METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE

Product Name: METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE
CAS No.: 877624-40-3
Chemical Name: METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE
Synonyms: METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE;3-Bromo-5-bromomethyl-benzoic acid methyl ester;Benzoic acid, 3-bromo-5-(bromomethyl)-, methyl ester
CBNumber: CB02455576
Molecular Formula: C9H8Br2O2
Formula Weight: 307.97
MOL File: 877624-40-3.mol

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METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE Property

Boiling point:: 344.6±32.0 °C(Predicted)
Density: 1.780±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: White to light yellow Solid

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: M295898
Product name: Methyl3-bromo-5-(bromomethyl)benzoate
Packaging: 100mg
Price: $65
Updated: 2021/12/16

Matrix Scientific

Product number: 102647
Product name: Methyl 3-bromo-5-(bromomethyl)benzoate
Purity: 98%
Packaging: 250mg
Price: $59
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-9-13
Product name: Methyl 3-bromo-5-(bromomethyl)benzoate
Purity: 98%
Packaging: 250mg
Price: $80
Updated: 2021/12/16

Matrix Scientific

Product number: 102647
Product name: Methyl 3-bromo-5-(bromomethyl)benzoate
Purity: 98%
Packaging: 1g
Price: $148
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-9-13
Product name: Methyl 3-bromo-5-(bromomethyl)benzoate
Purity: 98%
Packaging: 1g
Price: $200
Updated: 2021/12/16

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METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE Chemical Properties,Usage,Production

Synthesis

307353-32-8

877624-40-3

General procedure for the synthesis of methyl 3-bromo-5-(bromomethyl)benzoate from methyl 3-bromo-5-(hydroxymethyl)benzoate: methyl 3-bromo-5-(hydroxymethyl)benzoate (2.0 g, 8.2 mmol) was mixed with triphenylphosphine (4.28 g, 16.3 mmol) in tetrahydrofuran (20 mL) and the mixture was cooled down to 0°C. The reaction was completed by the addition of N-bromosuccinimidamide (3.05 g, 17.1 mmol). Subsequently, N-bromosuccinimide (3.05 g, 17.1 mmol) was added in batches and the reaction mixture was allowed to gradually warm up to room temperature. After 16 h of reaction, the reaction mixture was diluted with ethyl acetate, washed sequentially with saturated sodium bicarbonate solution (2×) and brine (2×), the organic phase was dried with anhydrous sodium sulfate and concentrated under reduced pressure. Purification by silica gel column chromatography (eluent: 10% ethyl acetate/hexane) gave 2.1 g of light brown oily product in 83% yield. The product was identified by 1H-NMR (CDCl3, 300 MHz): δ 8.07 (s, 1H), 7.96 (s, 1H), 7.70 (s, 1H), 4.42 (s, 2H), 3.90 (s, 3H). Mass spectrometry analysis showed a molecular ion peak of 308.93 (MH)+.

References

[1] Patent: US2007/249607, 2007, A1. Location in patent: Page/Page column 85

METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE Suppliers

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877624-40-3, METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATERelated Search:

(3-(BROMOMETHYL)PHENYL)METHANOL METHYL 3,3,5-TRIBROMO-OXINDOLE-7-CARBOXYLATE 3-(BROMOMETHYL)BENZOIC ACID Methyl 3-(bromomethyl)benzoate METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE

METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE

3-Bromo-5-bromomethyl-benzoic acid methyl ester

Benzoic acid, 3-bromo-5-(bromomethyl)-, methyl ester

877624-40-3