Benzyl4-iodobenzoate
- Product Name
- Benzyl4-iodobenzoate
- CAS No.
- 136618-42-3
- Chemical Name
- Benzyl4-iodobenzoate
- Synonyms
- Benzyl4-iodobenzoate;Benzoic acid, 4-iodo-, phenylmethyl ester
- CBNumber
- CB02499132
- Molecular Formula
- C14H11IO2
- Formula Weight
- 338.14
- MOL File
- 136618-42-3.mol
Benzyl4-iodobenzoate Property
- Melting point:
- 65-66°
- Boiling point:
- 397.6±25.0 °C(Predicted)
- Density
- 1.609±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
- Appearance
- White to off-white Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B279908
- Product name
- Benzyl4-iodobenzoate
- Packaging
- 1g
- Price
- $195
- Updated
- 2021/12/16
- Product number
- 074737
- Product name
- Benzyl 4-iodobenzoate
- Purity
- 95+%
- Packaging
- 5g
- Price
- $899
- Updated
- 2021/12/16
- Product number
- X9951
- Product name
- Benzyl4-iodobenzoate
- Packaging
- 25g
- Price
- $945
- Updated
- 2021/12/16
- Product number
- 074737
- Product name
- Benzyl 4-iodobenzoate
- Purity
- 95+%
- Packaging
- 10g
- Price
- $1286
- Updated
- 2021/12/16
- Product number
- HCH0368576
- Product name
- BENZYL-4-IODOBENZOATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $504.12
- Updated
- 2021/12/16
Benzyl4-iodobenzoate Chemical Properties,Usage,Production
Synthesis
619-58-9
100-39-0
136618-42-3
General procedure: 4-Iodobenzoic acid (15.62 g, 63 mmol, 1.05 eq.) was suspended in anhydrous DMF (90 mL, 6 vol.) under nitrogen protection, potassium carbonate (8.7 g, 63 mmol, 1.05 eq.) was added, and stirred for 10 minutes. Subsequently, benzyl bromide (10.25 g, 7.13 mL, 60 mmol, 1 eq.) was slowly added dropwise for a controlled time of about 5 minutes. The reaction mixture was continued to be stirred at room temperature for 6.25 hours. Upon completion of the reaction, the mixture was transferred to a partition funnel and extracted with ether (200 mL) and water (200 mL) by partition. The aqueous phase was extracted once more with ether, and the organic phases were combined and washed sequentially with water, aqueous lithium chloride and brine. The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to afford benzyl 4-iodobenzoate (18.38 g, 86% yield) as a white crystalline solid. The product was analyzed by LCMS: tRET = 3.81 min, 70% ES + ve 376,356 (artifactual peak appeared at 1.48 min, 28%).1H NMR (400 MHz, DMSO-d6) δ ppm: 7.92 (d, 2H), 7.74 (d, 2H), 7.46 (d, 2H), 7.35-7.42 (m, 3H ), 5.34 (s, 2H).
References
[1] Patent: WO2009/74590, 2009, A1. Location in patent: Page/Page column 59-60
[2] Patent: WO2009/50220, 2009, A1. Location in patent: Page/Page column 42
Benzyl4-iodobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Benzyl4-iodobenzoate Suppliers
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- sales@ajchem.in
- Country
- India
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