ChemicalBook > CAS DataBase List > 2-Hydroxyethyl methacrylate

2-Hydroxyethyl methacrylate

Product Name
2-Hydroxyethyl methacrylate
CAS No.
868-77-9
Chemical Name
2-Hydroxyethyl methacrylate
Synonyms
GMA;HEMA;EB 109;GE 610;Heme-a;HEMA 90;Mhoromer;BleMMer E;NSC 24180;HEMA HISS
CBNumber
CB4690827
Molecular Formula
C6H10O3
Formula Weight
130.14
MOL File
868-77-9.mol
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2-Hydroxyethyl methacrylate Property

Melting point:
-12 °C
Boiling point:
67 °C3.5 mm Hg(lit.)
Density 
1.073 g/mL at 25 °C(lit.)
vapor density 
5 (vs air)
vapor pressure 
0.01 mm Hg ( 25 °C)
refractive index 
n20/D 1.453(lit.)
Flash point:
207 °F
storage temp. 
2-8°C
form 
Liquid
pka
13.83±0.10(Predicted)
color 
Clear
Odor
Ester like
Water Solubility 
soluble
Sensitive 
Air Sensitive
BRN 
1071583
Stability:
Unstable - may polymerize in the absence of stabilizer. May be stabilized with, or contain small amounts of, diethylene glycol monomethacrylate, di(ethylene glycol)dimethacrylate, methacrylic acid. Incompatible with strong oxidizing agents, free radical initiators, peroxides, steel. Closed containers may explode if heated due to runaway polymer
InChIKey
WOBHKFSMXKNTIM-UHFFFAOYSA-N
CAS DataBase Reference
868-77-9(CAS DataBase Reference)
NIST Chemistry Reference
2-Hydroxyethyl methacrylate(868-77-9)
EPA Substance Registry System
2-Hydroxyethyl methacrylate (868-77-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38-43-36/37/38
Safety Statements 
26-36/37-28A-28
WGK Germany 
1
RTECS 
OZ4725000
8
TSCA 
Yes
HS Code 
29161490
Hazardous Substances Data
868-77-9(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 5050 mg/kg LD50 dermal Rabbit > 3000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P321Specific treatment (see … on this label).

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
128635
Product name
2-Hydroxyethyl methacrylate
Purity
contains ≤250 ppm monomethyl ether hydroquinone as inhibitor, 97%
Packaging
1kg
Price
$42.3
Updated
2021/03/22
Sigma-Aldrich
Product number
8.00588
Product name
2-Hydroxyethyl methacrylate
Purity
(stabilised with hydroquinone monomethyl ether) for synthesis
Packaging
250 mL
Price
$44.58
Updated
2021/03/22
Sigma-Aldrich
Product number
17348
Product name
2-Hydroxyethyl methacrylate
Purity
embedding medium (for microscopy)
Packaging
250 mL
Price
$92.4
Updated
2021/03/22
Sigma-Aldrich
Product number
8.00588
Product name
2-Hydroxyethyl methacrylate
Purity
(stabilised with hydroquinone monomethyl ether) for synthesis
Packaging
2.5 L
Price
$97.12
Updated
2021/03/22
Sigma-Aldrich
Product number
128635
Product name
2-Hydroxyethyl methacrylate
Purity
contains ≤250 ppm monomethyl ether hydroquinone as inhibitor, 97%
Packaging
18kg
Price
$445
Updated
2021/03/22
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2-Hydroxyethyl methacrylate Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

2-Hydroxyethyl methacrylate is used for preparation of hydrophilic polymers for biomedical devices.

Uses

2-Hydroxyethyl methacrylate is the methacrylic monomer for use in UV inks, adhesives, lacquers, dental materials, artificial nails, etc.

Definition

2-Hydroxyethyl methacrylate is an enoate ester that is the monomethacryloyl derivative of ethylene glycol.

Hazard

30% grade (with xylene): Flammable, moderate fire risk.

Purification Methods

Dissolve the ester in water and extract with n-heptane to remove ethylene glycol dimethacrylate (checked by gas-liquid chromatography and by NMR) and distil it twice under reduced pressure [Strop et al. J Phys Chem 80 694 1976]. [Beilstein 2 IV 1530.]

2-Hydroxyethyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Hydroxyethyl methacrylate Suppliers

SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel
021-52696680-
Fax
021-69106780
Email
bangchem1@163.com
Country
China
ProdList
4739
Advantage
60
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
021-20337333-801
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
24980
Advantage
65
Cheng Du Micxy Chemical Co.,Ltd
Tel
028-85632863-
Fax
028-85632863
Email
sales@micxy.com;
Country
China
ProdList
13065
Advantage
58
Qingdao RENAS Polymer Material Co.,Ltd.
Tel
86-0532-86867058
Fax
0532-86867058
Email
sales@qdrenas.com
Country
China
ProdList
105
Advantage
50
Shanghai Kangtuo Chemical Co., Ltd.
Tel
021-69185553;021-69185552
Fax
021-69186006
Email
kangtuochem@163.com;kangtuochem@163.com
Country
China
ProdList
4331
Advantage
55
Yancheng Green Chemicals Co.,Ltd.
Tel
Email
marketing@royal-chem.com
Country
China
ProdList
58
Advantage
58
Taizhou Haoxiang Chemical Co., Ltd
Tel
0523-13512558-852
Fax
13512558852
Email
363917402@qq.com
Country
China
ProdList
3
Advantage
58
Hubei yongkuo Technology Co., Ltd
Tel
027-59223108- ;027-59223108-
Fax
027-59223108
Email
1248580099@qq.com;1248580055@qq.com
Country
China
ProdList
9009
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40264
Advantage
62
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View Lastest Price from 2-Hydroxyethyl methacrylate manufacturers

Jinan Finer Chemical Co., Ltd
Product
2-Hydroxyethyl methacrylate (HEMA) 868-77-9
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
2000mt/year
Release date
2020-09-11
Yancheng Green Chemicals Co.,Ltd
Product
2-Hydroxyethyl methacrylate,HEMA 868-77-9
Price
US $0.00/KG
Min. Order
200KG
Purity
98
Supply Ability
10mt
Release date
2020-12-28
Wuhan Mulei New Material Technology Co. Ltd
Product
2-Hydroxyethyl methacrylate 868-77-9
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
99.9%
Supply Ability
100000kg per month
Release date
2021-04-03

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