6-BROMO-2,2'-BIPYRIDINE
- Product Name
- 6-BROMO-2,2'-BIPYRIDINE
- CAS No.
- 10495-73-5
- Chemical Name
- 6-BROMO-2,2'-BIPYRIDINE
- Synonyms
- 6-Bromo-2,2'-bipyridyl;6-bromo-2,2'-bipyridine;6-BROMO-2,2'-BIPYRIDINE;6-Bromo-[2,2']bipyridinyl;2,2'-Bipyridine, 6-bromo-;6-Bromo-2,2'-bipyridyl >6-broMo-2,2'-bipyridine 97%;2-BROMO-6-(2-PYRIDYL)PYRIDINE;2-bromo-6-(pyridin-2-yl) pyridine;6-BROMO-2,2'-BIPYRIDINE ISO 9001:2015 REACH
- CBNumber
- CB0214564
- Molecular Formula
- C10H7BrN2
- Formula Weight
- 235.08
- MOL File
- 10495-73-5.mol
6-BROMO-2,2'-BIPYRIDINE Property
- Melting point:
- 72.0 to 76.0 °C
- Boiling point:
- 133°C/2.2mmHg(lit.)
- Density
- 1.493±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Chloroform, Methanol
- form
- powder to crystal
- pka
- 3.70±0.22(Predicted)
- color
- White to Almost white
- BRN
- 130238
- InChI
- InChI=1S/C10H7BrN2/c11-10-6-3-5-9(13-10)8-4-1-2-7-12-8/h1-7H
- InChIKey
- NCRIDSGPLISUEU-UHFFFAOYSA-N
- SMILES
- C1(C2=NC=CC=C2)=NC(Br)=CC=C1
- CAS DataBase Reference
- 10495-73-5
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38-22
- Safety Statements
- 26-36/37/39
- RIDADR
- UN 2811
- WGK Germany
- 3
- HazardClass
- 6.1
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 690066
- Product name
- 6-Bromo-2,2′-bipyridine
- Purity
- 97%
- Packaging
- 1g
- Price
- $219
- Updated
- 2025/07/31
- Product number
- B4114
- Product name
- 6-Bromo-2,2'-bipyridyl
- Purity
- >97.0%(GC)
- Packaging
- 1g
- Price
- $147
- Updated
- 2025/07/31
- Product number
- B4114
- Product name
- 6-Bromo-2,2'-bipyridyl
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $584
- Updated
- 2025/07/31
- Product number
- B680575
- Product name
- 6-Bromo-2,2’-bipyridine
- Packaging
- 1g
- Price
- $135
- Updated
- 2021/12/16
- Product number
- 323989
- Product name
- 6-Bromo-2,2'-bipyridine
- Packaging
- 1g
- Price
- $140
- Updated
- 2021/12/16
6-BROMO-2,2'-BIPYRIDINE Chemical Properties,Usage,Production
Uses
6-Bromo-2,2’-bipyridine is a reagent used in the synthesis of electron transporting layers for OLEDs.
Synthesis
626-05-1
17997-47-6
10495-73-5
General procedure for the synthesis of 6-bromo-2,2'-bipyridine from 2,6-dibromopyridine and 2-tributylmethylstannylpyridine: 1.5 g (6.33 mmol) of 2,6-dibromopyridine, 3.48 g (9.48 mmol) of 2-tributylmethylstannylpyridine and 0.15 g (0.06 mmol) of tetrakis(triphenylphosphine)palladium (Pd(PPh3)4) were were dissolved in 15 mL of toluene in a two-necked round bottom flask. The reaction mixture was stirred at 80°C for about 24 hours. Upon completion of the reaction, the solvent was removed by evaporation under reduced pressure. The resulting residue was dissolved in dichloromethane and subsequently extracted with 6M hydrochloric acid solution. The aqueous layer was separated and collected, the pH was adjusted by adding ammonia to the aqueous layer and extracted with dichloromethane. The organic layer was separated and dried with anhydrous magnesium sulfate (MgSO4) followed by evaporation under reduced pressure to remove the solvent. Purification by column chromatography (eluent: hexane/ethyl acetate=5:1, v/v) afforded 0.9 g of 6-bromo-2,2'-bipyridine as a white solid (yield: 61%).
References
[1] Organic Letters, 2008, vol. 10, # 6, p. 1091 - 1094
[2] Chemical Communications, 2007, # 42, p. 4401 - 4403
[3] Organometallics, 2017, vol. 36, # 9, p. 1727 - 1735
[4] Patent: KR2015/142709, 2015, A. Location in patent: Paragraph 0473-0475
[5] Inorganic Chemistry, 2013, vol. 52, # 9, p. 5570 - 5580
6-BROMO-2,2'-BIPYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 6-BROMO-2,2'-BIPYRIDINE manufacturers
- Product
- 6-Bromo-2,2’-bipyridine 10495-73-5
- Price
- US $193.00-710.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 10kg
- Release date
- 2023-10-18
- Product
- 6-BROMO-2,2'-BIPYRIDINE 10495-73-5
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons Min
- Release date
- 2021-10-27
- Product
- 6-BROMO-2,2'-BIPYRIDINE 10495-73-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-12-31