ChemicalBook > CAS DataBase List > 4-Bromophenoxybenzene

4-Bromophenoxybenzene

Product Name
4-Bromophenoxybenzene
CAS No.
101-55-3
Chemical Name
4-Bromophenoxybenzene
Synonyms
1-Bromo-4-phenoxybenzene;4-BROMODIPHENYL ETHER;pbde 3;P-BROMDIPHENYL ETHER;BDE No 3 solution;4-bromo-diphenylethe;p-phenoxybromobenzene;4-BROMODIPHENYL OXIDE;4-bromophenoxybenzene;P-BROMODIPHENYL ETHER
CBNumber
CB0252643
Molecular Formula
C12H9BrO
Formula Weight
249.1
MOL File
101-55-3.mol
More
Less

4-Bromophenoxybenzene Property

Melting point:
18 °C (lit.)
Boiling point:
305 °C (lit.)
Density 
1.423 g/mL at 25 °C (lit.)
vapor pressure 
1.94 x 10-3 mmHg at 25 °C (subcooled liquid, Tittlemier et al., 2002)
refractive index 
n20/D 1.607(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Soluble in ether (Weast, 1986) and many other solvents including 1,4-dioxane, benzene, and toluene.
form 
Liquid
color 
Colorless to Almost colorless
BRN 
1308972
Henry's Law Constant
2.27 at 25 °C (integrated gas-stripping method, GC, Lau et al., 2006)
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey
JDUYPUMQALQRCN-UHFFFAOYSA-N
CAS DataBase Reference
101-55-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-bromo-4-phenoxy-(101-55-3)
EPA Substance Registry System
p-Bromophenyl phenyl ether (101-55-3)
More
Less

Safety

Hazard Codes 
N,Xn,F
Risk Statements 
50/53-67-65-38-11-43-41-22
Safety Statements 
60-61-62-36/37/39-26-33-29-16-9
RIDADR 
UN 3082 9/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29093090
Hazardous Substances Data
101-55-3(Hazardous Substances Data)
Toxicity
LC50 (24-h) for Daphnia magna 0.46 mg/L (LeBlanc, 1980).
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B65209
Product name
4-Bromodiphenyl ether
Purity
99%
Packaging
25g
Price
$137
Updated
2024/03/01
TCI Chemical
Product number
B0637
Product name
4-Bromodiphenyl Ether
Purity
>98.0%(GC)
Packaging
25g
Price
$46
Updated
2024/03/01
TCI Chemical
Product number
B0637
Product name
4-Bromodiphenyl Ether
Purity
>98.0%(GC)
Packaging
500g
Price
$500
Updated
2024/03/01
Alfa Aesar
Product number
L01473
Product name
4-Bromodiphenyl ether, 99%
Packaging
25g
Price
$48.4
Updated
2023/06/20
Alfa Aesar
Product number
L01473
Product name
4-Bromodiphenyl ether, 99%
Packaging
100g
Price
$145
Updated
2023/06/20
More
Less

4-Bromophenoxybenzene Chemical Properties,Usage,Production

Description

4-Bromophenyl phenyl ether is a brominateddiphenylether and a liquid at common ambient temperatures.Molecular weight=249.10; Boiling point=310.14 ℃;Specific gravity (H2O:1)=1.449 (1.4208 at 20 ℃);Freezing/Melting point=18.72℃; Vapor pressure 50.0015 mmHg at 20℃; Flash point=.110℃. HazardIdentification (based on NFPA-704 M Rating System):Health 1, Flammability 1, Reactivity 0. Poor solubility inwater; solubility=4.8 mg/L at 25℃.

Chemical Properties

light yellow liquid

Definition

ChEBI: An aromatic ether that is diphenyl ether substituted at position 4 by a bromo group.

General Description

Liquid. Freezing point 18°C. Density 1.423 g / cm3. Insoluble or slightly soluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Bromophenoxybenzene oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164].

Fire Hazard

Combustible.

Potential Exposure

Very little information on 4-bromophenyl phenyl ether exists. It is prepared by brominatingdiphenyl ether with Br2 at 95-100℃ in carbontetrachloride.[US EPA, 1986] 4-Bromophenyl phenyl ether hasbeen identified in raw water, in drinking water, and in riverwater.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

Environmental Fate

Biological. Using settled domestic wastewater inoculum, 4-bromophenyl phenyl ether (5 and 10 mg/L) did not degrade after 28 d of incubation at 25 °C (Tabak et al., 1981).
Chemical/Physical. At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 303, 112, 41, and 15 mg/g, respectively (Dobbs and Cohen, 1980).

storage

Color Code—Green: General storage may be used.Store away from heat, flames, or oxidizing materials; etherstend to peroxidize when exposed to air formingunstable peroxides that may detonate with extreme violence.

Shipping

The name of this material is not on the DOT listof materials for label and packaging standards. However,based on regulations, it may be classified as anEnvironmentally hazardous substances, liquid, n.o.s. It fallsin Hazard Class 9 and Packing Group III.[20, 21]

4-Bromophenoxybenzene Preparation Products And Raw materials

Raw materials

Preparation Products

Pyriproxyfen 4-PHENOXYPHENYLBORONIC ACID
More
Less

4-Bromophenoxybenzene Suppliers

Americas 1 Belgium 1 Canada 1 China 190 Europe 3 France 1 Germany 4 India 4 Japan 3 Switzerland 1 Ukraine 1 United Kingdom 8 United States 29 Global 247
Zhengzhou HQ Material Co., Ltd.
Tel
0371-67759225 13526468238
Fax
+86-37155919558
Email
sales@hqmat.com
Country
China
ProdList
525
Advantage
60
Henan Violet Technology Co., Ltd
Tel
0371-0371-55361188 13409345566
Fax
0371-55987170
Email
henanzll7175@zll-tech.com
Country
China
ProdList
132
Advantage
55
Pingdingshan Longwei Biotechnology Co. , Ltd.
Tel
15343756688
Email
3079249712@qq.com
Country
China
ProdList
316
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15848
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
More
Less

View Lastest Price from 4-Bromophenoxybenzene manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
4-Bromophenoxybenzene 101-55-3
Price
US $0.00/KG
Min. Order
10g
Purity
99.5%
Supply Ability
10TON S
Release date
2020-11-23
Hebei Duling International Trade Co. LTD
Product
4-Bromophenoxybenzene 101-55-3
Price
US $67.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 Ton
Release date
2023-04-14
Shanghai Daken Advanced Materials Co.,Ltd
Product
4-Bromophenoxybenzene 101-55-3
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
150KG /month
Release date
2021-11-17

101-55-3, 4-BromophenoxybenzeneRelated Search:

2,2?3,3?4,5,6-HEPTABROMODIPHENYL ETHER 2,6-DIBROMODIPHENYL ETHER 2,5-DIBROMOANISOLE Celiprolol hydrochloride 2,3,3',4,4',5,6-HEPTABROMODIPHENYL ETHER 2,5-DIBROMODIPHENYL ETHER 2,2?3-TRIBROMODIPHENYL ETHER 2,2',4,5'-TETRABROMODIPHENYL ETHER 2,3,5-TRIBROMODIPHENYL ETHER 3,5-DIBROMODIPHENYLETHER Decabromodiphenyl oxide 2,2?4,4?6,6?HEXABROMODIPHENYL ETHER 2-BROMODIPHENYL ETHER 2,2?3,3?TETRABROMODIPHENYL ETHER 2,2?DIBROMODIPHENYL ETHER 3-BROMODIPHENYL ETHER Pentabromodiphenyl ether 2,2?3,4,4?5,6-HEPTABROMODIPHENYL ETHER

  • 4-BROMOPHENYL PHENYL ETHER
  • 4-bromophenoxybenzene
  • 4-BROMODIPHENYL ETHER
  • 4-BROMODIPHENYL OXIDE
  • p-phenoxybromobenzene
  • p-Phenoxyphenyl bromide
  • 1-Bromo-4-phenoxybenzene
  • P-BROMODIPHENYL ETHER
  • P-BROMOPHENYL PHENYL ETHER
  • 1-BROMO-4-PHENOXY-BENZENE (4-BROMOPHENYL PHENYL ETHER)
  • 4-bromo-1-phenoxy-benzene
  • p-Bromodiphenyl ether? 4-Bromophenoxybenzene
  • P-BROMDIPHENYL ETHER
  • pbde 3
  • 4-PHENOXYBROMOBENZENE
  • MONOBROMODIPHENYLETHER
  • PARA-BROMODIPHENYLETHER
  • Bromophenyl phenyl ether, 4-
  • 4-Bromodiphenyl ether solution, PBDE 3
  • BDE No 3 solution
  • 4-Bromodiphenyl ether,50 μL/mL in Isooctane
  • 4-Bromophenyl phenyl ether 1g [101-55-3]
  • 4-Bromodiphenyl ether,4-Bromophenyl phenyl ether
  • 4-Bromodiphenyl ester
  • 11 -Bromo-4-phenoxybenzene
  • 1-bromo-4-phenoxy-benzen
  • 4-bromo-diphenylethe
  • benzene,1-bromo-4-phenoxy-
  • Diphenyl ether, 4-bromo-
  • diphenyl,4-bromo-ethe
  • Ether, 4-bromophenyl phenyl
  • Ether, p-bromophenyl phenyl
  • ether,4-bromophenylphenyl
  • ether,p-bromophenylphenyl
  • p-(Phenoxy)bromobenzene
  • p-Bromophenoxybenzene
  • p-Bromphenyl phenyl ether
  • Phenyl ether, 4-bromo-
  • phenyl(4-bromophenyl)ether
  • 4-Bromophenyl phenyl ether @5.0 mg/mL in MeOH
  • 4-Bromodiphenyl Ether &gt
  • 4-Bromophenyl Phenyl Ether @100 μg/mL in MeOH
  • 4-Bromodiphenylether Solution, 100μg/mL
  • PBDE 3(4-Bromodiphenyl Ether）
  • 18-ISOPROPYLCYCLOHEXANONE
  • 101-55-3
  • C12H6BrO
  • BrC6H4OC6H5
  • Oxygen Compounds
  • Organic Building Blocks
  • Ethers
  • Building Blocks
  • Alcohol& Phenol& Ethers
  • API intermediates
  • Biphenyl & Diphenyl ether