ChemicalBook > CAS DataBase List > Tris(1-Chloro-2-Propyl) Phosphate

Tris(1-Chloro-2-Propyl) Phosphate

Product Name
Tris(1-Chloro-2-Propyl) Phosphate
CAS No.
13674-84-5
Chemical Name
Tris(1-Chloro-2-Propyl) Phosphate
Synonyms
TCPP;TRIS(1-CHLORO-2-PROPYL) PHOSPHATE;tris(2-chloroisopropyl)phosphate;Tris(1-chloropropan-2-yl) phosphate;TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE;amgardtmcp;hostaflamop820;TCPP (FYROL PCF);Flame Retardant TCPP;Phosphoric acid tris
CBNumber
CB0221470
Molecular Formula
C9H18Cl3O4P
Formula Weight
327.57
MOL File
13674-84-5.mol
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Tris(1-Chloro-2-Propyl) Phosphate Property

Melting point:
-39.9°C
Boiling point:
270°C
Density 
1.28
refractive index 
1.460～1.466 (20℃/D)
Flash point:
-218 °C
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
liquid
color 
Clear Colourless
Odor
mild odor
Water Solubility 
<0.1 g/100 mL at 19.5 ºC
BRN 
1842347
Stability:
Moisture Sensitive
InChIKey
KVMPUXDNESXNOH-UHFFFAOYSA-N
CAS DataBase Reference
13674-84-5(CAS DataBase Reference)
NIST Chemistry Reference
2-Propanol, 1-chloro-, phosphate (3:1)(13674-84-5)
EPA Substance Registry System
Tris(1-chloro-2-propyl) phosphate (13674-84-5)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-37
WGK Germany 
1
RTECS 
TC9000000
Hazardous Substances Data
13674-84-5(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
32952
Product name
TCPP, mixture of isomers
Purity
analytical standard
Packaging
100mg
Price
$216
Updated
2024/03/01
TRC
Product number
T887860
Product name
Tris(1-chloro-2-propyl)Phosphate
Packaging
250mg
Price
$155
Updated
2021/12/16
Matrix Scientific
Product number
097972
Product name
Tris(1-chloropropan-2-yl) phosphate
Purity
95+%
Packaging
1g
Price
$95
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0370062
Product name
TRIS-(1-CHLOROPROPAN-2-YL)PHOSPHATE
Purity
95.00%
Packaging
1G
Price
$121.8
Updated
2021/12/16
AK Scientific
Product number
I990
Product name
TCPP, mixture of isomers
Packaging
500mL
Price
$150
Updated
2021/12/16
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Tris(1-Chloro-2-Propyl) Phosphate Chemical Properties,Usage,Production

Chemical Properties

Tris(2-chloro-1-methylethyl) phosphate is clear colorless oily liquid with high water solubility and low lipophilicity (as indicated by logKOW). This substance ismanufactured as a reactionmixture, which contains four isomers. It is the primary isomer in the mixture at 50–85% weight/weight (w/w), followed by bis(1- chloro-2-propyl)-2-chloropropyl phosphate [15–40% (w/w); CASRN: 76025-08-6], bis(2-chloropropyl)-1-chloro-2-propyl phosphate [<15% (w/w); CASRN: 76649-15-5], and tris(2- chloropropyl) phosphate [<1% (w/w); CASRN: 6145-73-9] (EURAR, 2008).

Uses

Tris(1-chloro-2-propyl) Phosphate is a flame retardant of low hydrolytic stability, used in polyurethane (PU) rigid and flexible foam, PVC, EVA, phenolics and epoxy resin.

Definition

ChEBI: Tris(1-chloropropan-2-yl) phosphate is a trialkyl phosphate.

General Description

Clear colorless viscous liquid. Tris(2-chloroisopropyl) Phosphate(TCPP), mixture of isomers is suitable for use in environmental and food residue analysis. It is a mixture of isomers, composition may vary, typical composition: main isomer tris(1-chloro-2-propyl) phosphate 66%, minor components: bis(1-chloro-2-propyl) (2-chloropropyl) phosphate and (1-chloro-2-propyl) bis(2-chloropropyl) phosphate.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Phosphoric acid tris(2-chloro-1-methylethyl) ester may hydrolyze under acidic or alkaline conditions.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition Phosphoric acid tris(2-chloro-1-methylethyl) ester emits very toxic fumes.

Fire Hazard

Phosphoric acid tris(2-chloro-1-methylethyl) ester is probably combustible.

Toxicology

Tris(1-Chloro-2-Propyl) Phosphate (TCPP) is considered a suspected carcinogenic, suspected reprotoxic, and suspected PBT (persistent, bioaccumulative and toxic) and is a potential endocrine disruptor (ECHA, 2019).  Thus, the presence of TCPP in the receiving water can affect aquatic organisms and potentially affect human health.

Tris(1-Chloro-2-Propyl) Phosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(1-Chloro-2-Propyl) Phosphate Suppliers

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View Lastest Price from Tris(1-Chloro-2-Propyl) Phosphate manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Phosphoric acid tris(2-chloro-1-methylethyl) ester 13674-84-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-30
Hebei Yanxi Chemical Co., Ltd.
Product
Phosphoric acid tris(2-chloro-1-methylethyl) ester 13674-84-5
Price
US $20.00-2.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
30 tons
Release date
2023-10-12
airuikechemical co., ltd.
Product
Tris(2-chloroisopropyl) Phosphate (TCPP) 13674-84-5
Price
US $0.00-0.00/g
Min. Order
1g
Purity
99.99%
Supply Ability
20 tons
Release date
2024-07-12

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