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Decabromodiphenyl oxide

Product Name
Decabromodiphenyl oxide
CAS No.
1163-19-5
Chemical Name
Decabromodiphenyl oxide
Synonyms
BDE-209;DECABROMODIPHENYL ETHER;DECA;DecaBDE;dbdpo;DBDE;PBDE209;PENTABROMOPHENYL ETHER;BIS(PENTABROMOPHENYL) ETHER;br55n
CBNumber
CB9705445
Molecular Formula
C12Br10O
Formula Weight
959.17
MOL File
1163-19-5.mol
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Decabromodiphenyl oxide Property

Melting point:
>300 °C(lit.)
Boiling point:
425°C
Density 
3 g/cm3
vapor pressure 
0Pa at 21℃
refractive index 
1.5000 (estimate)
Flash point:
-12 °C
storage temp. 
2-8°C
solubility 
<0.0001mg/l
form 
Solid
color 
White to Light Brown
Water Solubility 
<0.1 g/100 mL at 20 ºC
BRN 
2188438
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
WHHGLZMJPXIBIX-UHFFFAOYSA-N
LogP
6.625 at 25℃
CAS DataBase Reference
1163-19-5(CAS DataBase Reference)
IARC
3 (Vol. 48, 71) 1999
EPA Substance Registry System
Decabromodiphenyl oxide (1163-19-5)
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Safety

Hazard Codes 
Xn,Xi,N,F
Risk Statements 
20/21/22-67-65-63-50/53-48/20-38-11
Safety Statements 
36/37-62-61-60-16
RIDADR 
3152
WGK Germany 
1
RTECS 
KN3525000
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
9
PackingGroup 
II
HS Code 
29093031
Hazardous Substances Data
1163-19-5(Hazardous Substances Data)
Toxicity
Review IARC: Group 3 IMEMDT 48,73,90; Animal Limited Evidence IMEMDT 48,73,90. NTP Carcinogenesis Studies (feed); Some Evidence: rat NTPTR* NTP-TR-309,86; (feed); Equivocal Evidence: mouse NTPTR* NTP-TR-309,86. Polybrominated biphenyl compounds ar
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H304May be fatal if swallowed and enters airways

H312Harmful in contact with skin

H315Causes skin irritation

H318Causes serious eye damage

H320Causes eye irritation

H336May cause drowsiness or dizziness

H341Suspected of causing genetic defects

H351Suspected of causing cancer

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

P331Do NOT induce vomiting.

P370+P378In case of fire: Use … for extinction.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
NIST2258
Product name
BDE 209 in 2,2,4-Trimethylpentane
Purity
NIST?SRM?
Packaging
6G
Price
$1020
Updated
2024/03/01
Sigma-Aldrich
Product number
89407
Product name
BDE No 209 solution
Purity
~50?μg/mL (Isooctane:Toluene 50:50), analytical standard
Packaging
1ML
Price
$203
Updated
2024/03/01
TCI Chemical
Product number
D1388
Product name
Decabromodiphenyl Ether
Purity
>95.0%(GC)
Packaging
25g
Price
$14
Updated
2021/12/16
TRC
Product number
D212850
Product name
Decabromodiphenyl Ether
Packaging
100mg
Price
$1210
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
50540
Product name
DecabromodiphenylOxide
Packaging
100mg
Price
$2000
Updated
2021/12/16
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Decabromodiphenyl oxide Chemical Properties,Usage,Production

Description

DBDPO is a white to off-white powder.Molecular weight = 959.9. Hazard Identification (based onNFPA-704 M Rating System): Health 2, Flammability 0,Reactivity 0. Slightly soluble in water.

Chemical Properties

Decabromodiphenyl Oxide (DBDPO) is a white to off-white or light yellow powder. Almost insoluble in all solvents. Good thermal stability. Heated to 354 ℃, weight loss 5%. It is a non-toxic and non-polluting flame retardant.

Uses

Decabromodiphenyl ether is a brominated flame retardant that is used in conjunction with antimony trioxide in high impact polystyrene. DecaBDE is used as an additive flame retardant, and has a variety of applications including in plastics/polymers/composites, textiles, adhesives, sealants, coatings and inks. DecaBDE containing plastics are used in housings of computers and TVs, wires and cables, pipes and carpets. Adverse effects are reported for soil organisms, birds, fish, frog, rat, mice and humans. One of the new POPs under the Stockholm Convention

Definition

ChEBI: Decabromodiphenyl ether is a polybromodiphenyl ether that is diphenyl ether in which all of the hydrogens have been replaced by bromines. It has a role as a neurotoxin.

Application

Decabromodiphenyl oxide is an unreactive, additive flame retardant widely used for its thermal stability and its low cost in thermoplastic resins, thermoset resins, textiles and adhesives. The major applications are in high impact polystyrene, glass reinforced thermoplastic polyester and moulding resins, low density polyethylene extrusion coatings, polypropylene (homo- and copolymers), acrylonitrile butadiene styrene rubber, nylon and polyvinyl chloride.

Preparation

Decabromodiphenyl ether can be synthesized by reacting diphenyl ether with bromine in the presence of halogenated catalyst (iron powder, etc.).
The diphenyl ether is dissolved in the solvent, the catalyst is added, and then bromine is added to carry out the reaction. After the reaction, filter, wash and dry to obtain decabromodiphenyl ether. Commonly used solvents are dibromoethane, dichloroethane, dibromomethane, carbon tetrachloride, tetrachloroethane and the like.

General Description

White to off-white powder with a chemical odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Decabromodiphenyl oxide is incompatible with strong oxidizers .

Fire Hazard

Flash point data for Decabromodiphenyl oxide are not available; however, Decabromodiphenyl oxide is probably combustible.

Safety Profile

Questionable carcinogen with experimental neoplastigenic data. Experimental reproductive effects. Used as a flame retardant for thermoplastics. When heated to decomposition it emits toxic fumes of Br-. See also ETHERS and BROMIDES

Potential Exposure

It is used as a fire retardant for thermoplastics and man-made fibers.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

storage

Color Code—Green: General storage may be used.Prior to working with DPDPO you should be trained on itsproper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from strong oxidizers.Where possible, automatically transfer this chemical fromdrums or other storage containers to process containers. Useonly nonsparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition, such as smoking and open flames, are prohibited wherethis chemical is used, handled, or stored in a manner thatcould create a potential fire or explosion hazard. Whereverthis chemical is used, handled, manufactured, or stored, useexplosion-proof electrical equipment and fittings.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. UN3152 Polyhalogenated biphenyls, solid or Polyhalogenated ter- phenyls, solid, Hazard class: 9; Labels: 9-Miscellaneous hazardous material.

Incompatibilities

Incompatible with strong oxidizers (chlo- rates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Ethers have a tendency to form unstable and explosive peroxides.

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Decabromodiphenyl oxide Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7508
Advantage
55
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2883
Advantage
65
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18736
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12990
Advantage
57
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View Lastest Price from Decabromodiphenyl oxide manufacturers

Jinan Finer Chemical Co., Ltd
Product
Decabromodiphenyl oxide 1163-19-5
Price
US $0.00/kg
Min. Order
1kg
Purity
≥83%
Supply Ability
2000mt/year
Release date
2023-01-04
Hebei Guanlang Biotechnology Co., Ltd.
Product
Decabromodiphenyl oxide 1163-19-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-12-07
Hebei Mojin Biotechnology Co., Ltd
Product
Decabromodiphenyl oxide 1163-19-5
Price
US $0.00/Kg
Min. Order
1Kg
Purity
99%
Supply Ability
20ton
Release date
2023-08-24

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