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Ethyl methacrylate

Product Name
Ethyl methacrylate
CAS No.
97-63-2
Chemical Name
Ethyl methacrylate
Synonyms
EMA;PEMT;CD227;Episialin;rhoplexac-33;Rhoplex ac-33;Ethyl methacryla;CA15-3 ELISA Kit;Ethylmethacrylat;Ethylmethylacryate
CBNumber
CB9486656
Molecular Formula
C6H10O2
Formula Weight
114.14
MOL File
97-63-2.mol
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Ethyl methacrylate Property

Melting point:
-75 °C
Boiling point:
118-119 °C (lit.)
Density 
0.917 g/mL at 25 °C (lit.)
vapor density 
>3.9 (vs air)
vapor pressure 
15 mm Hg ( 20 °C)
refractive index 
n20/D 1.413(lit.)
Flash point:
60 °F
storage temp. 
Refrigerator (+4°C) + Flammables area
solubility 
5.1g/l
form 
Liquid
color 
Clear colorless
Odor
Acrid acrylic.
explosive limit
1.8%(V)
Water Solubility 
4 g/L (20 ºC)
BRN 
471201
Stability:
Polymerizes in the presence of light or heat. Incompatible with peroxides, oxidizing agents, bases, acids, reducing agents, halogens and amines. Flammable.
CAS DataBase Reference
97-63-2(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenoic acid, 2-methyl-, ethyl ester(97-63-2)
EPA Substance Registry System
Ethyl methacrylate (97-63-2)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38-43
Safety Statements 
9-16-29-33
RIDADR 
UN 2277 3/PG 2
WGK Germany 
1
RTECS 
OZ4550000
Autoignition Temperature
771 °F
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29161490
Hazardous Substances Data
97-63-2(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 14600 mg/kg LD50 dermal Rabbit > 9130 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.00579
Product name
Ethyl methacrylate
Purity
(stabilised) for synthesis
Packaging
100 mL
Price
$30.15
Updated
2021/03/22
Sigma-Aldrich
Product number
234893
Product name
Ethyl methacrylate
Purity
contains 15-20 ppm monomethyl ether hydroquinone as inhibitor, 99%
Packaging
100ml
Price
$54.4
Updated
2021/03/22
Sigma-Aldrich
Product number
8.00579
Product name
Ethyl methacrylate
Purity
(stabilised) for synthesis
Packaging
500 mL
Price
$56.89
Updated
2021/03/22
Sigma-Aldrich
Product number
234893
Product name
Ethyl methacrylate
Purity
contains 15-20 ppm monomethyl ether hydroquinone as inhibitor, 99%
Packaging
1l
Price
$89.1
Updated
2021/03/22
TCI Chemical
Product number
M0084
Product name
Ethyl Methacrylate (stabilized with HQ)
Purity
>99.0%(GC)
Packaging
25mL
Price
$15
Updated
2021/03/22
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Ethyl methacrylate Chemical Properties,Usage,Production

Chemical Properties

colourless liquid with an unpleasant odour

Chemical Properties

Ethyl methacrylate is a clear, colorless, and highly flammable liquid that polymerizes but at a slower rate than that of the parent acrylate.

Uses

Ethyl methacrylate can be manufactured via a reaction of methacrylic acid or methyl acrylate with ethanol. It is used primarily for manufacturing polymers and as a component of acrylic polymers for surface coatings and as a structural monomer for some artificial fingernail formulations.

Uses

Ethyl methacrylate is used in dental protheses or in photobonded sculptured nails.

Uses

Polymers, chemical intermediates.

Production Methods

Ethyl methacrylate can be manufactured via a reaction of methacrylic acid or methyl acrylate with ethanol.

General Description

A colorless moderately toxic liquid with an acrid odor. Flash point of 70°F. Boiling point 278°F. Vapors irritate the eyes and respiratory system. Less dense than water. Not soluble in water. Used to make polymers and other chemicals.

Air & Water Reactions

Highly flammable. A very dangerous fire and explosion hazard. Not soluble in water.

Reactivity Profile

May polymerize if heated for prolonged periods or accidentally contaminated. If polymerization takes place inside a container, the container may violently rupture. Can react with oxidizing materials. When heated to decomposition Ethyl methacrylate emits irritating fumes and acrid smoke [Sax, 9th ed., 1996, p. 1576].

Hazard

Flammable, dangerous fire and explosion hazard. An irritant.

Health Hazard

Inhalation may cause irritation of the mucous membrane. Ingestion causes irritation of mouth and stomach. Contact with liquid irritates eyes and skin.

Fire Hazard

Behavior in Fire: Sealed containers may rupture explosively if hot. Heat can cause a violent polymerization reaction with rapid release of energy. Vapors are heavier than air and can travel to a source of ignition and flash back.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: If proper concentration of inhibitor is not present or when material is hot, a violent polymerization reaction may occur; Inhibitor of Polymerization: Oxygen in the air inhibits polymerization.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. Mildly toxic by inhalation. Experimental teratogenic and reproductive effects. A skin irritant. A very dangerous fire and explosion hazard when exposed to heat, sparks, or flame; can react with oxidzing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Carcinogenicity

Not listed by ACGIH, California Proposition 65, IARC, NTP, or OSHA.

Purification Methods

Wash the ester successively with 5% aqueous NaNO2, 5% NaHSO3, 5% NaOH, then water. Dry it over MgSO4, add 0.2% (w/w) of phenyl-.-naphthylamine, and distil it through a short Vigreux column (p 11) [Schultz J Am Chem Soc 80 1854 1958]. [Beilstein 2 IV 1523.]

Ethyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyl methacrylate Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40264
Advantage
62
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30159
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24555
Advantage
81
Energy Chemical
Tel
021-58432009-
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
42923
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028-
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12282
Advantage
60
Adamas Reagent, Ltd.
Tel
400-600-9262
Email
bxy@titansci.com
Country
China
ProdList
13915
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202- ; ;
Fax
+86-21-64545202
Email
jerry.ma@hanhonggroup.com;jerry.ma@hanhonggroup.com;jerry.ma@hanhonggroup.com
Country
China
ProdList
43255
Advantage
64
Chengdu XiYa Chemical Technology Co., Ltd.
Tel
;
Fax
0539-6365991
Email
sale@xiyashiji.com;3007716753@qq.com
Country
China
ProdList
10578
Advantage
57
Syntechem Co.,Ltd
Tel
Please Email
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
13009
Advantage
57
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View Lastest Price from Ethyl methacrylate manufacturers

Hebei Crovell Biotech Co Ltd
Product
Ethyl methacrylate 97-63-2
Price
US $10.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 ton
Release date
2021-06-30
career henan chemical co
Product
Ethyl methacrylate 97-63-2
Price
US $1.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
100mt
Release date
2018-12-16

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