLPHENYLSILYLCHLORIDE;DK394;DK900;DK437;CP0160;DMPSCI;CHLORODIMETHYLPHENYLSILANE;chlorodimethylphenyl-silan
CBNumber
CB0480954
Molecular Formula
C8H11ClSi
Formula Weight
170.71
MOL File
768-33-2.mol
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Chlorodimethylphenylsilane Property

Melting point:
<0°C
Boiling point:
194-198 °C
Density 
1.017 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.509(lit.)
Flash point:
143 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Miscible with tetrahydrofuran, ether and hexane.
form 
clear liquid
color 
Colorless to Light yellow
Specific Gravity
1.017
Water Solubility 
MAY DECOMPOSE
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Sensitive 
Moisture Sensitive
BRN 
606292
InChIKey
KWYZNESIGBQHJK-UHFFFAOYSA-N
CAS DataBase Reference
768-33-2(CAS DataBase Reference)
NIST Chemistry Reference
Silane, chlorodimethylphenyl-(768-33-2)
EPA Substance Registry System
Silane, chlorodimethylphenyl- (768-33-2)
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Safety

Hazard Codes 
C
Risk Statements 
34-37
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2987 8/PG 2
WGK Germany 
1
F 
10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
113379
Product name
Chloro(dimethyl)phenylsilane
Purity
98%
Packaging
5g
Price
$61.1
Updated
2024/03/01
Sigma-Aldrich
Product number
113379
Product name
Chloro(dimethyl)phenylsilane
Purity
98%
Packaging
25g
Price
$197
Updated
2024/03/01
TCI Chemical
Product number
D1147
Product name
Chlorodimethylphenylsilane
Purity
>96.0%(GC)
Packaging
5mL
Price
$29
Updated
2024/03/01
TCI Chemical
Product number
D1147
Product name
Chlorodimethylphenylsilane
Purity
>96.0%(GC)
Packaging
25mL
Price
$73
Updated
2024/03/01
Alfa Aesar
Product number
A15638
Product name
Chlorodimethylphenylsilane, 97+%
Packaging
5g
Price
$36.65
Updated
2024/03/01
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Chlorodimethylphenylsilane Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.

Purification Methods

Fractionate it through a 1.5 x 18inch column packed with stainless steel helices, or a spinning band column. [Daudt & Hyde J Am Chem Soc 74 386 1952, Lewis et al. J Am Chem Soc 70 1115 1948, Eaborn J Chem Soc 494 1953.] It is used for standardising MeLi or MeMgBr which form Me3PhSi which is estimated by GC. [Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Beilstein 16 IV 1475.] TOXIC and MOISTURE SENSITIVE.

Chlorodimethylphenylsilane Preparation Products And Raw materials

Raw materials

Copper(I) Cyanide Hexane Nitrogen Toluene Bis(benzonitrile)palladium chloride Bromobenzene Tetrahydrofuran Diethyl ether Iodine CHLORO(DIETHYLAMINO)DIMETHYLSILANE 97 Triphenylphosphine Dichlorodimethylsilane Benzoyl chloride PETROLEUM ETHER Magnesium Lithium

Preparation Products

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View Lastest Price from Chlorodimethylphenylsilane manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
Chlorodimethylphenylsilane 768-33-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2022-12-10
Henan Aochuang Chemical Co.,Ltd.
Product
Chlorodimethylphenylsilane 768-33-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Zhuozhou Wenxi import and Export Co., Ltd
Product
Chlorodimethylphenylsilane 768-33-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

768-33-2, ChlorodimethylphenylsilaneRelated Search:

DIMETHYLSILANE Dimethyldimethoxysilane tert-Butyldimethylsilyl chloride Diethoxydimethylsilane PHENYLACETOXYTRIMETHYLSILANE Phenyltris(trimethylsiloxy)silane Trimethoxyphenylsilane Chloro(chloromethyl)dimethylsilane DIMETHYLTHEXYLSILYL CHLORIDE PHENYLDICHLOROSILANE Chloromethyl silane CHLOROPHENYLSILANE 97 Phenyltrichlorosilane Phenyltriethoxysilane CHLORODIMETHYLVINYLSILANE Dichlorodiphenylsilane 3,5-Bis(trifluoromethyl)phenyldimethylchlorosilane Chlorodimethylpentafluorophenylsilane

  • PHENYLDIMETHYLCHLOROSILANE
  • CHLORODIMETHYLPHENYLSILANE
  • DMPSCI
  • DIMETHYLPHENYLSILYLCHLORIDE
  • DIMETHYLPHENYL-CHLOROSILANE
  • chlorodimethylphenyl-silan
  • CP0160
  • Dimethylphenylchlorosilane~Dimethylphenylsilyl chloride~DMPSCl~Phenyldimethylchlorosilane
  • Phenyldimethylchlorosilane(Chlorodimethylphenylsilane)
  • Chlorodimethylphenylsilane,97%
  • Chlorodimethylphenylsilane ,95%
  • Phenylchlorodimethylsilane
  • Chloro(dimethyl)phenylsilane,DMPSCl, Dimethylphenylchlorosilane, Dimethylphenylsilylchloride, Phenyldimethylchlorosilane
  • ChlorodiMethylphenylsilane, 95% 25GR
  • DMPSCl
  • Benzene, (chlorodiMethylsilyl)-
  • Chlorodimethylphenylsilane &gt
  • Chlorodimethylphenylsilane, 97%, for synthesis
  • DK394
  • DK900
  • DK437
  • 768-33-2
  • C8H11ClS1
  • C8H11ClSi
  • C6H5SiCH32Cl
  • C8H11SiCl
  • Si (Classes of Silicon Compounds)
  • Monochlorosilanes
  • Si-Cl Compounds
  • Silicon Compounds (for Synthesis)
  • Protecting and Derivatizing Reagents
  • Protection and Derivatization
  • Silicon-Based
  • Synthetic Reagents
  • Monochlorosilanes
  • Si (Classes of Silicon Compounds)
  • Si-Cl Compounds
  • Silicon Compounds (for Synthesis)
  • Synthetic Organic Chemistry