ChemicalBook > CAS DataBase List > BENZENETHIOSULFONIC ACID S-PHENYL ESTER

BENZENETHIOSULFONIC ACID S-PHENYL ESTER

Product Name
BENZENETHIOSULFONIC ACID S-PHENYL ESTER
CAS No.
1212-08-4
Chemical Name
BENZENETHIOSULFONIC ACID S-PHENYL ESTER
Synonyms
NSC74657;Phenylphenylthiosulfone;Phenylbenzenethiosulfonate;S- phenylthiophenylsulfone;S-PHENYL BENZENETHIOSULFATE;(phenylthio)sulfonylbenzene;phenylsulfanylsulfonylbenzene;S-PHENYL BENZENETHIOSULFONATE;S-phenylbenzenethiosulphonate;S-PHENYLBENZENESULFONOTHIOATE
CBNumber
CB0189293
Molecular Formula
C12H10O2S2
Formula Weight
250.34
MOL File
1212-08-4.mol
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BENZENETHIOSULFONIC ACID S-PHENYL ESTER Property

Melting point:
36-53 °C(lit.)
Boiling point:
125 °C(Press: 0.01 Torr)
Density 
1.35±0.1 g/cm3(Predicted)
Flash point:
>230 °F
storage temp. 
-20°C Freezer
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Very Slightly)
form 
Solid
color 
Off-White
BRN 
1530592
InChIKey
ATKJLMWDXASAJA-UHFFFAOYSA-N
EPA Substance Registry System
Benzenesulfonothioic acid, S-phenyl ester (1212-08-4)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
390267
Product name
S-Phenyl benzenethiosulfonate
Purity
99%
Packaging
1g
Price
$223
Updated
2024/03/01
Sigma-Aldrich
Product number
390267
Product name
S-Phenyl benzenethiosulfonate
Purity
99%
Packaging
5g
Price
$575
Updated
2024/03/01
TRC
Product number
P319595
Product name
S-Phenyl benzenethiosulfonate
Packaging
1g
Price
$150
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
OGM0001340
Product name
S-PHENYL BENZENETHIOSULFONATE
Purity
95.00%
Packaging
1G
Price
$681.81
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
61124
Product name
S-Phenyl benzenethiosulfonate
Packaging
25g
Price
$1300
Updated
2021/12/16
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BENZENETHIOSULFONIC ACID S-PHENYL ESTER Chemical Properties,Usage,Production

Uses

S-Phenyl Benzenethiosulfonate is an high potency antifungal thiosulfonate that were tested against Aspergillus niger and Aspergillus flavus.

Preparation

BENZENETHIOSULFONIC ACID S-PHENYL ESTER can be prepared by oxidation of Diphenyl Disulfide with 30% Hydrogen Peroxide (72%).

Synthesis Reference(s)

Journal of the American Chemical Society, 99, p. 4405, 1977 DOI: 10.1021/ja00455a032
Tetrahedron Letters, 10, p. 1239, 1969

Purification Methods

Recrystallise the disulfoxide from EtOH or MeOH. It has also been purified from phenylsulfide impurities by dissolving in CHCl3, washing with aqueous saturated NaHCO3, drying (Na2SO4), filtering, evaporating the filtrate, and the residual oil is passed through a silica gel column (600g) and eluted with hexane/*C6H6 (1L, 4:1, eluting PhSSPh) then *C6H6 (1L) which elutes PhSSO2Ph. [Trost & Massiot J Am Chem Soc 99 4405 1977, Knoevenagel & R.mer Chem Ber 56 215 1923, Beilstein 11 IV 220.]

BENZENETHIOSULFONIC ACID S-PHENYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZENETHIOSULFONIC ACID S-PHENYL ESTER Suppliers

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View Lastest Price from BENZENETHIOSULFONIC ACID S-PHENYL ESTER manufacturers

Career Henan Chemical Co
Product
BENZENETHIOSULFONIC ACID S-PHENYL ESTER 1212-08-4
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2020-01-08
Career Henan Chemical Co
Product
BENZENETHIOSULFONIC ACID S-PHENYL ESTER 1212-08-4
Price
US $3.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
200KG
Release date
2020-01-07

1212-08-4, BENZENETHIOSULFONIC ACID S-PHENYL ESTERRelated Search:

2,5-DIMETHYL-BENZENETHIOSULFONIC ACID S-(2,5-DIMETHYL-PHENYL) ESTER DIPHENYL DISULFIDE methyl methanethiosulfinate BENZENETHIOSULFONIC ACID S-PHENYL ESTER S-Methyl methanethiolsulfonate PHENYLMETHANETHIOSULFONATE METHYL PHENYL DISULFIDE

  • (phenylthio)sulfonylbenzene
  • phenylsulfanylsulfonylbenzene
  • S-Phenyl benzenethiosulfonate 99%
  • BENZENETHIOSULFONIC ACID S-PHENYL ESTER
  • S-PHENYL BENZENETHIOSULFATE
  • S-PHENYL BENZENETHIOSULFONATE
  • Benzenesulfonicacid,thio-,S-phenylester
  • NSC74657
  • Phenylbenzenethiosulfonate
  • Phenylphenylthiosulfone
  • S-Phenylbenzenemonothiosulfonate
  • S-phenylbenzenethiosulphonate
  • S-PHENYLBENZENESULFONOTHIOATE
  • (Phenylsulfonyl)phenyl sulfide
  • Benzenethiosulfonic acid S-phenyl
  • Phenyl(phenylsulfonyl) sulfide
  • benzenesulfonylsulfanylbenzene
  • S- phenylthiophenylsulfone
  • Benzenesulfonothioic acid, S-phenyl ester
  • TIANFUCHEM 1212-08-4 BENZENETHIOSULFONIC ACID S-PHENYL ESTER
  • 1212-08-4
  • C6H5SO2SC6H5
  • Building Blocks
  • Sulfonates/Sulfinates
  • Sulfur Compounds
  • Organic Building Blocks
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Sulfonates/Sulfinates
  • Sulfur Compounds