I-PROPYLISOCYANIDE
- Product Name
- I-PROPYLISOCYANIDE
- CAS No.
- 598-45-8
- Chemical Name
- I-PROPYLISOCYANIDE
- Synonyms
- 2-isocyanopropane;1-Propylisocyanide;I-PROPYLISOCYANIDE;2-Isocyano-propane;2-Isonitrilopropane;ISOPROPYLISOCYANIDE;Isopropyl-isonitrile;isopropylcarbylamine;i-Propylisocyanide,99%;Isopropyl isocyanide 97%
- CBNumber
- CB0182698
- Molecular Formula
- C4H7N
- Formula Weight
- 69.11
- MOL File
- 598-45-8.mol
I-PROPYLISOCYANIDE Property
- Boiling point:
- 75 °C(lit.)
- Density
- 0.733 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.371(lit.)
- Flash point:
- 69 °F
- storage temp.
- 2-8°C
- form
- liquid
- Specific Gravity
- 0.7596
- color
- colorless
- Stability:
- store cold
Safety
- Hazard Codes
- F,T
- Risk Statements
- 11-23/24/25
- Safety Statements
- 16-23-26-33-36/37/39-45
- RIDADR
- UN 1992 3/PG 2
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
N-Bromosuccinimide Price
- Product number
- 553344
- Product name
- Isopropyl isocyanide
- Purity
- 97%
- Packaging
- 500mg
- Price
- $103.2
- Updated
- 2024/03/01
- Product number
- 06-1850
- Product name
- i-Propylisocyanide, min. 97%
- Packaging
- 1g
- Price
- $328
- Updated
- 2024/03/01
- Product number
- 06-1850
- Product name
- i-Propylisocyanide, min. 97%
- Packaging
- 5g
- Price
- $1308
- Updated
- 2024/03/01
- Product number
- CHM0117010
- Product name
- ISOPROPYL ISOCYANIDE
- Purity
- 95.00%
- Packaging
- 500MG
- Price
- $586.49
- Updated
- 2021/12/16
- Product number
- 1005649
- Product name
- PN101196:Isopropylisocyanide
- Purity
- 95
- Packaging
- 5G
- Price
- $720
- Updated
- 2021/12/16
I-PROPYLISOCYANIDE Chemical Properties,Usage,Production
Uses
Isopropyl isocyanide may be used in the preparation of:
- Ugi ligand A2C11I1, which is employed in the solid-phase Ugi synthesis.
- Pentafluorophenyl (PFP) functional monomers, via Passerini reaction.
- Dinuclear copper complex [Cu2(μ-PiPr2bipy)2{μ-CNCH(CH3)2}](PF6)2 [PiPr2bipy = 6-(diisopropylphosphanyl)-2,2′-bipyridine].
- (3E)-(Imino)thiaisoindoline 1,1-dioxide derivative.
- N,N′-diisopropylcarbodiimide (DIC) analog via reaction with propan-2-amine.
- 1-t-butyl-2-isopropyldiaziridinone via reaction with 2-methyl-2-nitrosopropane
- isopropyl isocyanate via reaction with ozone
- 1-phthalimidoazetidines via [1+3]cycloaddition reaction with 1-pththalimidoaziridines
Preparation
To a flask containing 100 ml (0.85 mole) of distilled quinoline is added with stirring 41 gm (0.214 mole) of /7-toluenesulfonyl chloride (see Note), and the solution is warmed to 75°C. Then 18.4 gm (0.212 mole) of isopropylformamide is added and the pressure of the system is reduced to 70 mm Hg. The isopropylisonitrile as it forms distills into a liquid nitrogencooled receiver. (Dry ice is not as effective but may be used.) The product is redistilled to afford 4.2 gm (30%), b.p. 88-89°C (735 mm Hg).
General Description
Isopropyl isocyanide is an alkyl isocyanide.
I-PROPYLISOCYANIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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