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2-METHOXYBENZENESULFONYL CHLORIDE

Product Name
2-METHOXYBENZENESULFONYL CHLORIDE
CAS No.
10130-87-7
Chemical Name
2-METHOXYBENZENESULFONYL CHLORIDE
Synonyms
AKOS BB-9465;2-Methoxyphenylsulfonyl chloride;o-Methoxybenzenesulfonyl chloride;5-Methoxybenzenesulfonyl chloride;2-METHOXYBENZENESULFONYL CHLORIDE;2-Methoxybenzenesulphonyl chloride;2-Methoxybenzene-1-sulfonyl chloride;2-Methoxybenzenesulfonylchloride,97%;Benzenesulfonyl chloride, 2-methoxy-;M**2-METHOXYBENZENE SULFONYL CHLORIDE
CBNumber
CB0219741
Molecular Formula
C7H7ClO3S
Formula Weight
206.65
MOL File
10130-87-7.mol
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2-METHOXYBENZENESULFONYL CHLORIDE Property

Melting point:
50-54°C
Boiling point:
126-129 °C(Press: 0.3 Torr)
Density 
1.376
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
Light brown to brown Solid
Sensitive 
Moisture Sensitive
InChI
InChI=1S/C7H7ClO3S/c1-11-6-4-2-3-5-7(6)12(8,9)10/h2-5H,1H3
InChIKey
GYOBZOBUOMDRRN-UHFFFAOYSA-N
SMILES
C1(S(Cl)(=O)=O)=CC=CC=C1OC
CAS DataBase Reference
10130-87-7
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Safety

Hazard Codes 
Xi
Risk Statements 
34-43
Safety Statements 
26-36/37/39-36/37
RIDADR 
3261
HazardClass 
IRRITANT
HazardClass 
8
PackingGroup 
HS Code 
2930909899
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M3470
Product name
2-Methoxybenzenesulfonyl Chloride
Packaging
200MG
Price
$68
Updated
2025/07/31
TCI Chemical
Product number
M3470
Product name
2-Methoxybenzenesulfonyl Chloride
Packaging
1G
Price
$204
Updated
2025/07/31
TRC
Product number
M265908
Product name
2-MethoxybenzenesulfonylChloride
Packaging
10mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
033182
Product name
2-Methoxy-benzenesulfonyl chloride
Packaging
1g
Price
$46
Updated
2021/12/16
Oakwood
Product number
088375
Product name
2-Methoxy-benzenesulfonylchloride
Packaging
250mg
Price
$36
Updated
2021/12/16
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2-METHOXYBENZENESULFONYL CHLORIDE Chemical Properties,Usage,Production

Uses

For synthesis and pharmacological evaluation of sulfonamide derivatives of thiazolidin-4-ones 5-Bromo-2-methoxybenzenesulfonyl chloride is used.

Synthesis

7217-59-6

10130-87-7

General procedure for the synthesis of 2-methoxybenzenesulfonyl chloride from 2-methoxybenzenethiol: To a solution of 2-methoxybenzenethiol (1 eq.) and isopropanol (CAS: 67-63-0) (2 eq.) in methylene chloride (0.15 M) was added batchwise N-bromosuccinimide (CAS: 128-08-5) or N-chlorosuccinimide (CAS: 128-09- 6) (4 or 3.5 equivalents), and the reaction was carried out at room temperature (when using NBS) or at 0 °C (when using NCS). The reaction mixture was stirred at room temperature until the starting material was undetectable by thin layer chromatography (TLC) (about 1 hour). Subsequently, the reaction mixture was diluted with cold saturated NaHCO3 solution and extracted with ethyl acetate (4 times). The organic extracts were combined, dried with Na2SO4 and concentrated in vacuum to give the crude product. Finally, pure 2-methoxybenzenesulfonyl chloride was purified by silica gel column chromatography or radial chromatography using a hexane/ethyl acetate/acetone solvent mixture as eluent to obtain pure 2-methoxybenzenesulfonyl chloride.

References

[1] Tetrahedron Letters, 2017, vol. 58, # 23, p. 2244 - 2247
[2] Green Chemistry, 2017, vol. 19, # 9, p. 2286 - 2295

2-METHOXYBENZENESULFONYL CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-METHOXYBENZENESULFONYL CHLORIDE Suppliers

skychemical Co.Ltd
Tel
021-20960837,QQ1332204249
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021-20960837
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sales@skychemical.com
Country
China
ProdList
3341
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J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
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jkinfo@jkchemical.com
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China
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96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006356688 18621169109
Fax
86-21-61259102
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market03@meryer.com
Country
China
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40228
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Alfa Aesar
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400-6106006
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021-67582001/03/05
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saleschina@alfa-asia.com
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China
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Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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Wuhan Chemwish Technology Co., Ltd
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86-027-67849912
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86-027-87531808
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sales@chemwish.com
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China
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Beijing Ouhe Technology Co., Ltd
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010-010-82967028 13522913783
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+86-10-82967029
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2355560935@qq.com
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China
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Shangchem Co., Ltd.
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+86-21-68182121
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+86-21-68182121
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China
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Shanghai Hanhong Scientific Co.,Ltd.
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021-54306202 13764082696
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info@hanhongsci.com
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China
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42934
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Shandong Xiya Chemical Co., Ltd
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4009903999 13355009207
Fax
0539-6365991
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3007715519@qq.com
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China
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18729
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57
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View Lastest Price from 2-METHOXYBENZENESULFONYL CHLORIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
2-Methoxybenzenesulfonyl chloride 10130-87-7
Price
US $0.00-0.00/Kg
Min. Order
1KG
Purity
99.0%+
Supply Ability
100 tons
Release date
2020-01-06
Career Henan Chemical Co
Product
2-METHOXYBENZENESULFONYL CHLORIDE 10130-87-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11