5-Hydroxymethylfurfural

Product Name: 5-Hydroxymethylfurfural
CAS No.: 67-47-0
Chemical Name: 5-Hydroxymethylfurfural
Synonyms: HMF;5-HMF;-2-furaL;5-HydroxyMethy;5-(HydroxyMethyl)-;TIMTEC-BB SBB004259;Furfural Impurity 2;Hydroxymethyl Water;5-Oxymethylfurfurole;5-HydroMethylfurfural
CBNumber: CB6266813
Molecular Formula: C6H6O3
Formula Weight: 126.11
MOL File: 67-47-0.mol

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5-Hydroxymethylfurfural Property

Melting point:: 28-34 °C (lit.) 28-34 °C (lit.)
Boiling point:: 114-116 °C/1 mmHg (lit.)
Density: 1.243 g/mL at 25 °C (lit.)
refractive index: n20/D 1.562(lit.)
Flash point:: 175 °F
storage temp.: 2-8°C
pka: 12.82±0.10(Predicted)
form: Liquid or Crystalline Powder and/or Chunks
color: Light yellow to yellow
Water Solubility: Soluble in water, alcohol, ethyl acetate, acetone, dimethylformamide, benzene, ether and chloroform.
Sensitive: Air & Light Sensitive
Merck: 14,4832
BRN: 110889
Stability:: Light Sensitive, Very Hygroscopic
InChIKey: NOEGNKMFWQHSLB-UHFFFAOYSA-N
CAS DataBase Reference: 67-47-0(CAS DataBase Reference)
NIST Chemistry Reference: 2-Furancarboxaldehyde, 5-(hydroxymethyl)-(67-47-0)
EPA Substance Registry System: 2-Furancarboxaldehyde, 5-(hydroxymethyl)- (67-47-0)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-52/53
Safety Statements: 26-36-24/25
WGK Germany: 2
RTECS: LT7031100
F: 8-10
TSCA: Yes
HS Code: 29321900
Hazardous Substances Data: 67-47-0(Hazardous Substances Data)
Toxicity: LD50 orally in Rabbit: 2500 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.20678
Product name: 5-Hydroxymethyl-2-furancarbaldehyde
Purity: for synthesis
Packaging: 100 mg
Price: $22.2
Updated: 2021/03/22

Sigma-Aldrich

Product number: 8.20678
Product name: 5-Hydroxymethyl-2-furancarbaldehyde
Purity: for synthesis
Packaging: 1 g
Price: $41.16
Updated: 2021/03/22

Sigma-Aldrich

Product number: W501808
Product name: 5-(Hydroxymethyl)furfural
Purity: ≥99%, FG
Packaging: 1 g
Price: $60
Updated: 2021/03/22

Sigma-Aldrich

Product number: H40807
Product name: 5-Hydroxymethyl-2-furaldehyde
Purity: 99%
Packaging: 1g
Price: $66.1
Updated: 2021/03/22

Sigma-Aldrich

Product number: 8.20678
Product name: 5-Hydroxymethyl-2-furancarbaldehyde
Purity: for synthesis
Packaging: 5 g
Price: $150.77
Updated: 2021/03/22

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5-Hydroxymethylfurfural Chemical Properties,Usage,Production

Chemical Properties

Beige Coloured Crystalline Solid

Uses

An antioxidant for grape and apple juice.

Uses

As an indicator for excess heat-treatment in sugar-containing food.

Definition

ChEBI: A member of the class of furans that is furan which is substituted at positions 2 and 5 by formyl and hydroxymethyl substituents, respectively. Virtually absent from fresh foods, it is naturally generated in sugar-containing foods during storage, and espec ally by drying or cooking. It is the causative component in honey that affects the presystemic metabolism and pharmacokinetics of GZ in-vivo.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 7259, 1994 DOI: 10.1021/jo00103a016

Safety Profile

Questionable carcinogen with experimental tumorigenic data.Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES

Metabolic pathway

When 5-hydroxymethyl-2-furaldehyde (HMF) is administered orally or intravenously to rats, HMF or its metabolites are rapidly eliminated in the urine with the recovery of 95 ? 100% after 24 h. HMF is completely converted to two metabolites which are identified as 5- hydroxymethyl-2-furoic acid and N-(5-hydroxymethyl-2- furoyl)glycine.

Purification Methods

Crystallise it from diethyl ether/pet ether. [Beilstein 18 III/IV 100, 18/1 V 130.]

5-Hydroxymethylfurfural Preparation Products And Raw materials

Raw materials

Preparation Products

2,5-Furandimethanol 2,5-Furandicarboxylic acid 5-ACETOXYMETHYL-2-FURALDEHYDE 5-[(1,3-DIOXO-1,3-DIHYDRO-2H-ISOINDOL-2-YL)METHYL]-2-FURALDEHYDE

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5-Hydroxymethylfurfural Suppliers

Belgium 2 Canada 1 China 407 Europe 1 France 1 Germany 7 India 2 Japan 4 Slovakia 1 Switzerland 1 United Kingdom 10 United States 52 Global 489

Zhejiang Tangneng Technology Co., Ltd.

Tel: 0574-55878979-
Email: zhoujingjing@sugarenergy.com
Country: China
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Alfa Aesar

Tel: 400-610-6006; 021-67582000
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
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Shanghai Worldyang Chemical Co.,Ltd.

Tel: +86-21-56791066;56795766;56795797
Fax: +86-21-56795266
Email: sales@worldyachem.com
Country: China
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Suzhou Guide Fine Material Co.Ltd.

Tel: 0512-66627360-8004;0512-66627360-8008
Fax: 0512-66627360
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Shanghai TongYuan Chemical Co., Ltd.

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T&W GROUP

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Suzhou Runsen Pharmaceutical Technology Co., Ltd.

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J & K SCIENTIFIC LTD.

Tel: 010-82848833- ;010-82848833-
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com;market6@jkchemical.com
Country: China
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Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 21-61259100-
Fax: 86-21-61259102
Email: sh@meryer.com
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INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3579
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View Lastest Price from 5-Hydroxymethylfurfural manufacturers

Wuhan wingroup Pharmaceutical Co., Ltd

Product: 5-hydroxymethylfurfural 67-47-0
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000MT/Month
Release date: 2021-07-16

Dideu Industries Group Limited

Product: 5-Hydroxymethylfurfural 67-47-0
Price: US $1.10/g
Min. Order: 1g
Purity: 99.9%
Supply Ability: 100 Tons min
Release date: 2021-09-18

Baoji Guokang Healthchem co.,ltd

Product: 5-Hydroxymethylfurfural 67-47-0
Price: US $1208.00/KG
Min. Order: 1KG
Purity: 99
Supply Ability: 10T
Release date: 2021-06-07

67-47-0, 5-HydroxymethylfurfuralRelated Search:

5-ACETOXYMETHYL-2-FURALDEHYDE 5-(2-METHOXY-PHENOXYMETHYL)-FURAN-2-CARBOXYLIC ACID 5-(NAPHTHALEN-2-YLOXYMETHYL)-FURAN-2-CARBOXYLIC ACID 5-[([1,1'-BIPHENYL]-4-YLOXY)METHYL]-2-FUROIC ACID ETHYL 5-[(ACETYLOXY)METHYL]-2-FUROATE METHYL 5-[([1,1'-BIPHENYL]-4-YLOXY)METHYL]-2-FUROATE Dimethyl Furan-2,5-dicarboxylate 5-FORMYL-2-FURANCARBOXYLIC ACID Trimethylolpropane 5-Hydroxymethylfurfural CARBOXYMETHYLCELLULOSE SODIUM SALT Hydroxymethyl 2-Hydroxyethyl methacrylate 5-Hydroxymethylthiazole 5-Methyl furfural 5-Nitrofurfural methylol cellulose Furfural

5-(HYDROXYMETHYL)FURFURAL 98%

TIMTEC-BB SBB004259

5-(Hydroxymethyl)furfural, 5-Hydroxymethyl-2-furaldehyde, 5-Hydroxymethyl-2-furancarboxaldehyde

5-(Hydroxymethyl)furfural, 5-Hydroxymethyl-2-furancarboxaldehyde

Hydroxymethylfurfuralaldehyde

5-(Hydroxymethyl)furfural ,98%

5-HMF

5-Hydroxymethyl-2-furaldehyde (stabilized with Water)

5-Hydroxymethyl-2-fluraldehyde

5-(Hydroxymethyl)furfural ,97%

5-Hydroxymethyl-2-furaldehyde,5-(Hydroxymethyl)furfural, 5-Hydroxymethyl-2-furancarboxaldehyde

5-(Hydroxymethyl)furfural,5-(Hydroxymethyl)furfural, 5-Hydroxymethyl-2-furaldehyde, 5-Hydroxymethyl-2-furancarboxaldehyde

5-(Hydroxymethyl)furan-2-carboxaldehyde

HydroxyMethyl furfural

5-HydroxyMethylfurfural (5-HMF)

5-(HydroxyMethyl)furfural, 98% 1GR

5-(HydroxyMethyl)furfural, 98% 5GR

5-(HydroxyMethyl)-

5-HydroxyMethylfufural

5-HYDROXYMETHYL-2-FURANCARBALDEHYDE

5-HYDROXYMETHYL-2-FURANCARBOXALDEHYDE

5-HYDROXYMETHYL-2-FURFURAL

5-HYDROXYMETHYL-2-FURFUROL

5-Hydroxymethyl-2-furaldehyde(HMF)

5-hydroxymethylfurfural 5

5-HydroMethylfurfural

-2-furaL

5-Hydroxymethylfurfurall

5-hydroxymethylfurfural(HMF)

Glucosamine Hydrochloride Impurity 5(Glucosamine Hydrochloride EP Impurity E)

Furfural Impurity 2

Furfural Impurity 2 (5-Hydroxymethyl Furfural)

5-HMF、5-Hydroxymethylfurfural

2-Furaldehyde, 5-(hydroxymethyl)-

2-Hydroxymethyl-5-furfural

5-(Hyddroxymethyl)Furfurole

5-(Hydroxymethyl)-2-formylfuran

5-(hydroxymethyl)-2-furaldehyd

5-(Hydroxymethyl)-2-furancarbonal

5-(hydroxymethyl)-2-furancarboxaldehyd

5-(hydroxymethyl)-2-furfural (HMF)

5-(Hydroxymethyl)-2-furfuraldehyde

5-(Hydroxymethyl)furan-2-aldehyde

5-Hydroxymethylfuraldehyde

5-Hydroxymethylfurfuraldehyde

5-Hydrxoymethylfurfural

5-Oxymethylfurfurole

Hydroxymethylfurfuraldehyde

Hydroxymethylfurfurole

5-(HYDROXYMETHYL)FURFURAL 99+%

5-Hydroxymethyl-2-furaldehyde,98+%

5-oxymethylfurfurole,5-(hydroxymethyl)-2-Furancarboxaldehyde,5-hydroxymethyl-2-furfural

2-Furancarboxaldehyde, 5-(hydroxymethyl)-

5-Hydroxymethyl-2-furancarbaldehyde for synthesis

2-ForMyl-5-hydroxyMethylfuran

2-Furaldehyde, 5-(hydroxyMethyl)- (8CI)

5-HydroxyMethylfuD23-RFural

HydroxyMethyl-2-furaldeh