Dimethyl hydroxymethylphosphonate

Product Name: Dimethyl hydroxymethylphosphonate
CAS No.: 24630-67-9
Chemical Name: Dimethyl hydroxymethylphosphonate
Synonyms: Dimethyl hydroxymethylphosphonate;Hydroxymethylphosphonic acid dimethyl ester;Phosphonic acid, P-(hydroxymethyl)-, dimethyl ester
CBNumber: CB02462149
Molecular Formula: C3H9O4P
Formula Weight: 140.07
MOL File: 24630-67-9.mol

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Dimethyl hydroxymethylphosphonate Property

Boiling point:: 209℃
Density: 1.245
Flash point:: 80℃
storage temp.: Inert atmosphere,Room Temperature
pka: 12.73±0.10(Predicted)
Appearance: Colorless to light yellow Liquid
InChI: InChI=1S/C3H9O4P/c1-6-8(5,3-4)7-2/h4H,3H2,1-2H3
InChIKey: OIERWUPLBOKSRB-UHFFFAOYSA-N
SMILES: P(CO)(=O)(OC)OC
CAS DataBase Reference: 24630-67-9(CAS DataBase Reference)

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Matrix Scientific

Product number: 097238
Product name: Dimethyl (hydroxymethyl)phosphonate
Purity: 95+%
Packaging: 250mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 097238
Product name: Dimethyl (hydroxymethyl)phosphonate
Purity: 95+%
Packaging: 1g
Price: $178
Updated: 2021/12/16

Ark Pharm

Product number: AK105037
Product name: Dimethyl(hydroxymethyl)phosphonate
Purity: 91%
Packaging: 10g
Price: $180
Updated: 2021/12/16

AK Scientific

Product number: 1882AB
Product name: Dimethyl(hydroxymethyl)phosphonate
Packaging: 1g
Price: $290
Updated: 2021/12/16

Ark Pharm

Product number: AK105037
Product name: Dimethyl(hydroxymethyl)phosphonate
Purity: 91%
Packaging: 25g
Price: $360
Updated: 2021/12/16

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Dimethyl hydroxymethylphosphonate Chemical Properties,Usage,Production

Synthesis

50-00-0

868-85-9

24630-67-9

Under stirring conditions, dimethyl phosphite (10.0 mL, 109 mmol), triethylamine (1.5 mL, 10.9 mmol) and paraformaldehyde (3.26 g) were mixed. The mixture was heated in an oil bath (external temperature) at 100°C. After 2.5 hours of reaction, the mixture was cooled to room temperature and subsequently concentrated under vacuum. The residue was purified by fast column chromatography (eluent: ethyl acetate/methanol, 95:5, v/v) to afford dimethyl hydroxymethylphosphonate as a colorless oil (9.41 g, 62% yield). The product was confirmed by 1H NMR (400 MHz, CDCl3): δ 4.32 (1H, br s), 3.95 (2H, d, J = 6 Hz), 3.83 (3H, s), 3.81 (3H, s); 31P{1H} NMR (400.1 MHz, CDCl3): δ 27.8; 13C NMR (100.6 MHz. CDCl3): δ 53.5, 56.0, 57.6.

References

[1] Journal of Polymer Science, Part A: Polymer Chemistry, 2012, vol. 50, # 12, p. 2432 - 2443
[2] Chemistry - A European Journal, 2009, vol. 15, # 9, p. 2064 - 2070
[3] Patent: WO2006/20779, 2006, A2. Location in patent: Page/Page column 77
[4] Organic Letters, 2012, vol. 14, # 18, p. 4798 - 4801
[5] Bioorganic and Medicinal Chemistry, 1998, vol. 6, # 3, p. 315 - 322

Dimethyl hydroxymethylphosphonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Dimethyl hydroxymethylphosphonate Suppliers

China 68 France 1 India 1 United Kingdom 1 United States 5 Global 76

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View Lastest Price from Dimethyl hydroxymethylphosphonate manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Dimethyl (hydroxymethyl)phosphonate 24630-67-9
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-25

XINXIANG RUNYU MATERIAL CO., LTD.

Product: Dimethyl(hydroxymethyl)phosphonate 24630-67-9
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 100kg
Release date: 2023-10-13

Zhuozhou Wenxi import and Export Co., Ltd

Product: Dimethyl hydroxymethylphosphonate 24630-67-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

24630-67-9, Dimethyl hydroxymethylphosphonateRelated Search:

Diethyl (hydroxymethyl)phosphonate DIMETHYL PHOSPHATE TRIMETHYL PHOSPHONOFORMATE butonate Trichlorfon Ethyl diethoxyphosphinylformate DIETHYL 1-HYDROXYBUTYLPHOSPHONATE Dimethyl phosphite 2-ETHOXY-TRIETHYLPHOSPHONOACETATE DIETHYL(DIETHOXYMETHYL)PHOSPHONATE DIPHENYL (2,4-DICHLOROPHENYL)(HYDROXY)METHYLPHOSPHONATE DIMETHYL (2,2,2-TRICHLORO-1-([(3-CHLOROANILINO)CARBONYL]OXY)ETHYL)PHOSPHONATE DIMETHYL (2,2,2-TRICHLORO-1-([(4-CHLOROANILINO)CARBONYL]OXY)ETHYL)PHOSPHONATE METHYL DIETHOXY PHOSPHINYL FORMATE DIMETHYL (1-([(BUTYLAMINO)CARBONYL]OXY)-2,2,2-TRICHLOROETHYL)PHOSPHONATE DIMETHYL [3-(4-BROMOPHENYL)-3-CHLORO-1-HYDROXYALLYL]PHOSPHONATE DIMETHYL [2,2,2-TRICHLORO-1-(([3-(TRIFLUOROMETHYL)ANILINO]CARBONYL)OXY)ETHYL]PHOSPHONATE DIPHENYL HYDROXY(4-PYRIDINYL)METHYLPHOSPHONATE

Dimethyl hydroxymethylphosphonate

Hydroxymethylphosphonic acid dimethyl ester

Phosphonic acid, P-(hydroxymethyl)-, dimethyl ester

24630-67-9