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2,5-Furandicarboxylic acid

Product Name
2,5-Furandicarboxylic acid
CAS No.
3238-40-2
Chemical Name
2,5-Furandicarboxylic acid
Synonyms
FURAN-2,5-DICARBOXYLIC ACID;2,5-furandicarboxylate;2,5-Furandicarboxylic;2,3-furandicarboxylic acid;2,5-Furandicarboxylic acid (FDCA);FDCA;NSC 40740;5-Furandic;5-Furandicar;DEHYDROMUCIC ACID
CBNumber
CB6264091
Molecular Formula
C6H4O5
Formula Weight
156.09
MOL File
3238-40-2.mol
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2,5-Furandicarboxylic acid Property

Melting point:
>300 °C
Boiling point:
240.29°C (rough estimate)
Density 
1.7400
refractive index 
1.6400 (estimate)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly Sonicated)
form 
Solid
pka
2.28±0.10(Predicted)
color 
White to Dark Brown
Water Solubility 
1g/L(18 ºC)
Stability:
Light Sensitive, Very Hygroscopic
InChIKey
CHTHALBTIRVDBM-UHFFFAOYSA-N
LogP
-1.43 at 20℃
CAS DataBase Reference
3238-40-2(CAS DataBase Reference)
NIST Chemistry Reference
Furan-2,5-dicarboxylic acid(3238-40-2)
EPA Substance Registry System
2,5-Furandicarboxylic acid (3238-40-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-36
Safety Statements 
26-36/37/39-36/37
WGK Germany 
1
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29321900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
722081
Product name
2,5-Furandicarboxylic acid
Purity
97%
Packaging
5g
Price
$280
Updated
2024/03/01
TCI Chemical
Product number
F0710
Product name
2,5-Furandicarboxylic Acid
Purity
>98.0%(HPLC)(T)
Packaging
5g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
F0710
Product name
2,5-Furandicarboxylic Acid
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$236
Updated
2024/03/01
Alfa Aesar
Product number
H28718
Product name
Furan-2,5-dicarboxylic acid, 98%
Packaging
1g
Price
$94.5
Updated
2024/03/01
Alfa Aesar
Product number
H28718
Product name
Furan-2,5-dicarboxylic acid, 98%
Packaging
5g
Price
$254
Updated
2024/03/01
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2,5-Furandicarboxylic acid Chemical Properties,Usage,Production

Description

2,5-Furandicarboxylic acid (FDCA) is an organic chemical compound consisting of two carboxylic acid groups attached to a central furan ring. It was first reported as dehydromucic acid by Rudolph Fittig and Heinzelmann in 1876, who produced it via the action of concentrated hydrobromic acid upon mucic acid. It can be produced from certain carbohydrates and as such is a renewable resource, it was identified by the US Department of Energy as one of 12 priority chemicals for establishing the “green” chemistry industry of the future.Furan-2,5-dicarboxylic acid (FDCA) has been suggested as an important renewable building block because it can substitute for terephthalic acid (PTA) in the production of polyesters and other current polymers containing an aromatic moiety.
wikipedia

Chemical Properties

2,5-Furandicarboxylic acid is a chemical intermediate with high sensitivity and good stability. It is soluble in water under alkaline conditions and is a white powder solid under acidic conditions, and is an important monomer for the preparation of corrosion-resistant plastics. It is irritating to eyes, respiratory tract and skin.

History

2,5-Furandicarboxylic acid, also known as dehydromucic acid, is a furan derivative. This organic compound was first obtained by Fittig and Heinzelmann in 1876. More than 125 years later, FDCA was identified by the US Department of Energy as one of 12 priority chemicals for establishing the "green" chemistry industry of the future. On a laboratory scale, it is often synthesized from 5- hydroxymethylfurfural (HMF), which in turn can be obtained from carbohydrate-containing sources such as glucose, fructose, sucrose, and starch. From fructose and glucose, HMF is obtained by acidic eliminating three moles of water.

Uses

Interest in renewable based polymers has led to 2,5-furandicarboxylic acid being proposed as a green, sustainable alternative to the widely used petroleum-based terephthalic acid in the synthesis of polyesters. 2,5-Furandicarboxylic acid is produced from oxidation of 5-hydroxymethylfurfural (HMF) which is obtained from the dehydration of bio-based sugars such as fructose.

Uses

2,5-Furandicarboxylic acid (FDCA) is a renewable, greener substitute for terephthalate in the production of polyesters. It is widely used as a precursor for the synthesis of bio-based polyesters and various other polymers.

Applications of FDCA in the synthesis of several metal-organic frameworks (MOFs) have also been reported.

Preparation

2,5-Furandicarboxylic acid (FDCA) can be produced from biomass or its derived sugars or platform chemicals, and has demonstrated to be a very promising substitute for petroleum-derived polymer products.
Chapter 5 - Advances in the synthesis and application of 2,5-furandicarboxylic acid

Definition

ChEBI: A member of the class of furans carrying two carboxy substituents at positions 2 and 5.

Application

2,5-Furandicarboxylic acid (FDCA) is a renewable, greener substitute for terephthalate in the production of polyesters. It is widely used as a precursor for the synthesis of bio-based polyesters and various other polymers.
Applications of FDCA in the synthesis of several metal-organic frameworks (MOFs) have also been reported.

Synthesis Reference(s)

Tetrahedron Letters, 26, p. 1777, 1985 DOI: 10.1016/S0040-4039(00)98336-9

Flammability and Explosibility

Not classified

Solubility in organics

2,5-Furandicarboxylic acid (FDCA) serves as a monomer in various polyesters and is often obtained through the oxidation of 5-hydroxymethylfurfural. In pure solvents and binary mixtures, the solubility of FDCA increased with the increasing temperature. The order from largest to smallest solubility in pure solvents was as follows: methanol, 1-butanol, isobutanol, acetic acid, water, MIBK, ethyl acetate, and acetonitrile.
https://doi.org/10.1021/acs.jced.7b00927

2,5-Furandicarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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2,5-Furandicarboxylic acid Suppliers

Zhongke Guosheng (Hangzhou) Technology Co., LTD
Tel
15698858777
Email
sales@guoshengtech.com
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China
ProdList
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58
Hefei Leaf Biotech Co.,Ltd.
Tel
055162628115 18155185130
Fax
+86-551-62628115
Email
3466118576@qq.com
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China
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Suzhou Runsen Pharmaceutical Technology Co., Ltd.
Tel
0512-65885589 18751140360
Fax
0512-65885589
Email
sales@rosen-chemicals.com
Country
China
ProdList
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Hubei Smer Pharmaceutical Technology Co., Ltd.
Tel
15527913960
Email
1784042512@qq.com
Country
China
ProdList
491
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Shanghai Eyougene biotechnology development co.LTD
Tel
021-52277372 13564545227
Email
dom.sales@eyougene.com
Country
China
ProdList
245
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58
Hangzhou Bingochem Co., Ltd.
Tel
0571-8512-5372
Email
sales@bingochem.com
Country
China
ProdList
21669
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58
Zhejiang Tangneng Technology Co., Ltd.
Tel
18067583072
Email
rsq@sugarenergy.com
Country
China
ProdList
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58
Shijiazhuang Jianxin Biotechnology Co., LTD
Tel
0311-17692708569 19062313169
Email
19062313169@163.com
Country
China
ProdList
292
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J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
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View Lastest Price from 2,5-Furandicarboxylic acid manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
2,5-Furandicarboxylic acid 3238-40-2
Price
US $0.00-0.00/Kg/Drum
Min. Order
1KG
Purity
99%min
Supply Ability
500kg
Release date
2021-06-02
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
2,5-Furandicarboxylic acid 3238-40-2
Price
US $100.00-75.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000Ton
Release date
2024-08-13
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
2,5-Furandicarboxylic acid 3238-40-2
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-25

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