4-(4-Pyridinyl)benzaldehyde

Product Name: 4-(4-Pyridinyl)benzaldehyde
CAS No.: 99163-12-9
Chemical Name: 4-(4-Pyridinyl)benzaldehyde
Synonyms: AKOS BAR-0607;4-(4-PYRIDYL)BENZALDEHYDE;4-(4-FORMYLPHENYL)PYRIDINE;4-(4-PYRIDINYL)BENZALDEHYDE;4-PYRIDIN-4-YL-BENZALDEHYDE;4-(4-Pyridyl)benzaldehyde>Benzaldehyde, 4-(4-pyridinyl)-;4-PYRIDIN-4-YL-BENZALDEHYDE, 95+%;4-(3-Fluoropyridin-4-yl)benzaldehyde;4-(2-Fluoropyridin-4-yl)benzaldehyde
CBNumber: CB0208594
Molecular Formula: C12H9NO
Formula Weight: 183.21
MOL File: 99163-12-9.mol

More

Less

4-(4-Pyridinyl)benzaldehyde Property

Melting point:: 85-89 °C (lit.)
Boiling point:: 336.7±25.0 °C(Predicted)
Density: 1.147±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: powder to crystal
pka: 4.98±0.10(Predicted)
color: White to Orange to Green
InChI: InChI=1S/C12H9NO/c14-9-10-1-3-11(4-2-10)12-5-7-13-8-6-12/h1-9H
InChIKey: MBJXDIYHLGBQOT-UHFFFAOYSA-N
SMILES: C(=O)C1=CC=C(C2C=CN=CC=2)C=C1
CAS DataBase Reference: 99163-12-9(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38
Safety Statements: 26-36/37/39-22
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29333990

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 645982
Product name: 4-(4-Formylphenyl)pyridine
Purity: 97%
Packaging: 1g
Price: $102
Updated: 2023/06/20

Sigma-Aldrich

Product number: 645982
Product name: 4-(4-Formylphenyl)pyridine
Purity: 97%
Packaging: 5g
Price: $451
Updated: 2023/06/20

TCI Chemical

Product number: P1983
Product name: 4-(4-Pyridyl)benzaldehyde
Purity: >98.0%(GC)
Packaging: 200mg
Price: $137
Updated: 2024/03/01

TCI Chemical

Product number: P1983
Product name: 4-(4-Pyridyl)benzaldehyde
Purity: >98.0%(GC)
Packaging: 1g
Price: $482
Updated: 2024/03/01

TRC

Product number: P996968
Product name: 4-Pyridin-4-yl-benzaldehyde
Packaging: 100mg
Price: $75
Updated: 2021/12/16

More

Less

4-(4-Pyridinyl)benzaldehyde Chemical Properties,Usage,Production

Chemical Properties

White solid

Synthesis

1692-15-5

1122-91-4

99163-12-9

Pyridine-4-boronic acid (498.3 mg, 4.05 mmol) and p-bromobenzaldehyde (500 mg, 2.70 mmol) were added to bis(triphenylporphyrinophosphate) palladium dichloride Pd(PPh3)2Cl2 (94.65 mg, 0.14 mmol) as a catalyst and dissolved in 20 mL of a solvent mixture of tetrahydrofuran and toluene (Vtoluene: VTHF = 1:1) in it. The reaction mixture was heated to 90°C under nitrogen protection for reflux reaction and the reaction process was monitored by thin layer chromatography (TLC). Upon completion of the reaction, the reaction solution was concentrated to remove the organic solvent and subsequently extracted with ethyl acetate. The organic layer was washed sequentially with water three times, saturated sodium chloride solution once, and then dried with anhydrous sodium sulfate. The dried organic phase was evaporated under reduced pressure to remove the solvent to obtain the crude product. The crude product was purified by silica gel column chromatography using a mixed solvent of petroleum ether and ethyl acetate (20:1) as eluent to finally obtain 4-(pyridin-4-yl)benzaldehyde (white solid, 288.7 mg, 68.4% yield).

References

[1] Journal of the American Chemical Society, 2018, vol. 140, # 21, p. 6622 - 6630
[2] Journal of Medicinal Chemistry, 2018, vol. 61, # 18, p. 8402 - 8416
[3] Crystal Growth and Design, 2018, vol. 18, # 11, p. 6936 - 6945
[4] Patent: CN105418515, 2016, A. Location in patent: Paragraph 0087; 0088; 0089
[5] Angewandte Chemie - International Edition, 2006, vol. 45, # 17, p. 2761 - 2766

4-(4-Pyridinyl)benzaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

4-(4-Pyridinyl)benzaldehyde Suppliers

Belgium 1 China 103 Germany 4 India 2 Japan 1 Russia 1 Switzerland 1 United Kingdom 5 United States 22 Global 140

Alfa Chemistry

Tel: +1-5166625404;
Fax: 1-516-927-0118
Email: Info@alfa-chemistry.com
Country: United States
ProdList: 20405
Advantage: 58

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63687
Advantage: 58

Protheragen-ING

Tel: +16313385890
Email: info@protheragen-ing.com
Country: United States
ProdList: 3868
Advantage: 58

Aladdin Scientific

Tel
Email: tp@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Synthonix Inc

Tel: --
Fax: --
Email: info@synthonix.com
Country: United States
ProdList: 6872
Advantage: 58

Sphinx Scientific Laboratory, LLC

Tel: --
Fax: --
Email: sales@sphinxscientificlab.com
Country: United States
ProdList: 3343
Advantage: 50

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6962
Advantage: 56

SynChem，Inc

Tel: --
Fax: --
Email: sales@synchem.com
Country: United States
ProdList: 4697
Advantage: 58

SynQuest Laboratories, Inc.

Tel: --
Fax: --
Email: info@synquestlabs.com
Country: United States
ProdList: 6871
Advantage: 62

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

TCI America

Tel: --
Fax: --
Email: sales@tciamerica.com
Country: United States
ProdList: 6909
Advantage: 75

Frontier Scientific, Inc.

Tel: --
Fax: --
Email: sales@frontiersci.com
Country: United States
ProdList: 6222
Advantage: 86

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

Anvia Chemicals, LLC

Tel: --
Fax: --
Email: sales@anviachem.com
Country: United States
ProdList: 3933
Advantage: 0

Chem-Impex International, Inc.

Tel: --
Fax: --
Country: United States
ProdList: 6730
Advantage: 64

Aroz Technologies, LLC.

Tel: --
Fax: --
Email: sales@aroztech.com
Country: United States
ProdList: 1877
Advantage: 30

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

AQS-USA.INC.

Tel: --
Fax: --
Country: United States
ProdList: 893
Advantage: 30

Array Biopharma Inc.

Tel: --
Fax: --
Email: sales@arraybiopharma.com
Country: United States
ProdList: 578
Advantage: 80

Pharmabridge Inc.

Tel: --
Fax: --
Email: sales@pharmabridgegroup.com
Country: United States
ProdList: 731
Advantage: 55

Synchem Inc.

Tel: --
Fax: --
Email: catalog@synchem.com
Country: United States
ProdList: 1154
Advantage: 46

Beta Pharma, Inc.

Tel: --
Fax: --
Email: sales@betapharma.com
Country: United States
ProdList: 6226
Advantage: 60

More

Less

View Lastest Price from 4-(4-Pyridinyl)benzaldehyde manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-(4-Pyridinyl)benzaldehyde 99163-12-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-(4-Pyridyl)benzaldehyde 99163-12-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: 4-(4-Pyridinyl)benzaldehyde 99163-12-9
Price: US $1.00/g
Min. Order: 1g
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-07

99163-12-9, 4-(4-Pyridinyl)benzaldehydeRelated Search:

4-Hydroxybenzaldehyde Pyridine 4-Pyridinecarboxaldehyde Benzaldehyde 4-Dimethylaminobenzaldehyde 2-Nitrobenzaldehyde 4-Pyrid-4-ylbenzoic acid rosoxacin 2-(4-PYRIDINYL)BENZALDEHYDE 3-(2-PYRIDINYL)BENZALDEHYDE 3-(3-PYRIDINYL)BENZALDEHYDE 4-(3-PYRIDINYL)BENZALDEHYDE 2-(3-PYRIDINYL)BENZALDEHYDE 4-(2-PYRIDINYL)BENZALDEHYDE 3-(4-PYRIDINYL)BENZALDEHYDE 4-(4-PYRIDYL)BENZOIC ACID, SODIUM SALT 4-(2,2':6',2''-TERPYRIDIN-4'-YL)BENZALDEHYDE METHYL 4-(4-PYRIDINYL)BENZOATE

AKOS BAR-0607

4-PYRIDIN-4-YL-BENZALDEHYDE

4-(4-PYRIDINYL)BENZALDEHYDE

4-(4-PYRIDYL)BENZALDEHYDE

4-(4-FORMYLPHENYL)PYRIDINE

4-(2-Chloropyridin-4-yl)benzaldehyde

4-(2-Fluoropyridin-4-yl)benzaldehyde

4-(3-Fluoropyridin-4-yl)benzaldehyde

4-PYRIDIN-4-YL-BENZALDEHYDE, 95+%

4-(4-Pyridyl)benzaldehyde&gt

Benzaldehyde, 4-(4-pyridinyl)-

99163-12-9