ChemicalBook > CAS DataBase List > 5-Hydroxymethylfurfural

5-Hydroxymethylfurfural

Product Name
5-Hydroxymethylfurfural
CAS No.
67-47-0
Chemical Name
5-Hydroxymethylfurfural
Synonyms
HMF;5-HMF;-2-furaL;5-HydroxyMethy;5-(HydroxyMethyl)-;TIMTEC-BB SBB004259;Furfural Impurity 2;Hydroxymethyl Water;5-Oxymethylfurfurole;5-HydroMethylfurfural
CBNumber
CB6266813
Molecular Formula
C6H6O3
Formula Weight
126.11
MOL File
67-47-0.mol
More
Less

5-Hydroxymethylfurfural Property

Melting point:
28-34 °C(lit.)
Boiling point:
114-116 °C1 mm Hg(lit.)
Density 
1.243 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.562(lit.)
Flash point:
175 °F
storage temp. 
2-8°C
pka
12.82±0.10(Predicted)
form 
Liquid or Crystalline Powder and/or Chunks
color 
Light yellow to yellow
Water Solubility 
Soluble in water, alcohol, ethyl acetate, acetone, dimethylformamide, benzene, ether and chloroform.
Sensitive 
Air & Light Sensitive
Merck 
14,4832
BRN 
110889
Stability:
Light Sensitive, Very Hygroscopic
InChIKey
NOEGNKMFWQHSLB-UHFFFAOYSA-N
CAS DataBase Reference
67-47-0(CAS DataBase Reference)
NIST Chemistry Reference
2-Furancarboxaldehyde, 5-(hydroxymethyl)-(67-47-0)
EPA Substance Registry System
2-Furancarboxaldehyde, 5-(hydroxymethyl)- (67-47-0)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-52/53
Safety Statements 
26-36-24/25
WGK Germany 
2
RTECS 
LT7031100
8-10
TSCA 
Yes
HS Code 
29321900
Toxicity
LD50 orally in Rabbit: 2500 mg/kg
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
H40807
Product name
5-Hydroxymethyl-2-furaldehyde
Purity
99%
Packaging
1g
Price
$66.1
Updated
2020/08/18
Sigma-Aldrich
Product number
53407
Product name
5-(Hydroxymethyl)furfural
Purity
analytical standard
Packaging
100mg
Price
$147
Updated
2020/08/18
TCI Chemical
Product number
H0269
Product name
5-Hydroxymethyl-2-furaldehyde (stabilized with Water)
Purity
>95.0%(GC)
Packaging
1g
Price
$13
Updated
2020/06/24
TCI Chemical
Product number
H0269
Product name
5-Hydroxymethyl-2-furaldehyde (stabilized with Water)
Purity
>95.0%(GC)
Packaging
5g
Price
$45
Updated
2020/06/24
Alfa Aesar
Product number
A12475
Product name
5-Hydroxymethyl-2-furaldehyde, 97%
Packaging
1g
Price
$35.8
Updated
2020/06/24
More
Less

5-Hydroxymethylfurfural Chemical Properties,Usage,Production

Chemical Properties

Beige Coloured Crystalline Solid

Uses

An antioxidant

Uses

As an indicator for excess heat-treatment in sugar-containing food.

Definition

ChEBI: A member of the class of furans that is furan which is substituted at positions 2 and 5 by formyl and hydroxymethyl substituents, respectively. Virtually absent from fresh foods, it is naturally generated in sugar-containing foods during storage, and espec ally by drying or cooking. It is the causative component in honey that affects the presystemic metabolism and pharmacokinetics of GZ in-vivo.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 7259, 1994 DOI: 10.1021/jo00103a016

Safety Profile

Questionable carcinogen with experimental tumorigenic data.Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES

Metabolic pathway

When 5-hydroxymethyl-2-furaldehyde (HMF) is administered orally or intravenously to rats, HMF or its metabolites are rapidly eliminated in the urine with the recovery of 95 ? 100% after 24 h. HMF is completely converted to two metabolites which are identified as 5- hydroxymethyl-2-furoic acid and N-(5-hydroxymethyl-2- furoyl)glycine.

Purification Methods

Crystallise it from diethyl ether/pet ether. [Beilstein 18 III/IV 100, 18/1 V 130.]

5-Hydroxymethylfurfural Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

5-Hydroxymethylfurfural Suppliers

Zhejiang Tangneng Technology Co., Ltd.
Tel
0574-55878979-
Email
yikang@cz-set.com
Country
China
ProdList
7
Advantage
58
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30163
Advantage
84
Shanghai Worldyang Chemical Co.,Ltd.
Tel
+86-21-56791066,56795766,56795797
Fax
+86-21-56795266
Email
sales@worldyachem.com
Country
China
ProdList
9108
Advantage
58
Suzhou Guide Fine Material Co.Ltd.
Tel
0512-66627360-8004;0512-66627360-8008
Fax
0512-66627360
Email
sales@guide-chemicals.com;lixm@guide-chemicals.com
Country
China
ProdList
262
Advantage
60
Shanghai TongYuan Chemical Co., Ltd.
Tel
021-69182866-
Fax
021-69182022
Email
tongyuanchem@126.com
Country
China
ProdList
4312
Advantage
58
Suzhou Runsen Pharmaceutical Technology Co., Ltd.
Tel
0512-65885589- ;
Fax
0512-65885589
Email
sales@rosun-chemical.com;sales@rosun-chemical.com
Country
China
ProdList
195
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40268
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3579
Advantage
66
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15880
Advantage
69
More
Less

View Lastest Price from 5-Hydroxymethylfurfural manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
5-Hydroxymethylfurfural 67-47-0
Price
US $10.00/PCS
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2020-11-27
Hebei Henghe Import and Export Trading Co. LTD
Product
5-Hydroxymethylfurfural 67-47-0
Price
US $70.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
20
Release date
2020-11-19
Xingtai pinmai biology science and technology co., ltd
Product
5-Hydroxymethylfurfural 67-47-0
Price
US $10.00/g
Min. Order
1g
Purity
99+%
Supply Ability
50tons
Release date
2020-09-17

67-47-0, 5-HydroxymethylfurfuralRelated Search:


  • 5-(HYDROXYMETHYL)FURFURAL 98%
  • TIMTEC-BB SBB004259
  • 5-(Hydroxymethyl)furfural, 5-Hydroxymethyl-2-furaldehyde, 5-Hydroxymethyl-2-furancarboxaldehyde
  • 5-(Hydroxymethyl)furfural, 5-Hydroxymethyl-2-furancarboxaldehyde
  • Hydroxymethylfurfuralaldehyde
  • 5-(Hydroxymethyl)furfural ,98%
  • 5-HMF
  • 5-Hydroxymethyl-2-furaldehyde (stabilized with Water)
  • 5-Hydroxymethyl-2-fluraldehyde
  • 5-(Hydroxymethyl)furfural ,97%
  • 5-Hydroxymethyl-2-furaldehyde,5-(Hydroxymethyl)furfural, 5-Hydroxymethyl-2-furancarboxaldehyde
  • 5-(Hydroxymethyl)furfural,5-(Hydroxymethyl)furfural, 5-Hydroxymethyl-2-furaldehyde, 5-Hydroxymethyl-2-furancarboxaldehyde
  • 5-(Hydroxymethyl)furan-2-carboxaldehyde
  • HydroxyMethyl furfural
  • 5-HydroxyMethylfurfural (5-HMF)
  • 5-(HydroxyMethyl)furfural, 98% 1GR
  • 5-(HydroxyMethyl)furfural, 98% 5GR
  • 5-(HydroxyMethyl)-
  • 5-HydroxyMethylfufural
  • 5-HYDROXYMETHYL-2-FURANCARBALDEHYDE
  • 5-HYDROXYMETHYL-2-FURANCARBOXALDEHYDE
  • 5-HYDROXYMETHYL-2-FURFURAL
  • 5-HYDROXYMETHYL-2-FURFUROL
  • 5-Hydroxymethyl-2-furaldehyde(HMF)
  • 5-hydroxymethylfurfural 5
  • 5-HydroMethylfurfural
  • -2-furaL
  • 5-Hydroxymethylfurfurall
  • 5-hydroxymethylfurfural(HMF)
  • Glucosamine Hydrochloride Impurity 5(Glucosamine Hydrochloride EP Impurity E)
  • Furfural Impurity 2
  • Furfural Impurity 2 (5-Hydroxymethyl Furfural)
  • 5-HMF、5-Hydroxymethylfurfural
  • 2-Furaldehyde, 5-(hydroxymethyl)-
  • 2-Hydroxymethyl-5-furfural
  • 5-(Hyddroxymethyl)Furfurole
  • 5-(Hydroxymethyl)-2-formylfuran
  • 5-(hydroxymethyl)-2-furaldehyd
  • 5-(Hydroxymethyl)-2-furancarbonal
  • 5-(hydroxymethyl)-2-furancarboxaldehyd
  • 5-(hydroxymethyl)-2-furfural (HMF)
  • 5-(Hydroxymethyl)-2-furfuraldehyde
  • 5-(Hydroxymethyl)furan-2-aldehyde
  • 5-Hydroxymethylfuraldehyde
  • 5-Hydroxymethylfurfuraldehyde
  • 5-Hydrxoymethylfurfural
  • 5-Oxymethylfurfurole
  • Hydroxymethylfurfuraldehyde
  • Hydroxymethylfurfurole
  • 5-(HYDROXYMETHYL)FURFURAL 99+%
  • 5-Hydroxymethyl-2-furaldehyde,98+%
  • 5-oxymethylfurfurole,5-(hydroxymethyl)-2-Furancarboxaldehyde,5-hydroxymethyl-2-furfural
  • 2-Furancarboxaldehyde, 5-(hydroxymethyl)-
  • 5-Hydroxymethyl-2-furancarbaldehyde for synthesis
  • 2-ForMyl-5-hydroxyMethylfuran
  • 2-Furaldehyde, 5-(hydroxyMethyl)- (8CI)
  • 5-HydroxyMethylfuD23-RFural
  • HydroxyMethyl-2-furaldeh