2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE

Product Name: 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
CAS No.: 81058-27-7
Chemical Name: 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
Synonyms: 2,3,4,6-Tetra-O-Pivaloyl-α-D-Glucopyranosyl Bromide;EOS-61173;Empagliflozin Impurity 66;Canagliflozin Intermediate3;per-O-pivaloyl-±-D-glucopyranosyl bromide;Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide;TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE;2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL;2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosylbromide;2, 3, 4, 6-0-tetrapentanoyl-a-D-Bromopyran glucose
CBNumber: CB0202527
Molecular Formula: C26H43BrO9
Formula Weight: 579.53
MOL File: 81058-27-7.mol

More

Less

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Property

Melting point:: 147-148°C
Boiling point:: 530.5±50.0 °C(Predicted)
Density: 1.22±0.1 g/cm3(Predicted)
vapor pressure: 0-0Pa at 20-25℃
storage temp.: Inert atmosphere,2-8°C
solubility: Chloroform (Sparingly)
form: Solid
color: White to Off-White
Stability:: Light Sensitive, Moisture Sensitive
InChIKey: BSDBCYHGMPHOAL-WPECYLAMNA-N
SMILES: O([C@@H]1[C@H](O[C@H](Br)[C@H](OC(=O)C(C)(C)C)[C@H]1OC(=O)C(C)(C)C)COC(=O)C(C)(C)C)C(=O)C(C)(C)C |&1:1,2,4,6,14,r|
LogP: 7.2 at pH7
CAS DataBase Reference: 81058-27-7

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
HS Code: 2932990090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

TRC

Product number: T306360
Product name: Tetra-O-pivaloyl-α-D-glucopyranosylBromide
Packaging: 1g
Price: $150
Updated: 2021/12/16

Usbiological

Product number: 166742
Product name: Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide
Packaging: 1g
Price: $460
Updated: 2021/12/16

TRC

Product number: T306360
Product name: Tetra-O-pivaloyl-α-D-glucopyranosylBromide
Packaging: 10g
Price: $1190
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CRB0002132
Product name: 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
Purity: 95.00%
Packaging: 50G
Price: $1150
Updated: 2021/12/16

Biosynth Carbosynth

Product number: MT04047
Product name: 2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosyl bromide
Packaging: 50g
Price: $160
Updated: 2021/12/16

More

Less

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Chemical Properties,Usage,Production

Uses

Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide was used in the preparation of glucosylated monoterpenoids rhodiolosides A and D.

Uses

K?nigs-Knorr glycosyl donor with considerably lower tendency to form orthoester side products during glycosylation than the traditional acetobromoglucose

Uses

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE was used in the preparation of glucosylated monoterpenoids rhodiolosides A and D.

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Suppliers

Canada 1 China 182 India 3 The Netherlands 1 United Kingdom 9 United States 14 Global 210

Toronto Research Chemicals

Tel: --
Fax: --
Email: info@trc-canada.com
Country: Canada
ProdList: 6038
Advantage: 71

More

Less

View Lastest Price from 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE manufacturers

Hangzhou ICH Biofarm Co., Ltd

Product: Tetra-o-pivaloyl-alpha-D-glucopyranosyl bromide 81058-27-7
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500
Release date: 2023-07-12

Henan Aochuang Chemical Co.,Ltd.

Product: 2,3,4,6-Tetra-o-pivaloyl-alpha-d-glucopyranosyl bromide 81058-27-7
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-29

Zhuozhou Wenxi import and Export Co., Ltd

Product: α-D-glucopyranosyl bromide, 2,3,4,6-tetra-O-pivaloyl 81058-27-7
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

81058-27-7, 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDERelated Search:

Sofosbuvir Potassium pyrophosphate D-Glucuronic acid Ampicillin Empagliflozin (4R,5R)-2-(4-chloro-3-(4-(((S)-tetrahydrofuran-3-yl)oxy)benzyl) phenyl)-5-((R)-1,2-dihydroxyethyl)tetrahydrofuran-3,4-diol Acetoxy Empagliflozin PF-04971729 Ipragliflozin Canagliflozin 1-Chloro-2-(4-ethoxybenzyl)-4-iodobenzene (3S)-3-[4-[(5-Bromo-2-chlorophenyl)methyl]phenoxy]tetrahydrofuran Benzo[b]thiophene, 2-[(5-broMo-2-fluorophenyl)Methyl]- (2-Chloro-5-iodophenyl)[4-[[(3S)-tetrahydro-3-furanyl]oxy]phenyl]methanone (2S,3R,4S,5S,6R)-2-(3-(4-((S)-tetrahydrofuran-3-yloxy)benzyl)-4-chlorophenyl)-tetrahydro-6-(hydroxyMethyl)-2-Methoxy-2H-pyran-3,4,5-triol 2,3,4,6-Tetra-O-benzyl-a-D-glucopyranosylbromide (R)-3-(4-(5-broMo-2-chlorobenzyl)phenoxy)tetrahydrofuran (3R,4S,5S,6R)-2-[4-chloro-3-[[4-[(3S)-oxolan-3-yl]oxyphenyl]methyl]phenyl]-6-(hydroxymethyl)-2-methoxyoxane-3,4,5-triol

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE

TETRAKIS(2,2-DIMETHYLPROPANOATE)-A-D-GLUCOPYRANOSYL BROMIDE

TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE

2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosyl bromide (stabilised with CaCO3)

[(2S,3S,4S,5R,6S)-6-broMo-3,4,5-tris(2,2-diMethylpropanoyloxy)tetrahydropyran-2-yl]Methyl2,2-diMethylpropanoate

2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosylbromide

(2R,3R,4S,5R,6R)-2-BroMo-6-((pivaloyloxy)Methyl)tetrahydro-2H-pyran-3,4,5-triyl tris(2,2-diMethylpropanoate)

Canagliflozin Intermediate3

α-D-glucopyranosyl bromide, 2,3,4,6-tetra-O-pivaloyl

2,3,4,6-Tetra-O-pivaloyl-alpha-D-glucopyranosyl bromide >=90% (TLC)

(2R,3R,4S,5R,6R)-2-Bromo-6-((pivaloyloxy)methyl)tetrahydro-2H-pyran-3,4,5-triyl tris(2,2-dimet

2,3,4,6-Tetra-O-pivaloyl-a-D-glucopytanosyl bromide

EOS-61173

2,3,4,6-Tetra-O-pivaloyl-α-D-glucopytanosyl bromide

2,3,4,6-Tetra-O-pivaloyl-alpha-D-glucopyranosyl bromide (Related Reference)

per-O-pivaloyl-±-D-glucopyranosyl bromide

4. 2,3,4,6-Tetra-O-pivaloyl-alpha-D-glucopyranosyl broMide

[(2R,3R,4S,5R,6R)-6-bromo-3,4,5-tris[(2,2-dimethylpropanoyl)oxy]oxan-2-yl]methyl 2,2-dimethylpropanoate

Empagliflozin Impurity 66

α-D-Glucopyranosyl bromide, 2,3,4,6-tetrakis(2,2-dimethylpropanoate)

2,3,4,6-Tetra-O-Pivaloyl-α-D-Glucopyranosyl Bromide

Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide

[(2S,3S,4S,5R,6S)-6-bromo-3,4,5-tris(2,2-dimethylpropanoylox...

2S,3S,4S,5R,6S)-6-bromo-3,4,5-tris(2,2-dimethylpropanoyloxy)tetrahydropyran-2-yl]methyl 2,2-dimethyl

2, 3, 4, 6-0-tetrapentanoyl-a-D-Bromopyran glucose

α-D-glucopyranosyl bromide, 2,3,4,6-tetra-O-pivaloyl

α-D-Glucopyranosyl bromide, 2,3,4,6-tetrakis(2,2-dimethylpropanoate)

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL

(2R,3R,4S,5R,6R)-2-Bromo-6-((pivaloyloxy)methyl)tetrahydro-2H-pyran-3,4,5-triyl tris(2,2-dimethylpropanoate) (Empagliflozin Impurity）

2,3,4,5-O-tetratervaloyl-ALPHA-D-bromopyranoglucose

81058-27-7

C26H43BrO9

SGLT2

substrate

Canagliflozin intermediate