ChemicalBook > CAS DataBase List > 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE

Product Name
2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
CAS No.
81058-27-7
Chemical Name
2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
Synonyms
2,3,4,6-Tetra-O-Pivaloyl-α-D-Glucopyranosyl Bromide;EOS-61173;Empagliflozin Impurity 66;Canagliflozin Intermediate3;per-O-pivaloyl-±-D-glucopyranosyl bromide;Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide;TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE;2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL;2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosylbromide;2, 3, 4, 6-0-tetrapentanoyl-a-D-Bromopyran glucose
CBNumber
CB0202527
Molecular Formula
C26H43BrO9
Formula Weight
579.53
MOL File
81058-27-7.mol
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2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Property

Melting point:
147-148°C
Boiling point:
530.5±50.0 °C(Predicted)
Density 
1.22±0.1 g/cm3(Predicted)
vapor pressure 
0-0Pa at 20-25℃
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Sparingly)
form 
Solid
color 
White to Off-White
optical activity
[α]/D 152.0±3.0°, c =3 in chloroform
Stability:
Light Sensitive, Moisture Sensitive
InChIKey
BSDBCYHGMPHOAL-WPECYLAMNA-N
SMILES
O([C@@H]1[C@H](O[C@H](Br)[C@H](OC(=O)C(C)(C)C)[C@H]1OC(=O)C(C)(C)C)COC(=O)C(C)(C)C)C(=O)C(C)(C)C |&1:1,2,4,6,14,r|
LogP
7.2 at pH7
CAS DataBase Reference
81058-27-7
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
HS Code 
2932990090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
T306360
Product name
Tetra-O-pivaloyl-α-D-glucopyranosylBromide
Packaging
1g
Price
$150
Updated
2021/12/16
Usbiological
Product number
166742
Product name
Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide
Packaging
1g
Price
$460
Updated
2021/12/16
TRC
Product number
T306360
Product name
Tetra-O-pivaloyl-α-D-glucopyranosylBromide
Packaging
10g
Price
$1190
Updated
2021/12/16
Biosynth Carbosynth
Product number
MT04047
Product name
2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosyl bromide
Packaging
10g
Price
$65
Updated
2021/12/16
Biosynth Carbosynth
Product number
MT06371
Product name
2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosyl bromide - stabilised with CaCO3
Packaging
5G
Price
$65.65
Updated
2021/12/16
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2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Chemical Properties,Usage,Production

Uses

Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide was used in the preparation of glucosylated monoterpenoids rhodiolosides A and D.

Uses

K?nigs-Knorr glycosyl donor with considerably lower tendency to form orthoester side products during glycosylation than the traditional acetobromoglucose

Uses

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE was used in the preparation of glucosylated monoterpenoids rhodiolosides A and D.

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Suppliers

Canada 1 China 186 India 3 The Netherlands 1 United Kingdom 9 United States 14 Global 214
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View Lastest Price from 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
2,3,4,6-Tetra-o-pivaloyl-alpha-d-glucopyranosyl bromide 81058-27-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-29
Hangzhou ICH Biofarm Co., Ltd
Product
Tetra-o-pivaloyl-alpha-D-glucopyranosyl bromide 81058-27-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500
Release date
2023-07-12
Zhuozhou Wenxi import and Export Co., Ltd
Product
α-D-glucopyranosyl bromide, 2,3,4,6-tetra-O-pivaloyl 81058-27-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

81058-27-7, 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDERelated Search:

Sofosbuvir Potassium pyrophosphate D-Glucuronic acid Ampicillin Empagliflozin (4R,5R)-2-(4-chloro-3-(4-(((S)-tetrahydrofuran-3-yl)oxy)benzyl) phenyl)-5-((R)-1,2-dihydroxyethyl)tetrahydrofuran-3,4-diol Acetoxy Empagliflozin PF-04971729 Ipragliflozin Canagliflozin 1-Chloro-2-(4-ethoxybenzyl)-4-iodobenzene (3S)-3-[4-[(5-Bromo-2-chlorophenyl)methyl]phenoxy]tetrahydrofuran Benzo[b]thiophene, 2-[(5-broMo-2-fluorophenyl)Methyl]- (2-Chloro-5-iodophenyl)[4-[[(3S)-tetrahydro-3-furanyl]oxy]phenyl]methanone (2S,3R,4S,5S,6R)-2-(3-(4-((S)-tetrahydrofuran-3-yloxy)benzyl)-4-chlorophenyl)-tetrahydro-6-(hydroxyMethyl)-2-Methoxy-2H-pyran-3,4,5-triol 2,3,4,6-Tetra-O-benzyl-a-D-glucopyranosylbromide (R)-3-(4-(5-broMo-2-chlorobenzyl)phenoxy)tetrahydrofuran (3R,4S,5S,6R)-2-[4-chloro-3-[[4-[(3S)-oxolan-3-yl]oxyphenyl]methyl]phenyl]-6-(hydroxymethyl)-2-methoxyoxane-3,4,5-triol

  • 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
  • TETRAKIS(2,2-DIMETHYLPROPANOATE)-A-D-GLUCOPYRANOSYL BROMIDE
  • TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
  • 2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosyl bromide (stabilised with CaCO3)
  • [(2S,3S,4S,5R,6S)-6-broMo-3,4,5-tris(2,2-diMethylpropanoyloxy)tetrahydropyran-2-yl]Methyl2,2-diMethylpropanoate
  • 2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosylbromide
  • (2R,3R,4S,5R,6R)-2-BroMo-6-((pivaloyloxy)Methyl)tetrahydro-2H-pyran-3,4,5-triyl tris(2,2-diMethylpropanoate)
  • Canagliflozin Intermediate3
  • α-D-glucopyranosyl bromide, 2,3,4,6-tetra-O-pivaloyl
  • 2,3,4,6-Tetra-O-pivaloyl-alpha-D-glucopyranosyl bromide >=90% (TLC)
  • (2R,3R,4S,5R,6R)-2-Bromo-6-((pivaloyloxy)methyl)tetrahydro-2H-pyran-3,4,5-triyl tris(2,2-dimet
  • 2,3,4,6-Tetra-O-pivaloyl-a-D-glucopytanosyl bromide
  • EOS-61173
  • 2,3,4,6-Tetra-O-pivaloyl-α-D-glucopytanosyl bromide
  • 2,3,4,6-Tetra-O-pivaloyl-alpha-D-glucopyranosyl bromide (Related Reference)
  • per-O-pivaloyl-±-D-glucopyranosyl bromide
  • 4. 2,3,4,6-Tetra-O-pivaloyl-alpha-D-glucopyranosyl broMide
  • [(2R,3R,4S,5R,6R)-6-bromo-3,4,5-tris[(2,2-dimethylpropanoyl)oxy]oxan-2-yl]methyl 2,2-dimethylpropanoate
  • Empagliflozin Impurity 66
  • α-D-Glucopyranosyl bromide, 2,3,4,6-tetrakis(2,2-dimethylpropanoate)
  • 2,3,4,6-Tetra-O-Pivaloyl-α-D-Glucopyranosyl Bromide
  • Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide
  • [(2S,3S,4S,5R,6S)-6-bromo-3,4,5-tris(2,2-dimethylpropanoylox...
  • 2S,3S,4S,5R,6S)-6-bromo-3,4,5-tris(2,2-dimethylpropanoyloxy)tetrahydropyran-2-yl]methyl 2,2-dimethyl
  • 2, 3, 4, 6-0-tetrapentanoyl-a-D-Bromopyran glucose
  • 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL
  • (2R,3R,4S,5R,6R)-2-Bromo-6-((pivaloyloxy)methyl)tetrahydro-2H-pyran-3,4,5-triyl tris(2,2-dimethylpropanoate) (Empagliflozin Impurity）
  • 2,3,4,5-O-tetratervaloyl-ALPHA-D-bromopyranoglucose
  • 2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-α-D-glucopyranosyl bromide
  • 2,3,4,6-Tetra-<i>O</i>-pivaloyl-α-<sc>D</sc>-glucopyranosyl bromide
  • 81058-27-7
  • C26H43BrO9
  • SGLT2
  • substrate
  • Canagliflozin intermediate