ChemicalBook > CAS DataBase List > 3,5-Dimethoxytoluene

3,5-Dimethoxytoluene

Product Name
3,5-Dimethoxytoluene
CAS No.
4179-19-5
Chemical Name
3,5-Dimethoxytoluene
Synonyms
1,3-Dimethoxy-5-methylbenzene;SKL305;3,5-DIMETHOXYTOLUENE;ORCINOL DIMETHYL ETHER;Toluene, 3,5-dimethoxy-;3,5-Dimethoxytoluene,99%;3,5-Dimethoxytoluene >3,5-DiMethoxytoluene, GC 98%;1,3-dimethoxy-5-methyl-benzen;3,5-Dimethoxy-1-methylbenzene
CBNumber
CB0230254
Molecular Formula
C9H12O2
Formula Weight
152.19
MOL File
4179-19-5.mol
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3,5-Dimethoxytoluene Property

Melting point:
61-62 C
Boiling point:
244 °C (lit.)
Density 
1.039 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.522(lit.)
Flash point:
215 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Sparingly), Methanol (Sparingly)
form 
Liquid
Specific Gravity
1.039
color 
Clear colorless to yellow
Odor
Warm and sweet, nut-like, earthy-mossy odor
BRN 
2043558
LogP
2.897 (est)
CAS DataBase Reference
4179-19-5(CAS DataBase Reference)
NIST Chemistry Reference
3,5-Dimethoxytoluene(4179-19-5)
EPA Substance Registry System
3,5-Dimethoxytoluene (4179-19-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
TSCA 
Yes
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
423742
Product name
3,5-Dimethoxytoluene
Purity
98%
Packaging
1g
Price
$20.52
Updated
2024/03/01
TCI Chemical
Product number
D2526
Product name
3,5-Dimethoxytoluene
Purity
>97.0%(GC)
Packaging
5g
Price
$47
Updated
2024/03/01
TCI Chemical
Product number
D2526
Product name
3,5-Dimethoxytoluene
Purity
>97.0%(GC)
Packaging
25g
Price
$186
Updated
2024/03/01
Alfa Aesar
Product number
L00809
Product name
3,5-Dimethoxytoluene, 98%
Packaging
1g
Price
$35.65
Updated
2024/03/01
Alfa Aesar
Product number
L00809
Product name
3,5-Dimethoxytoluene, 98%
Packaging
5g
Price
$102.65
Updated
2024/03/01
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3,5-Dimethoxytoluene Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to yellow liquid

Uses

3,5-Dimethoxytoluene (DMT) may be used in the synthesis of 3,5-dimethoxybenzoic acid by oxidation and 2-methoxy-6-methyl-1,4-benzoquinone by catalytic oxidation with hydrogen peroxide (H2O2)/methyltrioxorhenium (CH3ReO3) in dimethyl carbonate (DMC).

Uses

3,5-Dimethoxytoluene has been suggested for use in perfume compositions as supporting note for Oakmoss and Vetiver, and as a novel note in Chypre, Fougere and Oriental fragrance types.

Definition

ChEBI: 3,5-dimethoxytoluene is a member of the class of toluenes that is toluene in which the hydrogens at positions 3 and 5 have been replaced by methoxy groups. It is the major scent compound of many rose varieties. It has a role as a fragrance and a plant metabolite. It is a member of toluenes and a member of methoxybenzenes.

Production Methods

3,5-Dimethoxytoluene can be produced from Orcinol in weak aqueous alkali with Dimethylsulfate at controlled temperature.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 6, p. 859, 1988
The Journal of Organic Chemistry, 70, p. 3275, 2005 DOI: 10.1021/jo050075r

General Description

3,5-Dimethoxytoluene (DMT) is a methoxylated phenolic derivative. It is reported to be one of the main constituent of the floral volatiles in different rose varieties. It has been biosynthesized from orcinol by two successive methylation catalyzed by O-methyltransferases (OMTs). The features of its aerobic oxidation with metal/bromide catalysts have been investigated.

Synthesis

A solution of dry orcinol (14.2 g,0.115 mole) in dry anhydrous acetone(150 ml) containing anhydrous potassium carbonate (45 g) is refluxed withdimethyl sulphate (23.6 ml,31.46 g, 0.25 mole) for 4 hr. The dimethylsulphate is added in small lots of 5 ml. After refluxing, the solution isfiltered and the inorganic residue washed with hot acetone (2 x 25 ml).The combined acetone solution is distilled and the residue macerated withcrushed ice. It is extracted with ether, the ether extract dried (anhydroussodium sulphate) and distilled. Yield 14.2 g (81.6%).B.p.102° (8 mm)

3,5-Dimethoxytoluene Preparation Products And Raw materials

Raw materials

Preparation Products

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3,5-Dimethoxytoluene Suppliers

Anyang Hongmeng New Materials Co., Ltd
Tel
19588588067 19588588067
Email
19588588067@163.com
Country
China
ProdList
9737
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1390
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
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View Lastest Price from 3,5-Dimethoxytoluene manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
3,5-Dimethoxytoluene 4179-19-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
3,5-Dimethoxytoluene 4179-19-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
3,5-DIMETHOXYTOLUENE 4179-19-5
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-09

4179-19-5, 3,5-DimethoxytolueneRelated Search:


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