ChemicalBook > CAS DataBase List > 4-Bromophenoxybenzene

4-Bromophenoxybenzene

Product Name
4-Bromophenoxybenzene
CAS No.
101-55-3
Chemical Name
4-Bromophenoxybenzene
Synonyms
1-Bromo-4-phenoxybenzene;4-BROMODIPHENYL ETHER;pbde 3;P-BROMDIPHENYL ETHER;BDE No 3 solution;4-bromo-diphenylethe;p-phenoxybromobenzene;4-BROMODIPHENYL OXIDE;4-bromophenoxybenzene;P-BROMODIPHENYL ETHER
CBNumber
CB0252643
Molecular Formula
C12H9BrO
Formula Weight
249.1
MOL File
101-55-3.mol
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4-Bromophenoxybenzene Property

Melting point:
18 °C (lit.)
Boiling point:
305 °C (lit.)
Density 
1.423 g/mL at 25 °C (lit.)
vapor pressure 
1.94 x 10-3 mmHg at 25 °C (subcooled liquid, Tittlemier et al., 2002)
refractive index 
n20/D 1.607(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Soluble in ether (Weast, 1986) and many other solvents including 1,4-dioxane, benzene, and toluene.
form 
Liquid
color 
Colorless to Almost colorless
BRN 
1308972
Henry's Law Constant
2.27 at 25 °C (integrated gas-stripping method, GC, Lau et al., 2006)
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey
JDUYPUMQALQRCN-UHFFFAOYSA-N
CAS DataBase Reference
101-55-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-bromo-4-phenoxy-(101-55-3)
EPA Substance Registry System
p-Bromophenyl phenyl ether (101-55-3)
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Safety

Hazard Codes 
N,Xn,F
Risk Statements 
50/53-67-65-38-11-43-41-22
Safety Statements 
60-61-62-36/37/39-26-33-29-16-9
RIDADR 
UN 3082 9/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29093090
Hazardous Substances Data
101-55-3(Hazardous Substances Data)
Toxicity
LC50 (24-h) for Daphnia magna 0.46 mg/L (LeBlanc, 1980).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B65209
Product name
4-Bromodiphenyl ether
Purity
99%
Packaging
25g
Price
$137
Updated
2024/03/01
TCI Chemical
Product number
B0637
Product name
4-Bromodiphenyl Ether
Purity
>98.0%(GC)
Packaging
25g
Price
$46
Updated
2024/03/01
TCI Chemical
Product number
B0637
Product name
4-Bromodiphenyl Ether
Purity
>98.0%(GC)
Packaging
500g
Price
$500
Updated
2024/03/01
Alfa Aesar
Product number
L01473
Product name
4-Bromodiphenyl ether, 99%
Packaging
25g
Price
$48.4
Updated
2023/06/20
Alfa Aesar
Product number
L01473
Product name
4-Bromodiphenyl ether, 99%
Packaging
100g
Price
$145
Updated
2023/06/20
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4-Bromophenoxybenzene Chemical Properties,Usage,Production

Description

4-Bromophenyl phenyl ether is a brominateddiphenylether and a liquid at common ambient temperatures.Molecular weight=249.10; Boiling point=310.14 ℃;Specific gravity (H2O:1)=1.449 (1.4208 at 20 ℃);Freezing/Melting point=18.72℃; Vapor pressure 50.0015 mmHg at 20℃; Flash point=.110℃. HazardIdentification (based on NFPA-704 M Rating System):Health 1, Flammability 1, Reactivity 0. Poor solubility inwater; solubility=4.8 mg/L at 25℃.

Chemical Properties

light yellow liquid

Definition

ChEBI: An aromatic ether that is diphenyl ether substituted at position 4 by a bromo group.

General Description

Liquid. Freezing point 18°C. Density 1.423 g / cm3. Insoluble or slightly soluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Bromophenoxybenzene oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164].

Fire Hazard

Combustible.

Potential Exposure

Very little information on 4-bromophenyl phenyl ether exists. It is prepared by brominatingdiphenyl ether with Br2 at 95-100℃ in carbontetrachloride.[US EPA, 1986] 4-Bromophenyl phenyl ether hasbeen identified in raw water, in drinking water, and in riverwater.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

Environmental Fate

Biological. Using settled domestic wastewater inoculum, 4-bromophenyl phenyl ether (5 and 10 mg/L) did not degrade after 28 d of incubation at 25 °C (Tabak et al., 1981).
Chemical/Physical. At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 303, 112, 41, and 15 mg/g, respectively (Dobbs and Cohen, 1980).

storage

Color Code—Green: General storage may be used.Store away from heat, flames, or oxidizing materials; etherstend to peroxidize when exposed to air formingunstable peroxides that may detonate with extreme violence.

Shipping

The name of this material is not on the DOT listof materials for label and packaging standards. However,based on regulations, it may be classified as anEnvironmentally hazardous substances, liquid, n.o.s. It fallsin Hazard Class 9 and Packing Group III.[20, 21]

4-Bromophenoxybenzene Preparation Products And Raw materials

Raw materials

Preparation Products

Pyriproxyfen 4-PHENOXYPHENYLBORONIC ACID
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4-Bromophenoxybenzene Suppliers

Americas 1 Belgium 1 Canada 1 China 204 Europe 3 France 1 Germany 4 India 4 Japan 3 Switzerland 1 Ukraine 1 United Kingdom 8 United States 30 Global 262
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View Lastest Price from 4-Bromophenoxybenzene manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
4-Bromophenoxybenzene 101-55-3
Price
US $0.00/KG
Min. Order
10g
Purity
99.5%
Supply Ability
10TON S
Release date
2020-11-23
Shanghai Daken Advanced Materials Co.,Ltd
Product
4-Bromophenoxybenzene 101-55-3
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
150KG /month
Release date
2021-11-17
Hebei Weibang Biotechnology Co., Ltd
Product
4-Bromophenoxybenzene 101-55-3
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-04

101-55-3, 4-BromophenoxybenzeneRelated Search:

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