ChemicalBook > CAS DataBase List > 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

Product Name
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
CAS No.
173035-10-4
Chemical Name
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
Synonyms
SIMes.HCl;1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride;1,3-diMesityl-4,5-dihydro-1H-iMidazol-3-iuM chloride;1,3-Bis(2;inium ChL;1,3-Bis-(2,4,6-;1,3-Dimesitylimidazolidinium chloride;1,3-DiMesityliMidazolidin-1-iuM chloride;1,3-Bis-(2,4,6-trimethylphenyl)imidazolidinium;4,5-Dihydro-1,3-dimesityl-1H-imidazolium chloride
CBNumber
CB0197636
Molecular Formula
C21H29ClN2
Formula Weight
344.92
MOL File
173035-10-4.mol
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1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Property

Melting point:
280-286 °C
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
Beige to pink-brown
Sensitive 
air sensitive
InChIKey
COGMCBFILULEOS-UHFFFAOYSA-M
CAS DataBase Reference
173035-10-4
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-36
WGK Germany 
3
TSCA 
No
HS Code 
29332990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
656631
Product name
1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride
Purity
95%
Packaging
1g
Price
$55.56
Updated
2024/03/01
Sigma-Aldrich
Product number
656631
Product name
1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride
Purity
95%
Packaging
5g
Price
$155
Updated
2024/03/01
TCI Chemical
Product number
B3158
Product name
1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride
Purity
>98.0%(HPLC)(T)
Packaging
1g
Price
$71
Updated
2024/03/01
TCI Chemical
Product number
B3158
Product name
1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride
Purity
>98.0%(HPLC)(T)
Packaging
5g
Price
$247
Updated
2024/03/01
Strem Chemicals
Product number
07-4011
Product name
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride, min. 97%
Packaging
500mg
Price
$53
Updated
2024/03/01
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1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

beige to pink-brown powder

Uses

N-Heterocyclic Carbene Ligands Precursor to an N-heterocyclic carbene catalysts

Uses

N-Heterocyclic Carbene Ligands

Precursor to an N-heterocyclic carbene catalysts used for:

  • A regioselective cycloadditon of terminal acetylenes with azides leading to 1,4-disubstitutedtriazoles. Internal acetylenes can also be used with this catalyst.
  • Markovnikov-type hydration of terminal alkynes
  • Hydrosilylation of ketones and cycloaddition of azides and alkynes
  • Suzuki-Miyaura reactions
  • Luminescence experiments

General Description

1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride is an NHC (N-heterocyclic carbene) ligand which can bind with metal pre-catalysts to form complexes that show high catalytic activity.

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Suppliers

Americas 1 Belgium 1 China 174 Czech 1 Europe 1 Germany 5 India 2 Japan 1 Poland 1 Russia 1 Switzerland 1 United Kingdom 1 United States 15 Global 205
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View Lastest Price from 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride 173035-10-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Longyan Tianhua Biological Technology Co., Ltd
Product
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE 173035-10-4
Price
US $9.00/Kg/Bag
Min. Order
25Kg/Bag
Purity
99%
Supply Ability
20 Tons
Release date
2020-11-11
Career Henan Chemical Co
Product
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE 173035-10-4
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-07-04

173035-10-4, 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDERelated Search:

1,3-Bis (2,6-diisopropylphenyl) imidazolium chloride 1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE 1,3-Bis(2,6-di-isopropylphenyl)imidazol-2-ylidenegold(I)chloride,95% Ruthenium(III) chloride hydrate (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM GRUBBS CATALYST 2ND GENERATION 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride Umicore M42 Tricyclohexylphosphine[3-phenyl-1H-inden-1-ylidene][1,3-bis(2,4,6-triMethylphenyl)-4,5-dihydroiMidazol-2-ylidene]rutheniuM(II) Umicore M41 (1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDA& Isopentenylidene(1,3-dimesitylimidazolidin-2-ylidene) (tricyclohexylphosphine)ruthenium(II) dichloride RUTHENIUM, [1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO-[[2-ISOPROPOXY-5-(N-RESIN-LINKED AMINOSULFONYL)PHENYL]METHYLENE] TRICYCLOHEXYLPHOSPHINE[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE][(PHENYLTHIO)METHYLENE]RUTHENIUM (II) DICHLORIDE [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II)

  • N,Nμ-(2,4,6-Trimethylphenyl)dihydroimidazolium chloride
  • SIMes.HCl
  • 1,3-Bis(2,4,6-trimethylphenyl)-imidazolidinium-chlorid
  • 1,3-Bis(2
  • 1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDRO-1H-IMIDAZOLIUM CHLORIDE
  • 1,3-Bis-(2,4,6-trimethyl-phenyl)-imidazolidin-1-ium chloride
  • 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
  • 1,3-Bis-(2,4,6-trimethylphenyl)imidazolidinium
  • inium ChL
  • 1,3-Bis(2,4,6-trimethylphenyl)imidazolidiniumchloride,97%
  • 1,3-Bis-(2,4,6-
  • 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride
  • 1,3-Bis(2,4,6-trimethylphenyl)imidazolidinium-chloride,98+%,TLC
  • 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride, min. 97%
  • 1,3-Bis-(2,4,6-triMethylphenyl)-4,5-dihydro-3H-iMidazol-1-iuM chloride
  • 1,3-diMesityl-4,5-dihydro-1H-iMidazol-3-iuM chloride
  • 1,3-Bis(2,4,6-triMethlyphenyl)iMidazoliniuM Chloride
  • 1,3-DiMesityliMidazolidin-1-iuM chloride
  • 1,3-Bis(2,4,6-triMethylphenyl)iMidazoliniuM chloride 95%
  • 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride,97%
  • 1,3-Dimesitylimidazolidinium chloride
  • 4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium chloride
  • 4,5-Dihydro-1,3-dimesityl-1H-imidazolium chloride
  • 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-1-ium chloride
  • 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride, SIMes.HCl
  • 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride &gt
  • 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chlori
  • 173035-10-4
  • C21H29ClN2
  • C21H28N
  • C21H27ClN2
  • C23H33N
  • Achiral Nitrogen
  • NHC
  • Ligands
  • N-Heterocyclic Carbene Ligands
  • Synthetic Organic Chemistry