ChemicalBook > CAS DataBase List > 4-Bromophenylacetone

4-Bromophenylacetone

Product Name
4-Bromophenylacetone
CAS No.
6186-22-7
Chemical Name
4-Bromophenylacetone
Synonyms
4-BROMOPHENYLACETONE;4-BROMOPHENYLACETONATE;LABOTEST-BB LT01143429;4-Bromophenylacetone,97%;4-Bromophenylacetone,99%;4-Bromophenylacetone >4-Bromophenylacetone ,98%;P-BROMO BENZYL METHYL KETONE;1-(4-BROMOPHENYL)PROPAN-2-ONE;1-(4-BROMOPHENYL)-2-PROPANONE
CBNumber
CB0251262
Molecular Formula
C9H9BrO
Formula Weight
213.07
MOL File
6186-22-7.mol
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4-Bromophenylacetone Property

Melting point:
24-25 °C
Boiling point:
139°C/11mmHg(lit.)
Density 
1.3841 (rough estimate)
refractive index 
1.5560 to 1.5600
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid After Melting
color 
Clear yellow
Water Solubility 
Miscible with chloroform and dichloromethane. Slightly miscible with water.
InChI
InChI=1S/C9H9BrO/c1-7(11)6-8-2-4-9(10)5-3-8/h2-5H,6H2,1H3
InChIKey
CFMMTXJMIJRUSH-UHFFFAOYSA-N
SMILES
C(C1=CC=C(Br)C=C1)C(=O)C
CAS DataBase Reference
6186-22-7(CAS DataBase Reference)
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Safety

Safety Statements 
24/25
HS Code 
29143900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B4387
Product name
4-Bromophenylacetone
Purity
>98.0%(GC)
Packaging
5g
Price
$60
Updated
2025/07/31
TCI Chemical
Product number
B4387
Product name
4-Bromophenylacetone
Purity
>98.0%(GC)
Packaging
25g
Price
$211
Updated
2025/07/31
TRC
Product number
B686210
Product name
4-Bromophenylacetone
Packaging
25g
Price
$305
Updated
2021/12/16
TRC
Product number
B686210
Product name
4-Bromophenylacetone
Packaging
5g
Price
$120
Updated
2021/12/16
TRC
Product number
B686210
Product name
4-Bromophenylacetone
Packaging
10g
Price
$165
Updated
2021/12/16
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4-Bromophenylacetone Chemical Properties,Usage,Production

Chemical Properties

clear light yellow liquid after melting

Uses

4-Bromophenylacetone is used to prepare biphenyl-4-yl-acetone by reacting with phenylboronic acid using cesium fluoride as a reagent and palladium phosphine complex as a catalyst.

Synthesis

21892-60-4

6186-22-7

1-Bromo-4-(2-nitroprop-1-en-1-yl)benzene (116.8 g, 0.48 mol) was mixed with iron powder (228 g, 4.08 mol) and ferric(III) chloride (2.28 g, 14 mmol) in water (456 ml), heated to 65°C and then 37% hydrochloric acid (about 20 ml) was added slowly and dropwise. The heating was stopped and the mixture was warmed up to about 95°C due to an exothermic reaction. After the exothermic reaction subsided, 37% hydrochloric acid (about 200 ml) was added slowly and stirring was continued to room temperature. Ethyl acetate (900 ml) was added and stirred for 30 minutes. The reaction mixture was filtered through a diatomaceous earth pad and layered and the aqueous phase was re-extracted with ethyl acetate (200 ml). The organic phases were combined, washed with brine and dried over magnesium sulfate. Filtration and concentration gave 2-(4-bromophenyl)acetone (96.5 g, 94% yield) as an oil, which was pure enough to be used directly in the subsequent reaction.

References

[1] Patent: WO2017/29104, 2017, A1. Location in patent: Page/Page column 11
[2] Synthesis, 1985, # 6/7, p. 654 - 656
[3] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1978, p. 995 - 1001
[4] Chimica Therapeutica, 1968, vol. 3, p. 313 - 320
[5] Journal of the American Chemical Society, 1964, vol. 86, p. 684 - 687

4-Bromophenylacetone Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromophenylacetone Suppliers

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View Lastest Price from 4-Bromophenylacetone manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
4-Bromophenylacetone 6186-22-7
Price
US $1.00-4.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200000KG
Release date
2025-09-08
Shaanxi Dideu New Materials Co. Ltd
Product
4-Bromophenylacetone 6186-22-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-03-12
Shaanxi Franta Biotechnology Co., Ltd
Product
4-Bromophenylacetone 6186-22-7
Price
US $40.00/kg
Min. Order
100kg
Purity
99%
Supply Ability
1000kg
Release date
2024-09-23

6186-22-7, 4-BromophenylacetoneRelated Search:

4-Methoxyphenylacetone 1,3-Diphenylacetone 4-Chlorophenylacetone (4-Fluorophenyl)acetone 6-Bromo-2-tetralone Phenylacetone Bromindione 4,4'-DIBROMOBENZIL Propiophenone 3-BROMOPHENYLACETONE 2-BROMOPHENYLACETONE 2-(4-BROMOPHENYL)ACETOPHENONE 2-(4-Bromophenyl)-1-(2,4-dihydroxyphenyl)ethanone 2-(4-BROMOPHENYL)-3'-CYANOACETOPHENONE AKOS BBS-00006060 2-(4-BROMOPHENYL)-2'-IODOACETOPHENONE 2-(4-BROMOPHENYL)-4'-CYANOACETOPHENONE 2-(4-BROMOPHENYL)-3'-IODOACETOPHENONE

  • P-BROMO BENZYL METHYL KETONE
  • 1-(4-BROMOPHENYL)-2-PROPANONE
  • 1-(4-BROMOPHENYL)PROPAN-2-ONE
  • 4-BROMOPHENYLACETONATE
  • 4-BROMOPHENYLACETONE
  • LABOTEST-BB LT01143429
  • 4-Bromophenylacetone,99%
  • 4-Bromophenylacetone,97%
  • 4-Bromophenylacetone ,98%
  • 4-Bromophenylacetone &gt
  • 2-Propanone, 1-(4-bromophenyl)-
  • 6186-22-7
  • 3186-22-7
  • Aromatic Ketones (substituted)