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5-Hydroxymethylfurfural

Product Name
5-Hydroxymethylfurfural
CAS No.
67-47-0
Chemical Name
5-Hydroxymethylfurfural
Synonyms
HMF;5-HMF;-2-furaL;5-HydroxyMethy;5-(HydroxyMethyl)-;TIMTEC-BB SBB004259;Furfural Impurity 2;Hydroxymethyl Water;5-Oxymethylfurfurole;5-HydroMethylfurfural
CBNumber
CB6266813
Molecular Formula
C6H6O3
Formula Weight
126.11
MOL File
67-47-0.mol
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5-Hydroxymethylfurfural Property

Melting point:
28-34 °C (lit.) 28-34 °C (lit.)
Boiling point:
114-116 °C/1 mmHg (lit.)
Density 
1.243 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.562(lit.)
Flash point:
175 °F
storage temp. 
2-8°C
pka
12.82±0.10(Predicted)
form 
Liquid or Crystalline Powder and/or Chunks
color 
Light yellow to yellow
Water Solubility 
Soluble in water, alcohol, ethyl acetate, acetone, dimethylformamide, benzene, ether and chloroform.
Sensitive 
Air & Light Sensitive
Merck 
14,4832
BRN 
110889
Stability:
Light Sensitive, Very Hygroscopic
InChIKey
NOEGNKMFWQHSLB-UHFFFAOYSA-N
CAS DataBase Reference
67-47-0(CAS DataBase Reference)
NIST Chemistry Reference
2-Furancarboxaldehyde, 5-(hydroxymethyl)-(67-47-0)
EPA Substance Registry System
2-Furancarboxaldehyde, 5-(hydroxymethyl)- (67-47-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-52/53
Safety Statements 
26-36-24/25
WGK Germany 
2
RTECS 
LT7031100
8-10
TSCA 
Yes
HS Code 
29321900
Hazardous Substances Data
67-47-0(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 2500 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.20678
Product name
5-Hydroxymethyl-2-furancarbaldehyde
Purity
for synthesis
Packaging
100 mg
Price
$22.2
Updated
2021/03/22
Sigma-Aldrich
Product number
8.20678
Product name
5-Hydroxymethyl-2-furancarbaldehyde
Purity
for synthesis
Packaging
1 g
Price
$41.16
Updated
2021/03/22
Sigma-Aldrich
Product number
W501808
Product name
5-(Hydroxymethyl)furfural
Purity
≥99%, FG
Packaging
1 g
Price
$60
Updated
2021/03/22
Sigma-Aldrich
Product number
H40807
Product name
5-Hydroxymethyl-2-furaldehyde
Purity
99%
Packaging
1g
Price
$66.1
Updated
2021/03/22
Sigma-Aldrich
Product number
8.20678
Product name
5-Hydroxymethyl-2-furancarbaldehyde
Purity
for synthesis
Packaging
5 g
Price
$150.77
Updated
2021/03/22
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5-Hydroxymethylfurfural Chemical Properties,Usage,Production

Chemical Properties

Beige Coloured Crystalline Solid

Uses

An antioxidant for grape and apple juice.

Uses

As an indicator for excess heat-treatment in sugar-containing food.

Definition

ChEBI: A member of the class of furans that is furan which is substituted at positions 2 and 5 by formyl and hydroxymethyl substituents, respectively. Virtually absent from fresh foods, it is naturally generated in sugar-containing foods during storage, and espec ally by drying or cooking. It is the causative component in honey that affects the presystemic metabolism and pharmacokinetics of GZ in-vivo.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 7259, 1994 DOI: 10.1021/jo00103a016

Safety Profile

Questionable carcinogen with experimental tumorigenic data.Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES

Metabolic pathway

When 5-hydroxymethyl-2-furaldehyde (HMF) is administered orally or intravenously to rats, HMF or its metabolites are rapidly eliminated in the urine with the recovery of 95 ? 100% after 24 h. HMF is completely converted to two metabolites which are identified as 5- hydroxymethyl-2-furoic acid and N-(5-hydroxymethyl-2- furoyl)glycine.

Purification Methods

Crystallise it from diethyl ether/pet ether. [Beilstein 18 III/IV 100, 18/1 V 130.]

5-Hydroxymethylfurfural Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 5-Hydroxymethylfurfural manufacturers

Baoji Guokang Bio-Technology Co., Ltd.
Product
5-Hydroxymethylfurfural 67-47-0
Price
US $142.00/g
Min. Order
100g
Purity
98%
Supply Ability
100kg
Release date
2021-06-04
Wuhan wingroup Pharmaceutical Co., Ltd
Product
5-hydroxymethylfurfural 67-47-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000MT/Month
Release date
2021-07-16
Baoji Guokang Healthchem co.,ltd
Product
5-Hydroxymethylfurfural 67-47-0
Price
US $1208.00/KG
Min. Order
1KG
Purity
99
Supply Ability
10T
Release date
2021-06-07

67-47-0, 5-HydroxymethylfurfuralRelated Search:


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