Damascenone

Product Name: Damascenone
CAS No.: 23696-85-7
Chemical Name: Damascenone
Synonyms: β-Damascenone;2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-;DAMASCENONE TOTAL;4-(2,6,6-Trimethyl cyclohexa-1,3-dienyl)but-2-en-4-one;1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-Buten-1-one;(E)-1-(2,6,6-triMethylcyclohexa-1,3-dien-1-yl)but-2-en-1-one;FEMA 3420;Damasione;DAMASCENON;Trimethyl cyclohexadienyl butenone
CBNumber: CB0203140
Molecular Formula: C13H18O
Formula Weight: 190.28
MOL File: 23696-85-7.mol

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Damascenone Property

Boiling point:: 275.6±10.0 °C(Predicted)
Density: 0.800-0.830 g/mL at 25 °C (lit.)
refractive index: 1.350-1.380
FEMA: 3420 | 1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIENYL)-2-BUTEN-1-ONE
Flash point:: 62°F
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: liquid
color: yellow
Odor: at 10.00 % in dipropylene glycol. natural sweet fruity rose plum grape raspberry sugar
Odor Type: floral
JECFA Number: 387
Stability:: Light Sensitive
LogP: 4.04
CAS DataBase Reference: 23696-85-7(CAS DataBase Reference)
NIST Chemistry Reference: 2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-(23696-85-7)
EPA Substance Registry System: 2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)- (23696-85-7)

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-43
Safety Statements: 7-16-36/37
RIDADR: UN 1170
WGK Germany: 3
HS Code: 33021090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W342017
Product name: Damascenone
Purity: natural, 1.1-1.4 wt. % (190 proof ethanol), FG
Packaging: sample-k
Price: $58.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: W342017
Product name: Damascenone
Purity: natural, 1.1-1.4?wt. % (190 proof ethanol), FG
Packaging: 25g
Price: $184
Updated: 2024/03/01

Sigma-Aldrich

Product number: W342017
Product name: Damascenone
Purity: natural, 1.1-1.4?wt. % (190 proof ethanol), FG
Packaging: 100g
Price: $459
Updated: 2024/03/01

Sigma-Aldrich

Product number: W342017
Product name: Damascenone
Purity: natural, 1.1-1.4?wt. % (190 proof ethanol), FG
Packaging: 1kg
Price: $2420
Updated: 2024/03/01

Sigma-Aldrich

Product number: 41163
Product name: Damascenone
Purity: analytical standard
Packaging: 250mg
Price: $82.2
Updated: 2024/03/01

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Damascenone Chemical Properties,Usage,Production

Occurrence

Reported found in raspberry oil, Burley tobacco, apple, lemon balm, summer savory, anise, hyssop, apple juice, cooked apple, apricot, sweet and sour cherry, black currant berries, fresh blackberry, strawberry jam, hop oil rum, white wine, red wine, black tea, tomato, rye bread, blue cheese, cow, goat and sheep milk, hop oil, beer, cognac, rum, whiskies, scotch, cider, grape wines, coffee, tea, popcorn, oatmeal, soybean, plum, prune, beans, starfruit, mango, tamarind, dill seed, corn oil, okra, cape gooseberry, anise hyssop and Roman chamomile oil.

Uses

Damascenone is a fragrance ingredient that can be used in shampoos, fine fragrances, decorative cosmetics, toilet soaps as well as non-cosmetic products like household cleaners and detergents.

Preparation

By treating the corresponding ethyl safranate with allyl lithium, followed by catalytic isomerization of the reaction product; also from the oxirane derivative of β-damascone by an acid-catalyzed reaction.

Definition

ChEBI: Beta-damascenone is a cyclic monoterpene ketone that is 2,6,6-trimethylcyclohexa-1,3-diene substituted at position 1 by a crotonoyl group. It has a role as a fragrance, a volatile oil component and a plant metabolite. It is an enone, an apo carotenoid monoterpenoid and a cyclic monoterpene ketone.

Aroma threshold values

Detection: 0.0007 to 0.009 ppb. Aroma characteristics at 1.0%: sweet, brown woody, tobacco, davana-like fruity, with a spicy balsamic undernote.

Taste threshold values

Taste characteristics at 1 to 5 ppm: sweet brown, tea-like, davana dried fruity, with jamy berry, strawberry and raspberry nuances, woody, floral, herbal, green and fruity with spicy tobacco nuances.

General Description

Damascenone is a norisoprenoid ketone mainly found in red wines. It occurs naturally in tomato and grapes.

Biochem/physiol Actions

Taste at 1-5 ppm

Damascenone Preparation Products And Raw materials

Raw materials

Mesityl oxide TRANS-1,3-PENTADIENE

Preparation Products

beta-Damascenone

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View Lastest Price from Damascenone manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Damascenone 23696-85-7
Price: US $0.00/Kg/Drum
Min. Order: 1KG
Purity: 98%min
Supply Ability: 500KGS
Release date: 2021-06-19

Shandong Deshang Chemical Co., Ltd.

Product: Damascenone 23696-85-7
Price: US $15.00-10.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 10 tons
Release date: 2024-06-19

Shandong Deshang Chemical Co., Ltd.

Product: Damascenone 23696-85-7
Price: US $5.90-3.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10 tons
Release date: 2024-06-25

23696-85-7, DamascenoneRelated Search:

Tiglic aldehyde Cyclohexene Mesityl oxide 6-Methyl-5-hepten-2-one 2-Cyclohexen-1-one Phenylbutazone Methyl cyclopentenolone Trimethyl borate METHYLCYCLOHEXANONE Methyl vinyl ketone SAFRANAL 1,3-CYCLOHEXADIENE 1,4-HEXADIENE DAMASCONE METHYL CYCLOHEXADIENE 1-METHYL-1,3-CYCLOHEXADIENE 3,3-DIMETHYL-2-METHYLENE-BUTYRALDEHYDE Damascenone

DAMASCENONE

FEMA 3420

4-(2,6,6-Trimethyl cyclohexa-1,3-dienyl)but-2-en-4-one

Trimethyl cyclohexadienyl butenone

1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-buten-1-on

1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-Buten-1-one

Damasione

2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-

DAMASCENON

DAMASCENONE TOTAL

1-(2,6,6-Trimethyl-1,3-cyclohexadienyl)-2-butene-1-one

1-(2,6,6-Trimethylcyclohexa-1,3-diene-1-yl)-2-butene-1-one

1-(2-Butenoyl)-2,6,6-trimethyl-1,3-cyclohexadiene

3,5,8-Megastigmatrien-7-one

Damascenone (natural)

Einecs 245-833-2

Fema no. 3420

(E)-1-(2,6,6-triMethylcyclohexa-1,3-dien-1-yl)but-2-en-1-one

1-(2,6,6-Trimethylcyclohexa-1,3-dien-1-yl)-2-buten-1-one

β-Damascenone

Damascenone USP/EP/BP

DAMASCENONE1#,2#

Factory supply FEMA 3420 Damascenone cas 23696-85-7

Damacenone

(2E)-1-(2,6,6-trimethylcyclohexa-1,3-dienyl)but-2-en-1-one

Turkenone

Turkic peoples

23696-85-7

43952-87-5

C-D

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Flavors and Fragrances